Indian monsoon circulation is the primary driver of the long-range transboundary mercury (Hg) pollution from South Asia to the Himalayas and Tibet Plateau region, yet the northward extent of this transport remains unknown. In this study, a strong delta Hg-202 signature overlapping was found between Lake Gokyo and Indian anthropogenic sources, which is an indicative of the Hg source regions from South Asia. Most of the sediment samples were characterized with relatively large positive Delta Hg-199 values (mean = 0.07 parts per thousand-0.44 parts per thousand) and small positive Delta Hg-200 values (mean = 0.03 parts per thousand-0.08 parts per thousand). Notably, the Delta Hg-199 values in the lake sediments progressively increased from southwest to northeast. Moreover, the Delta Hg-199 values peaked at Lake Tanglha (mean = 0.44 parts per thousand +/- 0.04 parts per thousand) before decreased at Lake Qinghai that is under the influence of the westerlies. Our results suggest that transboundary atmospheric transport could transport Hg from South Asia northwards to at least the Tanglha Mountains in the northern Himalaya-Tibet.

Black carbon (BC) is one of the major aerosol components with relatively high implications on climatic patterns through its radiative forcing (RF). South Asia has recently experienced an increased concentration of pollution; however, relatively fewer studies have been carried out on long-term assessment of BC and its implications. The present study analyzed the long-term concentration of BC in selected urban locations over South Asia using the Modern-Era Retrospective analysis for Research and Applications, version 2 (MERRA-2). The study employed statistical analysis, including linear regression techniques, to assess the long-term concentration of BC. The results show that a rapid increase of BC is observed over most urban locations of South Asia with the predominance in winter and hence requires strict regional control measures to reduce the excess concentration of BC in the atmosphere. High concentration of BC in winter is attributed to anthropogenic activities and changes in meteorological conditions that enhance the accumulation of pollutants in the atmosphere. The relationship of BC with cloud top temperature and cloud effective radius demonstrates the direct and indirect effect of BC on cloud properties in this region. The RF results reveal that aerosol optical depth has positive aerosol RF in the atmosphere and negative RF at the top of the atmosphere (TOA) as well as at the bottom of the atmosphere (BOA). Negative RF at the TOA indicates less forcing efficiency due to fewer BC aerosols. On the other hand, averaging aerosol RF within the atmosphere reveals positive forcing, which suggests the efficiency force exerted by BC aerosols after absorbing solar radiation.

Surface albedo (SA) is crucial for understanding land surface processes and climate simulation. This study analyzed SA changes and its influencing factors in Central Asia from 2001 to 2020, with projections 2025 to 2100. Factors analyzed included snow cover fraction, fractional vegetation cover, soil moisture, average state climate indices (temperature and precipitation), and extreme climate indices (heatwave indices and extreme precipitation indices). Pearson correlation coefficient, geographical convergent cross mapping, and geographical detector were used to quantify the correlation, causal relationship strength, and impact degree between SA and the influencing factors. To address multicollinearity, ridge regression (RR), geographically weighted ridge regression (GWRR), and piecewise structural equation modeling (pSEM) were combined to construct RR-pSEM and GWRR-pSEM models. Results indicated that SA in Central Asia increased from 2001 to 2010 and decreased from 2011 to 2020, with a projected future decline. There is a strong correlation and significant causality between SA and each factor. Snow cover fraction was identified as the most critical factor influencing SA. Average temperature and precipitation had a greater impact on SA than extreme climate indices, with a 1 degrees C temperature increase corresponding to a 0.004 decrease in SA. This study enhances understanding of SA changes under climate change, and provides a methodological framework for analyzing complex systems with multicollinearity. The proposed models offer valuable tools for studying interrelated factors in Earth system science.

