Arundo donax (giant reed or giant cane) is a widely available, perennial, invasive, non-food crop, present worldwide and employed for several uses, including building practices. Considering the increasing demand for sustainable building materials, A. donax can be an efficient solution. This study investigated its properties as a bio-aggregate mixed with a sodium silicate solution as an adhesive. A horizontal analysis that provided a general characterization of the composite was carried out. The results showed that the A. donax-based composite had an apparent density of 517 kg/m3, thermal conductivity of 0.128 W/(m.K), and high hygroscopicity, with a moisture buffering value of 4.33 g/(m2 %RH), property that could be both an advantage for indoor comfort and a drawback. The uncommon sound absorption behaviour can be comparable to granular materials, with the highest sound absorption coefficient values, alpha, between 600 Hz and 700 Hz. Due to the range and the shape of the acoustic absorption property, this material may be helpful in acoustic treatments for speech noise. The me-chanical tests defined flexural and compressive strength, respectively, 0.35 N/mm2 and 0.9 N/mm2, ensuring applicability. Above all, these tests opened new possible solutions for A. donax-based composite production either alone or in combination with other agro-industrial wastes and justified further tests, such as fire resistance and bio-susceptibility.

Soot particles released in the atmosphere have long been investigated for their ability to affect the radiative forcing. Although freshly emitted soot particles are generally considered to yield only positive contributions to the radiative forcing, atmospheric aging can activate them into efficient cloud condensation or ice nuclei, which can trigger the formation of persistent clouds and ultimately provide a negative contribution to the radiative forcing. Depending on their residence time in the atmosphere, soot particles can undergo several physical and chemical aging processes that affect their chemical composition, particle size distribution and morphology, and ultimately their optical and hygroscopic properties. The impact of the physical-chemical aging on the properties of soot particles is still difficult to quantify, as well as their effect on the radiative forcing of the atmosphere.This work investigates the hygroscopic properties of chemically aged soot particles obtained from the combustion of aviation fuel, and in particular the interplay between aging mechanisms initiated by two widespread atmospheric oxidizers (O-3 and SO2). Activation is measured in water supersaturation conditions using a cloud condensation nuclei counter. Once particle morphology and size distribution are taken into account, the hygroscopicity parameter kappa is derived using kappa-K & ouml;hler theory and correlated to the change of the chemical composition of the particles aged in a simulation chamber. While fresh soot particles are poor cloud condensation nuclei (kappa < 10(-4)) and are not significantly affected by either O-3 or SO2 at the timescale of the experiments, rapid activation is observed when they are simultaneously exposed to both oxidizers. Activated particles become efficient cloud condensation nuclei, comparable to the highly hygroscopic particulate matter typically found in the atmosphere (kappa = 0.2-0.6 at RH = 20 %). Statistical analysis reveals a correlation between the activation and sulfur-containing ions detected on the chemically aged particles that are absent from the fresh particles.

The present work investigates the feasibility of producing boards, with unconventional materials, namely hazelnut shells as a high-mass bio-aggregate and a sodium silicate solution as a no-toxic adhesive, and discusses possible applications based on an extensive characterization. The aim is to define a feasible reuse of a largely produced agro-industrial by-product to reduce the high environmental impact caused by both the construction and the agriculture sectors, by proposing a building composite that improves indoor comfort. The presented combination of aggregate-adhesive generated a product with characteristics interesting to explore. The thermal conductivity is moderated, and the composite achieved values of sigma max = 0.39 N/mm2 for flexural strength and sigma max = 2.1 N/mm2 for compressive strength, but it showed high sorption capacity with a moisture buffering value of about 3.45 g/(m2 %RH), and a peak of sound absorption between 700 and 900 Hz. Therefore, the boards' most promising performance parameters seem to be their high hygroscopicity and acoustic absorption behaviour, namely in the frequency range of the human voice. Hence, the proposed composite could improve indoor comfort if applied as an internal coating board.

Both the effects of aerosol hygroscopicity and mixing state on aerosol optical properties were analyzed using ground-based measurements and a Mie model in this study. The sized-resolved particle hygroscopic growth factor at RH = 90% (Gf(90%)) and the enhancement factor for the scattering coefficients (f(RH)(sp)) were measured by a self-constructed Hygroscopic Tandem Differential Mobility Analyzer (H-TDMA) and two nephelometers in parallel (PNEPs) respectively from 22nd February to 18th March 2014 in the Pearl River Delta, China. In addition, the particle number size distribution (PNSD) and BC mass concentration (M-BC) were measured simultaneously. During the observation period, the f(RH)(sp) increased sharply along with increasing RH (40%-85%) and the value of f(80%)(sp) was 1.77 +/- 0.18. The mean Gf(90%) for all particles are 1.44 (80 nm), 1.48 (110 nm), 1.52 (150 nm) and 1.55 (200 nm), and the mean Gf(90%) for more-hygroscopic particles are 1.58 (80 nm), 1.63 (110 nm), 1.66 (150 nm) and 1.67 (200 nm) respectively. Based on Gf, PNSD and M-BC, the enhancement factor of the aerosol optical properties (extinction (f(RH)(ep)), scattering (f(RH)(sp)), backscattering (f(RH)(hbsp)), absorption (f(RH)(absp)), and hemispheric backscatter fraction (f(RH)(hbsp))) were calculated under three aerosol mixing state assumptions. The results show that the calculated f(80%)(sp) values agreed well with the ones measured by PNEPs, illustrating that the Gf size distribution fittings are reasonable. The f(RH)(ep), f(RH)(sp) and f(RH)(hbsp) increased along with increasing RH for three mixtures, while f(RH)(HBF) decreased. The f(RH)(absp) increased for the homogenously internal mixture, but remained stable for the external mixture. For the core-shell mixture, the f(RH)(absp) increased from RH = 0 to 75% and then decreased, due to a decrease of light entering the BC core. The enhancement factor of aerosol direct radiative forcing (f(RH)(Fr)) increased sharply as the RH elevated for the external mixing state.However, f(RH)(Fr) increased or decreased along with the elevated RH for the homogenously internal mixture and the core-shell mixture depending on initial value of the aerosol direct radiative forcing (Delta F-r) in a dry condition. (C) 2018 Elsevier B.V. All rights reserved.

In this study, the influences of water solubility and light absorption on the optical properties of organic aerosols were investigated. A size-resolved model for calculating optical properties was developed by combining thermodynamic hygroscopic growth and aerosol dynamics models. The internal mixtures based on the homogeneous and core shell mixing were compared. The results showed that the radiative forcing (RF) of Water Soluble Organic Carbon (WSOC) aerosol can be estimated to range from -0.07 to -0.49 W/m(2) for core shell mixing and from -0.09 to -0.47 W/m(2) for homogeneous mixing under the simulation conditions (RH = 60%). The light absorption properties of WSOC showed the mass absorption efficiency (MAE) of WSOC can be estimated 0.43-0.5 m(2)/g, which accounts for 5-10% of the MAE of elemental carbon (EC). The effect on MAE of increasing the imaginary refractive index of WSOC was also calculated, and it was found that increasing the imaginary refractive index by 0.001i enhanced WSOC aerosol absorption by approximately 0.02 m(2)/g. Finally, the sensitivity test results revealed that changes in the fine mode fraction (FMF) and in the geometric mean diameter of the acthmulation mode play important roles in estimating RF during hygroscopic growth. (C) 2015 Elsevier Ltd. All rights reserved.