Land surface temperature (LST) plays an important role in Earth energy balance and water/carbon cycle processes and is recognized as an Essential Climate Variable (ECV) and an Essential Agricultural Variable (EAV). LST products that are issued from satellite observations mostly depict landscape-scale temperature due to their generally large footprint. This means that a pixel-based temperature integrates over various components, whereas temperature individual components are better suited for the purpose of evapotranspiration estimation, crop growth assessment, drought monitoring, etc. Thus, disentangling soil and vegetation temperatures is a real matter of concern. Moreover, most satellite-based LSTs are contaminated by directional effects due to the inherent anisotropy properties of most terrestrial targets. The characteristics of directional effects are closely linked to the properties of the target and controlled by the view and solar geometry. A singular angular signature is obtained in the hotspot geometry, i.e., when the sun, the satellite and the target are aligned. The hotspot phenomenon highlights the temperature differences between sunlit and shaded areas. However, due to the lack of adequate multi-angle observations and inaccurate portrayal or neglect of solar influence, the hotspot effect is often overlooked and has become a barrier for better inversion results at satellite scale. Therefore, hotspot effect needs to be better characterized, which here is achieved with a three-component model that distinguishes vegetation, sunlit and shaded soil temperature components and accounts for vegetation structure. Our work combines thermal infrared (TIR) observations from the Sea and Land Surface Temperature Radiometer (SLSTR) onboard the LEO (Low Earth Orbit) Sentinel-3, and two sensors onboard GEO (geostationary) satellites, i.e. the Advanced Himawari Imager (AHI) and Spinning Enhanced Visible and Infrared Imager (SEVIRI). Based on inversion with a Bayesian method and prior information associated with component temperature differences as constrained, the findings include: 1) Satellite observations throughout East Asia around noon indicate that for every 10 degrees change in angular distance from the sun, LST will on average vary by 0.6 K; 2) As a better constraint, the hotspot effect can benefit from multi-angle TIR observations to improve the retrieval of LST components, thereby reducing the root mean squared error (RMSE) from approximately 3.5 K, 5.8 K, and 4.1 K to 2.8 K, 3.5 K, and 3.1 K, at DM, EVO and KAL sites, respectively; 3) Based on a dataset simulated with a threedimensional radiative transfer model, a significant inversion error may result if the hotspot is ignored for an angular distance between the viewing and solar directions that is smaller than 30 degrees. Overall, considering the hotspot effect has the potential to reduce inversion noise and to separate the temperature difference between sunlit and shaded areas in a pixel, paving the way for producing stable temperature component products.

Carbonaceous aerosol components (CACs) significantly influence global radiative forcing and human health. We developed a simultaneous inversion algorithm for four CACs: black carbon (BC), brown carbon (BrC), watersoluble organic matter (WSOM), and water-insoluble organic matter (WIOM), considering their distinct optical, solubility, and hygroscopicity properties. Using AERONET data, we inverted the global concentrations of these components for 2022. We observed that the mass concentration of black carbon (BC) is highest in the South Asian region, with an annual average of 4.74 mg m(-2). High values of brown carbon (BrC) correspond well with regions and seasons of biomass burning, with the annual average reaching 9.03 mg m(-2) at sites in Central and West Africa. Water-insoluble organic matter (WIOM) is the most predominant component in carbonaceous aerosols, with an annual average concentration as high as 53.11 mg m(-2) at the Dhaka_University site in Eastern South Asia. Additionally, the study also points out a significant correlation between the dominant components of carbonaceous aerosols and their seasonal variations with local emissions. Furthermore, the validation of optical parameters against official AERONET products demonstrates a good correlation.

Due to the differences in the green water (GW) budget patterns of different vegetation, improper vegetation restoration may not only fail to improve the ecological environment but also cause irreversible damage to ecologically vulnerable areas, especially when vegetation restoration continues to be implemented in the future, and the pressure on water scarcity increases further. However, there is a lack of standardized research on the differences in the patterns of recharge, consumption, and efficient use of GW in typical vegetation. This makes the research results vary and cannot provide direct support for water management decision-making. Therefore, in this study, 30-year-old woodlands (R. pseudoacacia and P. orientalis) and two typical grasslands (I. cylindrican and M. sativa) that are similar to each other except for species were selected in a headwater catchment in the rain-fed agricultural area. A new GW concept and assessment framework was constructed to study the GW of long-term revegetation using a combination of field experiments and model simulations during the 2019-2020 growing season. The study findings comprise the following: (1) High-efficiency green water (GWH), low-efficiency green water (GWL), ineffective green water (GWI), and available green water storage (GWA) in the four sample plots during the study period were defined, separated, and compared. (2) An analysis of GWA variations under different water scenarios. (3) The establishment of GWH and GWL thresholds. (4) Strategies to reduce GWI and optimize GW potential while maintaining soil erosion prevention measures. (5) Suggestions for vegetation restoration species based on diverse factors. This research enhances comprehension of the impact of vegetation restoration on green water dynamics in ecologically vulnerable areas such as the rain-fed agricultural zone of the Loess Plateau.