Winter baseflow (WB) can stabilize freshwater inputs and has important impacts on nutrient migration and the water cycle of a specific region and the oceans. This study systematically analyzed the WB variations in fourteen major Eurasian rivers and found they all had commonly increasing trends (except the Yellow River), with the mean increase ratio of 53.0% (+/- 34.8%, confidence interval 95%) over the past 100 years (the longest time series is 1879-2015). Relative to Northern Eurasia (60 degrees N-70 degrees N) and Southern Eurasia (30 degrees N-40 degrees N), the river WB in middle Eurasia (40 degrees N-60 degrees N) had the largest increase rate (0.60%/year). The increases of the WB in Northern Eurasia and Southern Eurasia have speeded up since the 1990s; on the contrary, they have slowed down or even turned to a decreasing trend after the 1990s in the middle Eurasian rivers. Using multiple linear regression analysis, the quantitative relationship between WB and winter surface air temperature (max, mean and min), snowfall, soil temperature, antecedent precipitation, as well as the river-ice dynamic were determined. We found that the winter air temperature, especially the minimum air temperature was one major factor accounting for WB variation in Eurasia over the past century. When the winter air temperature rises, this leads a reduction in the thickness and volume of river ice, and thus decreases water storage in river ice and leads to an increase in the WB. About 19.6% (6.7%-41.5%) of the winter WB increase in rivers of Siberia was caused by the decreased river ice during the past 100 years. Although groundwater recharge was the dominant reason for WB change, the role of river ice should not be ignored in hydrological study of cold regions.

Light-absorbing carbonaceous aerosols that dominate atmospheric aerosol warming over India remain poorly characterized. Here, we delve into UV-visible-IR spectral aerosol absorption properties at nine PAN-India COALESCE network sites (Venkataraman et al., 2020, ). Absorption properties were estimated from aerosol-laden polytetrafluoroethylene filters using a well-constrained technique incorporating filter-to-particle correction factors. The measurements revealed spatiotemporal heterogeneity in spectral intrinsic and extrinsic absorption properties. Absorption analysis at near-UV wavelengths from carbonaceous aerosols at these regional sites revealed large near-ultraviolet brown carbon absorption contributions from 21% to 68%-emphasizing the need to include these particles in climate models. Further, satellite-retrieved column-integrated absorption was dominated by surface absorption, which opens possibilities of using satellite measurements to model surface-layer optical properties (limited to specific sites) at a higher spatial resolution. Both the satellite-modeled and direct in-situ absorption measurements can aid in validating and constraining climate modeling efforts that suffer from absorption underestimations and high uncertainties in radiative forcing estimates. Particulate pollution in the atmosphere scatter and absorb incoming solar energy, thus cooling or warming Earth's atmosphere. In developing countries and especially in India, one of the most polluted regions of the world, the extent to which particles can absorb solar energy and warm the atmosphere is not well understood. Here, for the first time, we measure particle absorption simultaneously at nine ground sites across India, in diverse geographical regions with different levels and types of particulate pollution. We find that organic carbon particles exert large absorption at near-ultraviolet wavelengths, which contain significant solar energy. These light absorbing organic carbon particles, called brown carbon, are emitted in large quantities from biomass burning (e.g., burning crop residue and cooking on wood-fired stoves). Comparing ground measurements of absorption with satellite-retrieved measurements that are representative of the entire atmospheric column, we find that near-surface atmospheric particles can exert significant warming. This study highlights the need to improve climate model simulations of particulate pollution's impact on the climate by incorporating spatiotemporal surface-level absorption measurements, including absorption by brown carbon particles. Measurements at nine regional PAN-India sites reveal several regions with large aerosol absorption strength Brown carbon contributes significantly (21%-68%) to near-ultraviolet absorption, indicating its importance in shortwave light absorption Strong correlations observed between satellite data and surface absorption indicate future potential in modeling surface absorption

