Black carbon (BC) exerts a profound and intricate impact on both air quality and climate due to its high light absorption. However, the uncertainty in representing the absorption enhancement of BC in climate models leads to an increased range in the modeled aerosol climate effects. Changes in BC optical properties could result either from atmospheric aging processes or from variations in its sources. In this study, a source-age model for identifying emission sources and aging states presented by University of California at Davis/California Institute of Technology (UCD/CIT) was used to simulate the atmospheric age distribution of BC from different sources and to quantify its impact on the optical properties of BC-containing particles. The results indicate that regions with greater aged BC concentrations do not correspond to regions with higher BC emissions due to atmospheric transport. High concentrations of aged BC are found in northern Yangtze River Delta (YRD) regions during summer. The chemical compositions of particles from different sources and with different atmospheric ages differ significantly. BC and primary organic aerosols (POA) are dominating in Traffic-dominated source while other components dominate in Industry-dominated source. As the atmospheric age increases, the mass fraction of secondary inorganic aerosols rises. Compared to the original model, the simulated mass absorption cross of BC particles in the source-age model decreases while the single scattering albedo increases. This compensates for -11 % of the overestimation of the simulated BC direct radiative forcing. Our study highlights that

Fluorescence spectroscopy is a commonly used technique to analyze dissolved organic matter in aquatic environments. Given the high sensitivity and non-destructive analysis, fluorescence has recently been used to study water-soluble organic carbon (WSOC) in atmospheric aerosols, which have substantial abundance, various sources and play an important role in climate change. Yet, current research on WSOC characterization is rather sparse and limited to a few isolated sites, making it challenging to draw fundamental and mechanistic conclusions. Here we presented a review of the fluorescence properties of atmospheric WSOC reported in various field and laboratory studies, to discuss the current advances and limitations of fluorescence applications. We highlighted that photochemical reactions and relevant aging processes have profound impacts on fluorescence properties of atmospheric WSOC, which were previously unnoticed for organic matter in aquatic environments. Furthermore, we discussed the differences in sources and chemical compositions of fluorescent components between the atmosphere and hydrosphere. We concluded that the commonly used fluorescence characteristics derived from aquatic environments may not be applicable as references for atmospheric WSOC. We emphasized that there is a need for more systematic studies on the fluorescence properties of atmospheric WSOC and to establish a more robust reference and dataset for fluorescence studies in atmosphere based on extensive source specific experiments. (C) 2020 Elsevier Ltd. All rights reserved.

This study reports on the measurements of ion and refractory black carbon (rBC) concentrations in a shallow (10.96 m) ice core sample which was drilled from the field site of the East Greenland Ice Core Project (EGRIP) in July, 2016. The results provide a recent record of rBC deposition in the East Greenland ice sheet from 1990 to 2016. The annual variability in oxygen (delta O-18) and hydrogen (delta D) isotopic compositions indicated that notably warm events occurred since 2008. Peaks in rBC occurred during summer seasons, which may be attributed to the burning of biomass in boreal summer. The rBC record and analysis of historical air trajectories using the HYSPLIT model indicated that anthropogenic BC emissions from Russia, North America and Europe contributed to the majority of rBC deposition in the Greenland region, and a reduction in anthropogenic BC consumption in these areas played a dominant role in the decrease in BC concentrations since 2000. This record also suggests that the emissions from the East Asian region (China) contributed very little to the recorded BC concentrations in East Greenland ice core. The model results indicated that radiative forcing due to BC had decreased significantly since 1990, and had remained below 0.02W m(-2) since 2000.

This study reports on the measurements of ion and refractory black carbon (rBC) concentrations in a shallow (10.96 m) ice core sample which was drilled from the field site of the East Greenland Ice Core Project (EGRIP) in July, 2016. The results provide a recent record of rBC deposition in the East Greenland ice sheet from 1990 to 2016. The annual variability in oxygen (delta O-18) and hydrogen (delta D) isotopic compositions indicated that notably warm events occurred since 2008. Peaks in rBC occurred during summer seasons, which may be attributed to the burning of biomass in boreal summer. The rBC record and analysis of historical air trajectories using the HYSPLIT model indicated that anthropogenic BC emissions from Russia, North America and Europe contributed to the majority of rBC deposition in the Greenland region, and a reduction in anthropogenic BC consumption in these areas played a dominant role in the decrease in BC concentrations since 2000. This record also suggests that the emissions from the East Asian region (China) contributed very little to the recorded BC concentrations in East Greenland ice core. The model results indicated that radiative forcing due to BC had decreased significantly since 1990, and had remained below 0.02W m(-2) since 2000.

Brown carbon (BrC), a carbonaceous aerosol which absorbs solar radiation over a broad range of wavelengths, is beginning to be seen as an important contributor to global warming. BrC absorbs both inorganic and organic pollutants, leading to serious effects on human health. We review the fundamental features of BrC, including its sources, chemical composition, optical properties and radiative forcing effects. We detail the importance of including photochemical processes related to BrC in the GEOS-Chem transport model for the estimation of aerosol radiative forcing. Calculation methods for BrC emission factors are examined, including the problems and limitations of current measurement methods. We provide some insight into existing publications and recommend areas for future research, such as further investigations into the reaction mechanisms of the aging of secondary BrC, calculations of the emission factors for BrC from different sources, the absorption of large and long-lived BrC molecules and the construction of an enhanced model for the simulation of radiative forcing. This review will improve our understanding of the climatic and environmental effects of BrC. (C) 2018 Elsevier B.V. All rights reserved.

We carried out an analysis of black carbon (BC) surface mass concentration, its radiative effects, and sources of origin in an urban atmosphere in east India, during winter season, through ground-based measurements and application of modelling tools. BC surface mass concentration exhibited diurnal variation with their higher values and a larger variability during evening to early morning hours than during daytime (1100-1600 h, Local Time, LT) hours. Daytime mean surface BC mass concentration and BC mass fraction in total aerosol (size range 0.23-20 mu m) and in submicronic aerosol (size range 0.23-1 mu m) during the study period, corresponding to the well-mixed atmospheric layer were 11 mu g m(-3), 3-10%, and 9-16% respectively. The mean BC optical depth (BC-ADD) and BC-AOD fraction at 0.5 mu m were estimated in an optical model as 0.11 and 13% respectively. Mean shortwave aerosol radiative forcing due to BC at top-of-atmosphere (TOA) during the study period was found to be +0.94 W m(-2), which is about 59% the global mean radiative forcing due to carbon-dioxide gases. Estimates from BC simulations in a general circulation model showed BC surface concentration and BC optical depth in east India are primarily attributed to emissions from biofuel and fossil fuel combustion. Most of BC surface concentration (95%) and BC optical depth (60%) are contributed by emissions arising from the Indo-Gangetic plain (IGP) but there is a significant influence to BC columnar loading through elevated transport channels attributed mainly to emissions from open biomass burning from distant regions outside IGP. (C) 2012 Elsevier Ltd. All rights reserved.