Large-scale wildfires are essential sources of black carbon (BC) and brown carbon (BrC), affecting aerosol-induced radiative forcing. This study investigated the impact of two wildfire plumes (Plume 1 and 2) transported to Moscow on the optical properties of BC and BrC during August 2022. During the wildfires, the total light absorption at 370 nm (b(abs_370nm)) increased 2.3-3.4 times relative to background (17.30 +/- 13.98 Mm(-)(1)), and the BrC contribution to total absorption increased from 14 % to 42-48 %. BrC was further partitioned into primary (BrCPri) and secondary (BrCSec) components. Biomass burning accounted for similar to 83-90 % of BrCPri during the wildfires. The b(abs_370nm) of BrCPri increased 5.6 times in Plume 1 and 11.5 times in Plume 2, due to the higher prevalence of peat combustion in Plume 2. b(abs_370nm) of BrCSec increased 8.3-9.6 times, driven by aqueous-phase processing, as evidenced by strong correlations between aerosol liquid water content and b(abs_370nm) of BrCSec. Daytime b(abs_370nm) of BrCSec increased 7.6 times in Plume 1 but only 3.6 times in Plume 2, due to more extensive photobleaching, as indicated by negative correlations with oxidant concentrations and longer transport times. The radiative forcing of BrCPri relative to BC increased 1.8 times in Plume 1 and Plume 2. In contrast, this increase for BrCSec was 3.4 times in Plume 1 but only 2.3 times in Plume 2, due to differences in chemical processes, which may result in higher uncertainty in its radiative forcing. Future work should prioritize elucidating both the emissions and atmospheric processes to better quantify wildfire-derived BrC and its radiative forcing.

Soil organic matter (SOM) stability in Arctic soils is a key factor influencing carbon sequestration and greenhouse gas emissions, particularly in the context of climate change. Despite numerous studies on carbon stocks in the Arctic, a significant knowledge gap remains regarding the mechanisms of SOM stabilization and their impact on the quantity and quality of SOM across different tundra vegetation types. The main aim of this study was to determine SOM characteristics in surface horizons of permafrost-affected soils covered with different tundra vegetation types (pioneer tundra, arctic meadow, moss tundra, and heath tundra) in the central part of Spitsbergen (Svalbard). Physical fractionation was used to separate SOM into POM (particulate organic matter) and MAOM (mineral-associated organic matter) fractions, while particle-size fractionation was applied to evaluate SOM distribution and composition in sand, silt, and clay fractions. The results indicate that in topsoils under heath tundra POM fractions dominate the carbon and nitrogen pools, whereas in pioneer tundra topsoils, the majority of the carbon and nitrogen are stored in MAOM fractions. Moreover, a substantial proportion of SOM is occluded within macro-and microaggregates. Furthermore, the results obtained from FTIR analysis revealed substantial differences in the chemical properties of individual soil fractions, both concerning the degree of occlusion in aggregates and across particle size fractions. This study provides clear evidence that tundra vegetation types significantly influence both the spatial distribution and chemical composition of SOM in the topsoils of central Spitsbergen.

Slope failures resulting from thaw slumps in permafrost regions, have developed widely under the influence of climate change and engineering activities. The shear strength at the interface between the active layer and permafrost (IBALP) at maximum thawing depth is a critical factor to evaluate stability of permafrost slopes. Traditional direct shear, triaxial shear, and large-scale in-situ shear experiments are unsuitable for measuring the shear strength parameter of the IBALP. Based on the characteristics of thaw slumps in permafrost regions, this study proposes a novel test method of self-weight direct shear instrument (SWDSI), and its principle, structure, measurement system and test steps are described in detail. The shear strength of the IBALP under maximum thaw depth conditions is measured using this method. The results show that under the condition that the permafrost layer is thick underground ice and the active layer consists of silty clay with 20% water content, the test results are in good agreement with the results of field large-scale direct shear tests and are in accordance with previous understandings and natural laws. The above analysis indicates that the method of the SWDSI has a reliable theoretical basis and reasonable experimental procedures, and meets the needs of stability assessment of thaw slumps in permafrost regions. The experimental data obtained provide important parameter support for the evaluation of related geological hazards.

Widespread dieback of natural Mongolian pine (Pinus sylvestris var. mongolica) forests in Hulunbuir sandy land since 2018 has raised concerns about their sustainability in afforestation programs. We hypothesized that this dieback is driven by two interrelated mechanisms: (1) anthropogenic fire suppression disrupting natural fire regime, and (2) climate change-induced winter warming reducing snow cover duration and depth. To test these, we quantified dieback using Green Normalized Difference Vegetation Index (GNDVI) across stands with varying fire histories via UAV-based multispectral imagery, alongside long-term climatic observations (1960-2024) of temperature, precipitation, and snow dynamics from meteorological stations combined with remote sensing datasets. Results showed that an abrupt change point in 2018 for both annual precipitation and mean temperature was identified, coinciding with dieback. Significant negative linear relationship between GNDVI (forest health) and last fire interval indicated prolonged fire exclusion exacerbating dieback, possibly via pathogen/pest accumulation. Winter temperature rose significantly during 1960-2023, with notable acceleration following abrupt change point in 1987. Concurrently, winters during 2018-2023 exhibited pronounced warming, with snow cover duration reduced by 23 days and snow depth diminished by 7.6 cm. These conditions reduced snowmelt -derived soil moisture (critical water source) recharge in early spring, exacerbating drought stress during critical growth periods and predisposing trees to pest and disease infestations. Our results support both hypotheses, demonstrating that dieback is synergistically driven by fire regime alteration and climate-mediated snowpack reductions. Converting pure pine forests into mixed pine-broadleaf forests via differentiated water sources was proposed to restore ecological resilience in sandy ecosystems.