This study uses a new dataset on gauge locations and catchments to assess the impact of 21st-century climate change on the hydrology of 221 high-mountain catchments in Central Asia. A steady-state stochastic soil moisture water balance model was employed to project changes in runoff and evaporation for 2011-2040, 2041-2070, and 2071-2100, compared to the baseline period of 1979-2011. Baseline climate data were sourced from CHELSA V21 climatology, providing daily temperature and precipitation for each subcatchment. Future projections used bias-corrected outputs from four General Circulation Models under four pathways/scenarios (SSP1 RCP 2.6, SSP2 RCP 4.5, SSP3 RCP 7.0, SSP5 RCP 8.5). Global datasets informed soil parameter distribution, and glacier ablation data were integrated to refine discharge modeling and validated against long-term catchment discharge data. The atmospheric models predict an increase in median precipitation between 5.5% to 10.1% and a rise in median temperatures by 1.9 degrees C to 5.6 degrees C by the end of the 21st century, depending on the scenario and relative to the baseline. Hydrological model projections for this period indicate increases in actual evaporation between 7.3% to 17.4% and changes in discharge between + 1.1% to -2.7% for the SSP1 RCP 2.6 and SSP5 RCP 8.5 scenarios, respectively. Under the most extreme climate scenario (SSP5-8.5), discharge increases of 3.8% and 5.0% are anticipated during the first and second future periods, followed by a decrease of -2.7% in the third period. Significant glacier wastage is expected in lower-lying runoff zones, with overall discharge reductions in parts of the Tien Shan, including the Naryn catchment. Conversely, high-elevation areas in the Gissar-Alay and Pamir mountains are projected to experience discharge increases, driven by enhanced glacier ablation and delayed peak water, among other things. Shifts in precipitation patterns suggest more extreme but less frequent events, potentially altering the hydroclimate risk landscape in the region. Our findings highlight varied hydrological responses to climate change throughout high-mountain Central Asia. These insights inform strategies for effective and sustainable water management at the national and transboundary levels and help guide local stakeholders.

Empirical orthogonal function (EOF) and correlation analyses were employed to investigate the winter and spring snow depth in Eurasia and its relationship with Eastern China precipitation based on the observed and reanalyzed data from 1980 to 2016. The results show that the winter and spring snow cover in Eurasia not only highlights a decreasing trend due to global warming (the first EOF mode, its variance accounted for 24.4% and 22.6% of the total variance) but also exhibits notable interdecadal variation (the second EOF mode, its variance accounted for 10.2% and 11.5% of the total variance). The second EOF mode of winter snow depth in Eurasia is characterized by a west-east dipole pattern. It was observed that the spatial correlation pattern between the EOF2 of Eurasian snow depth and summer precipitation in China closely resembles the meridional quadrupole structure of the third EOF mode of summer precipitation in China. This pattern is characterized by excessive rainfall in Northeast China and the lower-middle reaches of the Yangtze River, and less rainfall over the Yellow River basin and southern China. The EOF mode of spring snow depth not only reflects the declining trend but also regulates precipitation in Eastern China. The possible mechanisms by which snow depth causes changes in soil moisture and subsequently affects atmospheric circulation are then explored from the perspective of the hydrological effects of snow cover. Decreased (Increased) snow depth in Eurasia during the winter and spring directly leads to diminished (increased) soil moisture while increasing (decreasing) net radiation and sensible heat flux at the surface. The meridional distribution of surface temperature also exhibits a dipole pattern, leading to enhanced subtropical westerly jet in the upper troposphere. The Eurasian snow cover anomalies pattern triggered an anomalous mid-latitude Eurasian wave train, which strengthened significantly in the Western Siberian Plain. It then splits into two branches, one continuing to propagate eastward at high latitudes and the other shifting towards East Asia, thereby impacting precipitation in Eastern China. This work indicates that the second EOF mode of Eurasian snow cover can impact the precipitation variability in Eastern China during the same period and in summer on an interdecadal scale.

In the context of China's dual carbon goal, emissions of air pollutants are expected to significantly decrease in the future. Thus, the direct climate effects of black carbon (BC) aerosols in East Asia are investigated under this goal using an updated regional climate and chemistry model. The simulated annual average BC concentration over East Asia is approximately 1.29 mu g/m(3) in the last decade. Compared to those in 2010-2020, both the BC column burden and instantaneous direct radiative forcing in East Asia decrease by more than 55% and 80%, respectively, in the carbon peak year (2030s) and the carbon neutrality year (2060s). Conversely, the BC effective radiative forcing (ERF) and regional climate responses to BC exhibit substantial nonlinearity to emission reduction, possibly resulting from different adjustments of thermal-dynamic fields and clouds from BC-radiation interactions. The regional mean BC ERF at the tropopause over East Asia is approximately +1.11 W/m(2) in 2010-2020 while negative in the 2060s. BC-radiation interactions in the present-day impose a significant annual mean cooling of -0.2 to -0.5 K in central China but warming +0.3 K in the Tibetan Plateau. As China's BC emissions decline, surface temperature responses show a mixed picture compared to 2010-2020, with more cooling in eastern China and Tibet of -0.2 to -0.3 K in the 2030s, but more warming in central China of approximately +0.3 K by the 2060s. The Indian BC might play a more important role in East Asian climate with reduction of BC emissions in China.

