Backfill mining is a lucrative method for extracting coal buried under buildings, and water bodies, which can substantially increase the resource usage efficiency by mitigating the strata movement and surface subsidence. Its effectiveness depends on the mechanical properties of granular backfill materials. A permeability test was performed on gangue and fly ash samples under different stress levels using an original seepage test system. The variation patterns of the broken rock's internal pressure and permeability were determined. The test results indicate the weakening of the seepage effect on granular materials and a gradual reduction of washed away fly ash. The permeability values fall into the range of 3.2 x 10(-15) similar to 3.2 x 10(-13)m(-2), and non-Darcy factor is between 3.2 x 10(10) and 3.2 x 10(12) m(-1). This phenomenon was more pronounced in samples with smaller particle sizes. As the axial stress increased, the backfill material showed a decline in permeability and an increase in the non-Darcy flow coefficient. As the content of fly ash increased, the mass loss grew sharply, which occurred mainly at the early seepage stage. The results are considered instrumental in the characterization of water and sand inrush.

The morphology of sheep wool applied as organic fertilizer biodegraded in the soil was examined. The investigations were conducted in natural conditions for unwashed waste wool, which was rejected during sorting and then chopped into short segments and wool pellets. Different types of wool were mixed with soil and buried in experimental plots. The wool samples were periodically taken and analyzed for one year using Scanning Electron Microscopy (SEM) and Energy-dispersive X-ray Spectroscopy (EDS). During examinations, the changes in the fibers' morphology were observed. It was stated that cut wool and pellet are mechanically damaged, which significantly accelerates wool biodegradation and quickly destroys the whole fiber structure. On the contrary, for undamaged fibers biodegradation occurs slowly, layer by layer, in a predictable sequence. This finding has practical implications for the use of wool as an organic fertilizer, suggesting that the method of preparation can influence its biodegradation rate. (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(SEM)(sic)(sic)(sic)(sic)(sic)X(sic)(sic)(sic)(sic)(EDS)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic).

The reasonable value of good gradation characteristic parameters is key in designing and optimising soil-rock mixed high fill embankment materials. Firstly, the DJSZ-150 dynamic-static large-scale triaxial testing instrument was used for triaxial compression shear tests on compacted skeleton structure soil-rock mixture standard specimens. The changes in strength and deformation indicators under different gradation parameters and confining pressure were analysed. Then, based on the Janbu empirical formula, relationships between parameters K, n, and (sigma 1-sigma 3)ult and the coefficient of uniformity Cu and coefficient of curvature Cc were explored. Empirical fitting formulas for Duncan-Chang model constants a and b were proposed, establishing an improved Duncan-Chang model for soil-rock mixtures considering gradation characteristics and stress states. Finally, based on significant differences in particle spatial distribution caused by gradation changes, three generalised models of matrix-block stone motion from different particle aggregation forms were proposed. Results indicate the standard specimen's strength and deformation indicators exhibit significant gradation effects and stress-state correlations. The improved Duncan-Chang model effectively simulates the stress-strain relationship curve under different gradations and confining pressure, with its characteristics explainable based on the matrix block stone motion generalised model.

On December 18, 2023, a magnitude MS6.2 earthquake struck Jishishan County, Gansu Province, triggering over 40 seismic subsidence sites within a seismic intensity VI zone, 32 km from the epicenter.The earthquake caused tens of millions in economic losses to mountain photovoltaic power stations. Extensive geological surveys and comparisons with similar landslides (such as soil loosening, widespread cracks, and stepped displacements) triggered by the 1920 Haiyuan MS8.5 earthquake and the 1995 Yongdeng MS5.8 earthquake, this study preliminarily identifies one subsidence sites as a seismic-collapsed loess landslide. To investigate its disaster-causing mechanism: the dynamic triaxial test was conducted to assess the seismic subsidence potential of the loess at the site, and the maximum subsidence amount under different seismic loads were calculated by combining actual data from nearby bedrock stations with site amplification data from the active source; simulation of the destabilization evolution of seismic-collapsed loess landslides by large-scale shaking table tests; and a three-dimensional slope model was developed using finite element method to study the complex seismic conditions responsible for site damage. The research findings provide a theoretical foundation for further investigations into the disaster mechanisms of seismic-collapsed loess landslides.

Liquefaction hazard analysis is crucial in earthquake-prone regions as it magnifies structural damage. In this study, standard penetration test (SPT) and shear wave velocity (Vs) data of Chittagong City have been used to assess the liquefaction resistance of soils using artificial neural network (ANN). For a scenario of 7.5 magnitude (Mw) earthquake in Chittagong City, estimating the liquefaction-resistance involves utilizing peak horizontal ground acceleration (PGA) values of 0.15 and 0.28 g. Then, liquefaction potential index (LPI) is determined to assess the severity of liquefaction. In most boreholes, the LPI values are generally higher, with slightly elevated values in SPT data compared to Vs data. The current study suggests that the Valley Alluvium, Beach and Dune Sand may experience extreme liquefaction with LPI values ranges from 9.55 to 55.03 and 0 to 37.17 for SPT and Vs respectively, under a PGA of 0.15 g. Furthermore, LPI values ranges from 25.55 to 71.45 and 9.55 to 54.39 for SPT and Vs correspondingly. The liquefaction hazard map can be utilized to protect public safety, infrastructure, and to create a more resilient Chittagong City.