Human disturbance in the Arctic is increasing. Abrupt changes in vegetation may be expected, especially when spots without vegetation are made available; additionally, climate change alters competition between species. We studied whether 34- to 35-year-old seismic operations had left imprints on local vegetation and whether changes could be related to different soil characteristics. The study took place in Jameson Land in central east Greenland where winter seismic operations in search of oil took place from 1985 to 1989. This area is dominated by continuous dwarf shrub heath with Cassiope tetragona, Betula nana, and Vaccinium uliginosum as dominant species. Using point frame analyses, we registered vascular plants and other surface types in frames along 10-m transects in vehicle tracks (hereafter damages) and in undisturbed vegetation parallel to the track (hereafter references) at eleven study sites. We also measured temperature and pH and took soil samples for analysis. Damaged and reference vegetation types were compared with S & oslash;rensen similarity indices and detrended correspondence analyses. Although most vascular plant species were equally present in damaged vegetation and in references the detrended correspondence analyses showed that at ten out of eleven study sites the damages and references still differed from each other. Graminoids and the herb Polygonum viviparum had the highest occurrence in damages. Shrubs and the graminoid Kobresia myosuroides had the highest occurrence in references. Cassiope tetragona was negatively impacted where vehicles had compacted the snow. Moss, organic crust or biocrust, soil, and sand occurred more often in damages than in references, whereas lichens and litter had the highest occurrence in references. The richness of vascular plant species varied between the eleven study sites, but between damages and references the difference was only up to four species. Temperature was the soil parameter with the most significant differences between damages and references. Total recovery of the damaged vegetation will most likely not occur within several decades. The environmental regulations were important to avoid more serious impacts.

Aim Alaska's boreal forest is experiencing increasingly severe fires, droughts, and pest attacks that may destabilize carbon sequestration. Our aim was to understand boreal forest resilience to changing wildfire regimes using remote-sensed datasets validated with ground-truthing (GT).Location Five recently burned boreal forest sites (2010-2019) near Fairbanks, Alaska.Methods We used four AVIRIS-NG hyperspectral image datasets (425 spectral bands at 5-nm intervals; 3.5 x 43 km average swath) imaged by NASA in 2017-2018 during the Arctic-Boreal Vulnerability Experiment (ABoVE). Spectral analysis included fire fuel loads and random forest (RF) models constructed from key bands to describe common pre- and postburned vegetation classes. Models were validated with 89 GT plots inside the AVIRIS scenes. GT included tree stem densities, understory cover, soil characteristics, radial growth of 51 spruce trees from cores, and visual damage assays of 668 conifers and deciduous trees.Results Spectral evidence of high fuel loads in 2017 pre-dated a 2019 wildfire. Post-GT local models described vegetation more accurately than pre-GT, but accuracy decreased when spectral rulesets were broadened to increase overall classification. Soil temperature, basal area, slope, elevation, and tree density varied widely; thaw depth, soil moisture, moss cover, and canopy height varied mainly by vegetation class. Invasive species and thermokarst were insignificant. Deciduous seedlings were abundant in postburned sites; however, conifer seedling densities were similar to unburned forest. Upland spruce radial growth showed earlier drought sensitivity than lowland spruce.Conclusion Spectral analysis revealed fire vulnerability in some areas; however, local and temporal spectral variation presented challenges to accurately classify vegetation in AVIRIS scenes. GT suggests that recovering forests near Fairbanks may lack sufficient conifer recruitment to replace existing stands. Sites with stable seasonal thaw may offset drought stress under global warming.

BackgroundAccelerated glacial retreat driven by climate change is rapidly reshaping alpine and polar environments, exposing deglaciated terrains that serve as critical sites for microbial colonization and early ecosystem development. These newly exposed substrates provide a unique setting for studying primary microbial succession, the onset of soil formation, and the initiation of biogeochemical cycles, particularly carbon cycling. Microbial communities, including bacteria, archaea, fungi, algae, and viruses, play pivotal roles in regulating elemental fluxes and establishing foundational ecosystem processes in these nascent landscapes.ResultsRecent studies highlight substantial shifts in microbial community structure and function across different glacial forefields and cryospheric habitats. Microbial assemblages display pronounced spatial heterogeneity shaped by physicochemical gradients and successional age. Functional analyses reveal diverse metabolic pathways involved in carbon fixation, organic matter transformation, and long-term carbon storage. Additionally, viral populations emerge as influential regulators of microbial metabolism and potential archives of past environmental conditions. The assembly of these communities is influenced by a combination of abiotic factors, dispersal mechanisms, and local adaptation, with cascading effects on carbon fluxes and nutrient dynamics.ConclusionsMicrobial processes in deglaciated environments are central to early biogeochemical transformations and represent key drivers of carbon sequestration in retreating glacial landscapes. Understanding the ecological roles, functional diversity, and climate sensitivity of these microbial communities is essential for projecting biogeochemical and climate system feedbacks in the context of ongoing glacial loss. Integrating microbial ecology into Earth system models will enhance predictions of carbon dynamics and inform conservation and climate mitigation strategies in polar and alpine regions.