Chemical stabilization is among the methods utilized to improve the shear strength properties and volumetric changes of problematic soils. This research assesses the possibility of using sludge ash from a wood and paper mill (SAWP) as an industrial sludge to improve the fat clay engineering characteristics. Thus, unconsolidated-undrained triaxial, direct shear, one-dimensional swelling, and consolidation tests were conducted. Results showed that shear strength parameters (both in short and long-term) increase with increasing SAWP contents and curing period due to the production of sufficient cementitious components and the formation of strong bonds between the particles. Investigating the direct shear test results indicated that the failure envelope in stabilized samples with high SAWP contents was slightly curved. Stabilized samples with high amounts of SAWP at low vertical stresses show brittle failure, while the type of failure observed for these samples at high vertical stresses is more ductile. Moreover, the magnitude of free swell gradually decreased with increasing SAWP contents. The replacement of clay particles with SAWP and flocculation and/or agglomeration of clay particles were the main reasons for this issue. Finally, the compression index, swell index, and coefficient of volume compressibility decrease with increasing SAWP content for the applied load increment, indicating the effect of stabilization in reducing the consolidation settlement of the layers. The test results revealed that the sludge ash used in this study can be used to enhance the engineering properties of fat clay.

Strong soil-tool adhesion on soil-engaging components is a key factor leading to the energy consumption and agricultural tool damage in agriculture tillage. A number of chemical and physical strategies have been widely proposed to eliminate soil-tool adhesion, but subjecting to limited anti-soil capabilities. In this work, we present an earthworm-inspired matter-repellent surface by stably grafting dimethyl dimethoxy silicane and infusing silicone oil, allowing for a superior resistance to soil-steel adhesion in an eco-friendly mode. The presence of such coating enables a theoretical adhesion work reduction by 10 times, thereby resulting in robust repellency to stick soil. Furthermore, the influence of water fraction in soil, adhesion velocity, and adhesion angle on the anti-soil performance of matter-repellent surfaces are fully revealed to guide its potential application in agricultural tools. It is anticipated that incorporating our matter-repellent coating into soil-engaging components is beneficial to the development of agricultural machinery.

With the increasing capacity of offshore wind turbines, the diameter of wind power monopiles has been continuously growing, leading to a significant decrease in the length-to-diameter ratio (L/D). Existing methods primarily focus on correcting the p-y curve due to increased pile diameter but fail to adequately consider the impact of changes in resistance components distribution resulting from a decreased L/D. This study aims to analyse the pile-soil interaction of large-diameter horizontally loaded monopiles by examining the distributed resistance components. Through finite element analysis and verification via engineering pile testing, the paper explores the resistance composition, deformation characteristics, and changes in resistance components of large-diameter monopiles. The findings reveal that the pile-soil horizontal resistance primarily governs the lateral bearing capacity of large-diameter monopiles for small range of length-to-diameter ratios (4 similar to 10). It is found that the deformation mode of monopiles is controlled by the pile-soil relative stiffness. A p-y resistance component curve for large-diameter horizontally loaded monopiles under various interlayer states of sand and clay was proposed as a function of pile-soil relative stiffness. For engineering practice, a simple but useful method for evaluating and correcting the lateral bearing capacity of monopiles was demonstrated based on the proposed resistance component curve.

Freeze-thaw (FT) events profoundly perturb the biochemical processes of soil and water in mid- and high-latitude regions, especially the riparian zones that are often recognized as the hotspots of soil-water interactions and thus one of the most sensitive ecosystems to future climate change. However, it remains largely unknown how the heterogeneously composed and progressively discharged meltwater affect the biochemical cycling of the neighbor soil. In this study, stream water from a valley in the Chinese Loess Plateau was frozen at -10 degrees C for 12 hours, and the meltwater (at +10 degrees C) progressively discharged at three stages (T1 similar to T3) was respectively added to rewet the soil collected from the same stream bed (Soil+T1 similar to Soil+T3). Our results show that: (1) Approximately 65% of the total dissolved organic carbon and 53% of the total NO3--N were preferentially discharged at the first stage T1, with enrichment ratios of 1.60 similar to 1.94. (2) The dissolved organic matter discharged at T1 was noticeably more biodegradable with significantly lower SUVA(254) but higher HIX, and also predominated with humic-like, dissolved microbial metabolite-like, and fulvic acid-like components. (3) After added to the soil, the meltwater discharged at T1 (e.g., Soil+T1) significantly accelerated the mineralization of soil organic carbon with 2.4 similar to 8.07-folded k factor after fitted into the first-order kinetics equation, triggering 125 similar to 152% more total CO2 emissions. Adding T1 also promoted significantly more accumulation of soil microbial biomass carbon after 15 days of incubation, especially on the FT soil. Overall, the preferential discharge of the nutrient-enriched meltwater with more biodegradable DOM components at the initial melting stage significantly promoted the microbial growth and respiratory activities in the recipient soil, and triggered sizable CO2 emission pulses. This reveals a common but long-ignored phenomenon in cold riparian zones, where progressive freeze-thaw can partition and thus shift the DOM compositions in stream water over melting time, and in turn profoundly perturb the biochemical cycles of the neighbor soil body.

