A two-lift gradient design for airport pavements has been proposed to mitigate the functional degradation, especially the salt-frost (S-F) damage induced by deicing slat fluids. Herein, this study focuses on elucidating the mechanism and improvement of incorporating mineral admixtures in the development of a novel S-F resistant surface concrete material, which is of great significance for delaying the functional deterioration of pavement surface in northern China. The results indicated that the filling effect and secondary hydration reaction between the fly ash (FA) and silica fume (SF) and cement hydration products results in a dense spatial network structure, effectively reducing porosity and optimizing pore structure. It was found that SF can effectively improve the frost resistance and salt corrosion resistance of cement mortar, while the influence of FA depends on its content and environmental conditions. The incorporation of FA and SF significantly enhanced the structural density of cement concrete and reduced chloride ion permeability. The improvement in impermeability is most pronounced when both FA and SF are used in combination. In addition, a fitting equation between the admixture content and chloride ion permeability has been established, demonstrating good fitting results. In non-frozen saline soil areas, a large amount of FA or SF could be incorporated; in seasonally frozen areas, the priority should be given to SF to ensure salt corrosion resistance and frost resistance. The findings of this study provide a scientific basis for sustainable airport pavement construction in northern China.