The environmental threat, pollution and damage posed by heavy metals to air, water, and soil emphasize the critical need for effective remediation strategies. This review mainly focuses on microbial electrochemical technologies (MET) for treating heavy metal pollutants, specifically includes Chromium (Cr), Copper (Cu), Zinc (Zn), Cadmium (Cd), Lead (Pb), Nickel (Ni), and Cobalt (Co). First, it explores the mechanisms and current applications of MET in heavy metal treatments in detail. Second, it systematically summarizes the key microbial communities involved, analyzing their extracellular electron transfer (EET) processes and summarizing strategies to enhance the EET efficiencies. Next, the review also highlights the synergistic microbial interactions in bioelectrochemical systems (BES) during the recovery and removal (remediation) processes of heavy metals, underscoring the crucial role of microorganisms in the transfer of the electrons. Then, this paper discussed how factors including pH values, applied voltages, types and concentrations of electron donors, electrode materials, biofilm thickness and other factors affect the treatment efficiencies of some specific metals in BES. BES has shown its great superiority in treating heavy metals. For example, for the treatments of Cr6+, under low pH conditions, the recovery and removal rate of Cr-6(+) by double chambers microbial fuel cell (DCMFC) can generally reach 98-99%, with some cases even achieving 100% (Gangadharan & Nambi, 2015). For the treatments of heavy metal ions such as Cu2+, Zn2+ and Cd2+, BES can also achieve the rates of treatments of more than 90% under the corresponding conditions of appropriate pH values and applied voltages(Choi, Hu, & Lim, 2014; W. Teng, G. Liu, H. Luo, R. Zhang, & Y. Xiang, 2016; Y. N. Wu et al., 2019; Y. N. Wu et al., 2018). After that, the review outlines the future challenges and the research opportunities for understanding the mechanisms of BES and microbial EET in heavy metal treatments. Finally, the prospect of future BES researches are pointed out, including the combinations with existing wastewater treatment systems, the integrations with the wind energy and the solar energy, and the application of machine learning (ML) in future BES. This article has certain significance and value for readers to better understand the working principles of BES and better operate and control BES to deal with heavy metal pollutants.
Background: With growing concern during the COVID-19 pandemic, indoor environmental quality has received significant attention. Radon, a radioactive gas produced from the decay of radium found in soil, rocks, and building materials, can accumulate indoors, posing serious health risks such as lung cancer. University environments, where occupants spend significant time indoors, are particularly susceptible to prolonged radon exposure. Method: This study focused on the estimation of indoor radon concentrations from multiple university buildings in Shanghai. A field investigation was conducted between June 2020 and August 2022. Continuous radon measurements were conducted in the dormitories and classroom buildings. Environmental factors include indoor air temperature and relative humidity. Results: Radon concentrations were influenced by season, floor level, and measurement period, with the highest concentrations recorded during summer and on lower floors due to reduced ventilation. The mean radon concentration in dormitories was 14.8 +/- 9.2 Bq/m3, and in classrooms 12.6 +/- 6.7 Bq/m3, both below national safety limits and lower than those in the pre-pandemic era. Seasonal effect, floor level, and time of measurement were the significant factors for indoor radon concentrations. Conclusion: This study has identified the main factors that affect indoor radon concentration in university campus. The radon concentrations at the lower floor levels remain the highest in the building. The results provide evidence for conducting refined radon monitoring and risk assessment in campus environment, especially during the summer.
In this essay, by summarizing the research progress and achievements of various scholars at home and abroad in recent years on the material properties and corrosion resistance of magnesium phosphate cement (MPC), we review the factors influencing on the properties of MPC, and analyze the effects of raw materials, retarders, and admixtures on the properties of MPC. Two different hydration mechanisms of MPC are discussed, and finally the research progress of MPC in the field of anti-corrosion coatings for steel and ordinary concrete (OPC) is highlighted, and suggestions and prospects are given.
Covered sinkhole, due to its hidden, uncertain, and sudden characteristics, often becomes a key and difficult issue in the prevention and control of karst geological disasters. This paper takes the sinkhole in Yaoshan Huamu Farm, Guilin City as an engineering case, and uses field investigation, indoor and outdoor experiments, and theoretical analysis to systematically analyze the main patterns, influencing factors, and evolution laws of sinkhole. The results show that: (1) High-density resistivity tests show that there are many significant low-resistance anomalies at different locations and depths in the study area, indicating that karst fissures are developed in the study area. This is the basic condition for the occurrence of sinkhole. (2) Drilling results show that the groundwater level in the study area is shallow and groundwater is abundant. Groundwater changes the state and strength of the soil, or dissolves the mineral components of the soil layer and dissolves and transports the soil particle aggregates through subsurface erosion and seepage. Therefore, groundwater destroys the soil structure, resulting in the formation of soil caves or sinkholes. (3) Rainfall monitoring shows that the rainy season from May to July each year provides abundant groundwater for the karst area and changes the physical and mechanical properties of the rock and soil mass; while the small rainfall peak around November may trigger the occurrence of sinkhole through mechanisms such as groundwater level fluctuations and enhanced seepage. (4) The vibrations caused by long-term pumping irrigation, surface water leakage, and planting activities in the study area provide important external dynamic conditions for sinkhole. This study can provide theoretical basis and technical support for the prevention and control of collapse disasters in karst areas.