Central and Eastern European geography, shaped by its entanglement of natural and social sciences, provides a distinctive lens for rethinking the unity of the discipline. Its historical and institutional hybridity makes the region particularly well positioned to foster integrative geographical perspectives. The objective of this study was to evaluate the present, post-transitional state of the discipline in Central and Eastern Europe (CEE), to identify its future trajectory and to uncover the significant role of CEE geography in addressing global environmental, social and economic challenges. To facilitate this process, four significant geographical topics have been identified as potentially providing a conducive environment for the partial reintegration of geography. The aforementioned themes encompass a range of topics, including migrations, the green transition, anthropogenic climate change, global tipping points, wetland disturbance, peatland carbon sequestration and cryosphere degradation. Furthermore, we have sought to assess the perspective and significance of geographical unity in addressing global crises that impact human life on Earth. This analysis has enabled the identification of critical issues that necessitate integrated approaches. The necessity for enhanced collaboration between physical and human geography, as well as between nature studies and social and economic explorations, is emphasised. In this regard, it is acknowledged that a more inclusive approach is employed in the field of CEE geography, with contributions from other disciplines such as biology, ecology, physics, sociology and economics being welcomed. These disciplines address processes that span from local to global scales, as well as those that study long-term phenomena, such as history and archaeology. The establishment of robust interdisciplinary networks has the potential to enhance the scientific standing of integrated geography and to strengthen innovative connections between human and physical geography.

An analytical methodology was developed for the first time in this work enabling the simultaneous enantiomeric separation of the fungicide fenpropidin and its acid metabolite by Capillary Electrophoresis. A dual cyclodextrin system consisting of 4 % (w/v) captisol with 10 mM methyl-beta-cyclodextrin was employed in a 100 mM sodium acetate buffer at pH 4.0. Optimal experimental conditions (temperature 25 degrees C, separation voltage -25 kV, and hydrodynamic injection of 50 mbar x 10 s) allowed the simultaneous separation of the four enantiomers in <10.7 min with resolutions of 3.1 (fenpropidin) and 3.2 (its acid metabolite). Analytical characteristics of the method were evaluated and found adequate for the quantification of both chiral compounds with a linearity range from 0.75 to 70 mg L-1, good accuracy (trueness included 100 % recovery, precision with RSD<6 %), and limits of detection and quantification of 0.25 and 0.75 mg L-1, respectively, for the four enantiomers. No significant differences were found between the concentrations determined and labelled of fenpropidin in a commercial agrochemical formulation. The stability over time (0-42 days) of fenpropidin enantiomers using the commercial agrochemical formulation was evaluated in two sugar beet soils, revealing to be stable at any time in one sample, while in the other a decrease of 45 % was observed after 42 days. Individual and combined toxicity of fenpropidin and its metabolite was determined for the first time for marine organism Vibrio fischeri, demonstrating higher damage caused by parent compound. Synergistics and antagonists' interactions were observed at low and high effects levels of contaminants.

Understanding changes in water balance and land-atmosphere interaction under climate change is crucial for managing water resources in alpine regions, especially in the Qinghai-Tibet Plateau (QTP). Evapotranspiration (ET), a key process in the land-atmosphere interaction, is influenced by permafrost degradation. As the active layer in permafrost regions deepens due to climate warming, the resulting shifts in surface hydrologic connectivity and water storage capacity affect vegetation's ability to access water, thereby influencing its growth and regulating ET dynamics, though the full complexity of this process remains unclear. This study employs the Budyko-Fu model to assess the spatiotemporal dynamics of ET and the ET ratio (the ratio of ET to precipitation) on the QTP from 1980 to 2100. While ET shows a continuous upward trend, the ET ratio exhibits a non-monotonic pattern, increasing initially and then decreasing. More than two-thirds of permafrost areas on the QTP surpassed the critical ET ratio threshold by 2023, under three emission scenarios. By 2100, nearly all areas are projected to reach the tipping point, with 97 % affected under the SSP5-8.5 scenario. Meadow and steppe regions are expected to encounter this threshold earlier, whereas forested areas will be less affected, with over 80 % unlikely to reach the tipping point by 2100. Basin-level differences are notable: nearly 90 % of the Qaidam basin exceeded the threshold before 2023, compared to less than 50 % in the Yangtze basin. By 2100, more than 80 % of regions in all basins are expected to cross the tipping point due to ongoing permafrost degradation. This study advances understanding of land-atmosphere interactions in alpine regions, providing critical insights for water resource management and improving extreme weather predictions.