Aerosol optical properties, including absorption and scattering coefficients (B-abs, and B-scat), extinction coefficient (B-ext), single scattering albedo (SSA), and so forth, are critical metrics to estimate the radiative balance of the atmosphere. However, their ground measurements are sparsely distributed in the world, where Central Asia is void in these measurements. We had been performing the measurements of AOPs and BC with a photoacoustic extinctiometer (PAX) in Jimunai, a border town of China neighboring Kazakhstan, Central Asia, from Aug 2016 to Apr 2019. This three-year study first reported statistically significant trends of B-abs, B-scat, B-ext, SSA, and derived concentrations of BC (Mann-Kendall trend test, p-value 0.05) in the Central-Asian area. B-abs and B-scat show increasing trends and SSA was decreasing determined by the greater increasing pace of B-abs than B-scat. Seasonal and diurnal variations of the AOPs were associated with climate shift and residents' commute activity, respectively. The difference in the magnitudes and trends of AOPs between the measurements and satellites' observations advise that more care should be invested when choosing remote-sensing data to represent the AOPs at a specific site. The increasing trend of derived BC concentrations is reflected in the deposition record of BC in a snowpit of the nearby Muz Taw glacier. We suppose that the dramatically increasing BC particles emitted from Jimunai are significant factors triggering the melting of the adjacent mountain glaciers. The outflow of dust from the neighboring Gurbantiinggiit Desert could occasionally invade into Jimunai and deteriorate the local air quality, as evidenced by a probable dust event captured by the PAX on Feb 15, 2018. Finally, we outlook the future perspectives of measurements in Jimunai as a long-standing station.

High Mountain Asia (HMA) shows a remarkable warming tendency and divergent trend of regional precipitation with enhanced meteorological extremes. The rapid thawing of the HMA cryosphere may alter the magnitude and frequency of nature hazards. We reviewed the influence of climate change on various types of nature hazards in HMA region, including their phenomena, mechanisms and impacts. It reveals that: 1) the occurrences of extreme rainfall, heavy snowfall, and drifting snow hazards are escalating; accelerated ice and snow melting have advanced the onset and increased the magnitude of snowmelt floods; 2) due to elevating trigger factors, such as glacier debuttressing and the rapid shift of thermal and hydrological regime of bedrock/snow/ice interface or subsurface, the mass flow hazards including bedrock landslide, snow avalanche, ice-rock avalanches or glacier detachment, and debris flow will become more severe; 3) increased active-layer detachment and retrogressive thaw slumps slope failures, thaw settlement and thermokarst lake will damage many important engineering structures and infrastructure in permafrost region; 4) multi-hazards cascading hazard in HMA, such as the glacial lake outburst flood (GLOF) and avalanche-induced mass flow may greatly enlarge the destructive power of the primary hazard by amplifying its volume, mobility, and impact force; and 5) enhanced slope instability and sediment supply in the highland areas could impose remote catastrophic impacts upon lowland regions, and threat hydropower security and future water shortage. In future, ongoing thawing of HMA will profoundly weaken the multiple-phase material of bedrock, ice, water, and soil, and enhance activities of nature hazards. Compounding and cascading hazards of high magnitude will prevail in HMA. As the glacier runoff overpasses the peak water, low flow or droughts in lowland areas downstream of glacierized mountain regions will became more frequent and severe. Addressing escalating hazards in the HMA region requires tackling scientific challenges, including understanding multiscale evolution and formation mechanism of HMA hazard-prone systems, coupling thermo-hydro-mechanical processes in multi-phase flows, predicting catastrophes arising from extreme weather and climate events, and comprehending how highland hazards propagate to lowlands due to climate change.