The approach bridge of the pile-supported wharf is an important structure that connects the pile foundation platform and the land, and it has a significant impact on the safety of the high-pile wharf. However, the influence of an approach bridge on the seismic dynamic response of a pile-supported wharf has often been neglected in previous studies. Besides, the excess pore water pressure (Delta u) generated under combined vertical and horizontal seismic components is typically greater than that induced by unidirectional excitations, which may further impact the dynamic response of pile-supported wharf. Firstly, this study developed a numerical method for simulating the approach bridge of a pile-supported wharf. Secondly, the three-dimensional finite element model of a pile-supported wharf with an approach bridge is established to investigate the dynamic response during horizontal and vertical seismic components. Additionally, the effects of seismic frequency and relative density of liquefied layer on the dynamic response of pile-supported wharf were also studied. By comparing with the experimental results, the numerical model effectively simulated the overall response of the pile-supported wharf and the liquefaction behavior of the surrounding soil. During high-frequency earthquakes, the influence of the approach bridge on the dynamic response of the pile-supported wharf is minimal, whereas it has a more significant impact during low-frequency earthquakes. Furthermore, vertical seismic components significantly amplify the effect of approach bridge on the lateral displacement and internal forces of piles. The effect of the approach bridge on the lateral displacement and internal force of the pile decreases with the increase of the relative density of the liquefaction layer.

Zinc deficiency is one of the most widespread nutritional problems, affecting nearly one-third of the world population. In addition, it is known that zinc deficiency not only reduces crop yield but also its quality. The effect of different methods of zinc application on the growth, yield, and quality of safflower seeds under regular irrigation and interruption of irrigation from flowering to harvest (82 and 80 DAS in the first and second years, respectively) was evaluated. Zinc sulfate was applied in both soil and foliar methods. The zinc sulfate treatments include no zinc sulfate, soil application of 20, 40, and 60 kg ha(-1) at the planting stage; spraying 2.5, 5, and 7.5 g L-1 in the rosette stage; and spraying 2.5, 5, and 7.5 g L-1 in the flowering stage. The end-season drought caused a decrease in the chlorophyll index, leaf area index, relative water content, plant height, yield components, biological yield, seed yield, harvest index, seed oil content, oil harvest index, and seed element content compared to regular irrigation. The decrease in yield occurred with a decrease in the capitol number and diameter, seed number per capitol, and 1000-seed weight. The severity of the damage of the end-season drought stress in the second year was higher than in the first year due to the higher temperatures and the decrease in the rainfall. In both years, the application of zinc sulfate in different ways had an increasing effect on the studied traits in both normal and stress conditions. The application of zinc sulfate reduced the negative effects of unfavorable environmental conditions and improved the yield and nitrogen, phosphorus, potassium, zinc, and iron element content in the seed. In both application methods of zinc sulfate, the increment in the zinc sulfate concentration decreased the seed phosphorus content. However, the phosphorous content was more than that of the treatment of non-zinc application. The application of zinc increased the biological, seed, and oil yield of the treated plants, but the seed and oil yield were more affected. This effect was shown in the seed and oil harvest index increment. Under regular irrigation, higher concentrations of zinc sulfate enhanced plant performance, but under stress conditions, medium and lower concentrations were more effective. The highest 1000-seed weight and potassium and zinc content were obtained by spraying zinc sulfate at 5 g L-1 in the flowering stage under normal irrigation conditions. A comparison of the two methods of applying zinc sulfate showed that foliar spraying was more effective than soil application in improving the seed yield. The soil application is more effective on biological yield than seed yield.

To address the issue of high fracture and wear failure rates caused by the lack of toughness and abrasion resistance in the steel used for soil-engaging components of tillage machinery, a novel composite heat treatment process, normalizing and intercritical quenching and tempering (NIQT), is proposed. By regulating the austenitizing heating temperature in the intercritical area (ferrite/austenite two-phase area), the type, content, and distribution of phases in the 27MnCrB5 test sample could be precisely controlled, which further influenced the mechanical properties of the material. The results demonstrated that a multiphase composite microstructure, predominantly consisting of martensite and ferrite, could be obtained in the 27MnCrB5 steel treated by the NIQT process. The results of an EBSD test indicated that the predominant type of grain boundary following the NIQT heat treatment was a high-angle grain boundary (approximately 59.5%), which was favorable for hindering crack propagation and improving the impact toughness of the material. The results of the mechanical tests revealed that, when the quenching temperature was set to 790 degrees C, the 27MnCrB5 steel attained excellent comprehensive mechanical properties, with a tensile strength of 1654 MPa, elongation of 10.4%, impact energy of 77 J, and hardness of 530 HV30. Compared with conventional heat treatment processes for soil-engaging components, this novel process has the potential to enhance the performance of soil-engaging components and prolong their service life.