Granite residual soils (GRS) are often encountered in geotechnical projects in the Guangdong-Hong Kong-Macao Greater Bay Area (briefly written as the Greater Bay Area, or abbreviated as GBA). The rea experiences frequent rainfall, leading to wetting-drying cycles that progressively diminish the shear strength of GRS. This weakening effect is not only significant but also accumulates, exhibiting a direct positive correlation with the number of cycles. Current studies on the soil strength attenuation due to wetting-drying cycles are typically limited to no more than 10 cycles, which is rather insufficient to uncover the long-term water-weakening behaviors and their accumulative impacts on GRS. To address this gap, typical GRS samples were first taken from the GBA and then prepared by making them go through a certain number of wetting-drying cycles (maximum of up to 100). Next, a total of 552 small- and large-scale direct shear tests were conducted to investigate the mechanisms of water-weakening effects on soil internal friction angle, cohesion, and shear strength. The degree of saturation and number of cycles were also examined to see their effects on the cumulation of water weakening. Based on results from the small-scale direct shear tests, a model was developed for assessing the weakening impact of water on soil strength. The accuracy of the model prediction was statistically evaluated. Last, the effectiveness and efficiency of the proposed model were demonstrated by validating against the results from the large-scale direct shear tests.
In this study, the mitigating effects of CaO NPs obtained from pomegranate extract via environmentally friendly green synthesis on CdCl2 stress in two varieties (Yolboyu and Kirac) of Turkish Kavilca wheat (Triticum dicoccum Schrank) under in vitro callus culture conditions were investigated. The calluses developed from embryos of both wheat varieties were exposed to either CaO NPs alone (1 and 2 mg/L), CdCl2 alone (1 or 10 mM) or the different combinations of these two compounds in MS medium for 4 weeks. Changes in the expressions of two genes (Traes_5BL_9A790E8CF and Traes_6BL_986D595B9) known to be involved in wheat's response to CdCl2 stress were analyzed by qRT-PCR. Additionally, certain physiological parameters, such as lipid peroxidation (LPO), H2O2, proline and soluble sugar content, and SEM-EDX analysis were used to assess the response of calluses to the applications. The CaO NPs treatments alone generally upregulated the expression of the 5BL and 6BL genes, while the CdCl2 applications decreased their expression in both cultivars. The CaO NPs reduced the proline content in both cultivars compared to the control. Co-treatment with CdCl2 and CaO NPs increased the sugar content and decreased the MDA content, but did not cause a significant change in the H2O2 content. SEM analysis showed that when CdCl2 and CaO NPs were applied to calluses together, the membranous and mucilaginous spherical structures were regained. The application of CaO NPs reduces the amount of cellular damage caused by CdCl2 stress and improves gene expressions.
In order to investigate the influence of the CaO and fly ash (FA) dosage and proportion on the mechanical properties, durability, and microstructure of solidified sludge, freeze-thaw (F-T) cycles and dry-wet (D-W) cycles are conducted to study the change in appearance and the strength attenuation of CaO-FA solidified sludge. Low-field nuclear magnetic resonance (LF-NMR) is used to analyze the microstructure of the solidified sludge with various dosages and ratios of CaO-FA. The results demonstrate that the unconfined compressive strength (UCS) and direct shear strength of solidified sludge increase with the prolongation of the curing age. Furthermore, the mechanical properties of solidified sludge are improved as the ratio of CaO-FA increases. As the curing age increases, the distribution of transverse relaxation time (T2) becomes narrow, the spectral area decreases, and the amplitude of the LF-NMR signal shows a downward and leftward tendency. Additionally, with the increase in the number of F-T cycles and D-W cycles, the UCS of solidified sludge declines and the degree of pore deterioration increased gradually. This study offers a theoretical foundation and empirical data for the dredging and treatment of sludge in cold regions.
Plants are subject to various abiotic stresses such as water shortage and exposure to heavy metals, such as Pb in soil. These types of stress trigger a series of plant responses, ranging from a decrease in leaf gas exchange, an increase in lipid peroxidation, and even changes in the chemical composition of leaves and roots. As an essential micronutrient, Fe is involved in several physiological and biochemical processes in plants, such as photosynthetic activity, directly participating in chlorophyll synthesis and electron transport, being necessary for the maintenance of the structure and functioning of chloroplasts. The main objective of this work was to evaluate the action of Fe in mitigating Pb toxicity in young plants of the CCN 51 cacao genotype, subjected to water deficit in the soil, through photosynthetic responses and analysis of the chemical composition of different parts of the plant. Plants were grown with Pb (2 mmol Pb kg-1 soil) and different equimolar doses of Pb+Fe in the soil (2+0.5, 2+1, 2+1.5 and 2+2 mmol kg(-1) soil), maintaining constant the Pb dose, whose soil was subjected to water deficit, with gradual reduction of water content, or its moisture was maintained near to field capacity, making a total of 12 treatments, together with the control treatment (without addition of Pb and Fe in soil). It was observed that the greater Fe absorbing, by the root system, mitigated the Pb toxicity. Fe application, in adequate dose in soil (2 mmol Pb kg-1 soil + 0.5 mmol Fe kg(-1) soil), mitigated the toxic effects caused by Pb and water deficit in the plants, through the greater Fe taking up and translocation for the shoot in Pb detriment. Greater Pb translocation and accumulation in the leaves caused damage to leaf gas exchange and to the accumulation of carbohydrates in leaves. Fe and Pb applied in soil competed with each other for root absorbing regardless of soil water conditions.
Vibratory penetration was successfully used to install 120 integral thin-walled steel cylinders 22 m in diameter in the Hong Kong-Zhuhai-Macao Bridge. However, the eight-hammer group was found overpowered at the western island and underpowered at the eastern site due to insufficient understanding of the mechanisms of vibratory piling. In this study, energy analysis was conducted to reveal the energy characteristics of vibratory penetration, including the periodical energy superposition along the cylinder shaft, the continuous energy consumption in the soil, and the dynamic equilibrium of the total energy. The influences of vibratory soil resistance and loading frequency on the energy distributions have been thoroughly discussed. In contrast to the notion that larger input energy leads to a faster penetration, it is revealed that the vibratory penetration velocity positively correlates to the energy stored in the cylinder, the ratio of kinetic to strain energy, and the characteristic frequencies of the soil-pile system. The actual output power of the vibratory motors is influenced by the vibratory force, the ultimate soil resistance, and the soil mobilization degree. The vibration frequency is optimized as 31.1 Hz for Cylinder E9 and 15 Hz for Cylinder W36 to ensure efficiency and safety.