Flash floods are often responsible for deaths and damage to infrastructure. The objective of this work is to create a data-driven model to understand how predisposing factors influence the spatial variation of the triggering factor (rainfall intensity) in the case of flash floods in the continental area of Portugal. Flash floods occurrences were extracted from the DISASTER database. We extracted the accumulated precipitation from the Copernicus database by considering two days of duration. The analysed predisposing factors for flooding were extracted considering the whole basin where each occurrence is located. These factors include the basin area, the predominant lithology, drainage density, and the mean or median values of elevation, slope, stream power index (SPI), topographic wetness index (TWI), roughness, and four soil properties. The Random Forest algorithm was used to build the models and obtained mean absolute percentage error (MAPE) around 19%, an acceptable value for the objectives of the work. The median of SPI, mean elevation and the area of the basin are the top three most relevant predisposing factors interpreted by the model for defining the rainfall input for flash flooding in mainland Portugal.

In highway construction across the southeastern coastal regions of China, granite residual soil is widely used as subgrade fill material in pavement engineering. Its mechanical behaviour under dynamic loads warrants in-depth investigation. Dynamic events such as vehicular traffic and earthquakes are complex, involving multidirectional loads. The dynamic behaviour of soil under bidirectional cyclic loading differs significantly from that under cyclic loading in one direction. A large-scale bidirectional cyclic direct shear apparatus was utilised to carry on a series of horizontal cyclic direct shear tests on granite residual soil with water contents of 14% and 24% at different normal stress amplitudes (sigma a) (0, 100, 200 kPa). Based on these tests, discrete element method (DEM) models were developed to simulate the laboratory tests. The test results revealed that cyclic normal stress increases dynamic shear strength during forward shear but reduces it during reverse shear. The energy dissipation capacity increases with rising sigma a. The dynamic behaviour of granite residual soil is more significantly affected by cyclic normal stress when the water content is higher. The DEM simulation results indicated that as cyclic shearing progresses, the location of the maximum principal stress (sigma 1) shifts from the top of the specimen toward the shear interface. The distribution of the angle between sigma 1 and the x-axis, as well as sigma 1 and the z-axis, transitions from 'M' distribution to 'Arch' distribution. With increasing sigma a, during forward shear, the magnitude of the maximum principal stress increases, and the orientation of sigma 1 rotates toward the normal direction. Conversely, during reverse shear, the magnitude of the maximum principal stress decreases, and its orientation shifts toward the horizontal shear direction. The material fabric anisotropy coefficient decreases with increasing sigma a, while the anisotropy orientation increases with increasing normal stress.

Canopy reflectance (CR) models describe the transfer and interaction of radiation from the soil background to the canopy layer and play a vital role in the retrieval of biophysical variables. However, few efforts have focused on estimating soil background scattering operators, resulting in uncertainties in CR modelling, especially over sloping terrain. This study developed a canopy reflectance model for simulating CR over sloping terrain, which combines the general spectral vector (GSV) model, the PROSPECT model, and 4SAIL model coupled with topography (GSV-PROSAILT). The canopy reflectance simulated by GSV-PROSAILT was validated against two datasets: discrete anisotropic radiative transfer (DART) simulations and remote sensing observations. A comparison with DART simulations under various conditions revealed that the GSV-PROSAILT model captures terrain-induced CR distortion with high accuracy (red band: coefficient of determination $\lpar {\rm R 2} \rpar = 0.731$(R2)=0.731, root-mean-square error (RMSE) = 0.007; near infrared (NIR) band: $\rm R2 = 0.8319$R2=0.8319, RMSE = 0.0098). The results of remote sensing observation verification revealed that the GSV-PROSAILT model can be successfully used in CR modelling. These validations confirmed the performance of GSV-PROSAILT in soil and canopy reflectance modelling over sloping terrain, indicating that it can provide a potential tool for biophysical variable retrieval over mountainous areas.

An analytical methodology was developed for the first time in this work enabling the simultaneous enantiomeric separation of the fungicide fenpropidin and its acid metabolite by Capillary Electrophoresis. A dual cyclodextrin system consisting of 4 % (w/v) captisol with 10 mM methyl-beta-cyclodextrin was employed in a 100 mM sodium acetate buffer at pH 4.0. Optimal experimental conditions (temperature 25 degrees C, separation voltage -25 kV, and hydrodynamic injection of 50 mbar x 10 s) allowed the simultaneous separation of the four enantiomers in <10.7 min with resolutions of 3.1 (fenpropidin) and 3.2 (its acid metabolite). Analytical characteristics of the method were evaluated and found adequate for the quantification of both chiral compounds with a linearity range from 0.75 to 70 mg L-1, good accuracy (trueness included 100 % recovery, precision with RSD<6 %), and limits of detection and quantification of 0.25 and 0.75 mg L-1, respectively, for the four enantiomers. No significant differences were found between the concentrations determined and labelled of fenpropidin in a commercial agrochemical formulation. The stability over time (0-42 days) of fenpropidin enantiomers using the commercial agrochemical formulation was evaluated in two sugar beet soils, revealing to be stable at any time in one sample, while in the other a decrease of 45 % was observed after 42 days. Individual and combined toxicity of fenpropidin and its metabolite was determined for the first time for marine organism Vibrio fischeri, demonstrating higher damage caused by parent compound. Synergistics and antagonists' interactions were observed at low and high effects levels of contaminants.

Correlations between the mechanical properties and surface scratch resistance of polylactic acid (PLA) are investigated via tensile and scratch tests on samples after degradation in soil for various times. The results show that the tensile yield strength of PLA is inversely proportional to the natural logarithm of the degradation time, and the scratch resistance and fracture toughness of PLA and the temperature rise near the indenter all increase and then decrease. The surface crystallinity of PLA also increases and then decreases, indicating that it and the scratch resistance are closely related. These findings provide useful information about how PLA behaves under degradation conditions. (c) 2025 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution-NonCommercial 4.0 International (CC BY-NC) license (https://creativecommons.org/licenses/by-nc/4.0/).