In recent years, prestressed pipe piles have been widely used in the reinforcement of soft soil foundation, and there will be obvious soil squeezing effect in the construction of pipe piles. However, the research on the soil squeezing effect of pipe piles under various influencing factors is not clear, and it is difficult to guide the actual construction on site. In this paper, the evolution mechanism of soil squeezing effect, pile-soil deformation characteristics and bearing characteristics in the process of pile sinking are analyzed in depth by means of field monitoring and laboratory test. Combined with visual model test, the distribution law of soil displacement field is clarified, and the effects of various influencing factors such as changing pile spacing and pile sinking sequence are revealed. The results show that the soil deformation caused by pile sinking increases first and then decreases in depth, and the soil deformation decreases exponentially in the horizontal direction. The width of the shear strain zone does not change with the increase of penetration, that is, the influence of the squeezing effect on the adjacent pile is mainly rotation and translation. For double piles, the expansion trend of the inner side of the two piles is smaller than that of the outer side of the pile. The squeezing effect will cause the adjacent pile to move and rotate. When the subsequent pile penetration is completed, the displacement field is no longer a basically symmetrical state, and the influence range in the depth area increases. When the pile spacing is set to more than 4 times the pile diameter, the synergistic bearing capacity of the pile group can be better played; The construction sequence from near to far is preferentially selected during construction, which can effectively reduce the impact on adjacent structures. The research results of this paper can provide a reference for further solving the disposal problem of composite foundation reinforced by pipe pile group.
To alleviate problems in urban living environments, an increasing number of shield tunnels have been built that go through rivers or underwater areas. Most of these tunnels experience leakage after a long period of operation, which can impact the safety of the tunnel and induce dangerous accidents, resulting in a loss of life and property. This paper reports the leakage characteristics during operation of a double-line ultralarge-diameter underwater shield tunnel that crosses the Yangtze River. After detailed geological surveys and field inspections of the prototype tunnel, the leakage characteristics and patterns of the tunnel were summarized based on long-term monitoring data. The distribution of leak-related defects was described in-depth with sketches and field photographs. Factors influencing the leakage of the prototype tunnel (i.e., the groundwater table, longitudinal settlement, and soil conditions) were interpreted based on field measurements. The mechanisms that triggered two typical leakage accidents that occurred during tunnel operation were systematically analyzed. The leakage mechanisms of the prototype tunnel were subsequently categorized into three patterns: joint leakage, bolt hole leakage and concrete crack leakage. Four countermeasures against leakage were proposed considering the leakage-associated damage to the prototype tunnel: backfill grouting, joint grouting, installation of a bolt hole sealing cover, and caulking gasket addition. The proposed mitigation measures were validated through laboratory tests and field applications. This unique tunnel prototype engineering case can provide a reference for water leakage prevention and control in the design, construction, and operation stages of similar underwater shield tunnel projects.
In Northeast China, permafrost is controlled by a combination of biotic, climatic, physiographic, and anthropogenic factors. Due to the complexity of these governing or influencing factors, it is challenging to exactly describe the features of the Xing'an permafrost in Northeast China. By integrating remote sensing (RS) and geographic information system (GIS) technologies, we have quantified these influencing factors of permafrost changes as an important approach to understanding the nature of latitudinal and mountain permafrost in Northeast China at the mid-latitudes in the Northern Hemisphere. In this study, we combine Geographical Detector (Geodetector) model, trend analysis, and multi-source RS data to quantify the controlling or influencing factors of permafrost thermal state and of permafrost changes, and explain the interactions among permafrost, environment, and climate. The results indicate that, at the regional scale, changes in the thermal state of permafrost are primarily governed or influenced by mean annual land surface temperature (MALST), precipitation, and snow cover duration (SCD). Topographic factors also affect the spatial patterns of permafrost development. Additionally, in the context of climate warming, the insulation effect of snow cover on the permafrost is weakened, or has been weakening. Moreover, the interactive effects among various factors significantly enhance their explanatory power for changes in the thermal state of permafrost. The study emphasizes the complexity of the interactions among permafrost, climate, and the environment, and highlights the significance of understanding these interactions for regional socio-economic development, ecological management, carbon pool stabilization, and research on future climate change in Northeast China.
Cut-fill interfaces within the loess subgrade tend to form potential failure surfaces, controlling the mechanical properties of cut-fill engineering. Focusing on the cut-fill interface, extensive laboratory tests in this research show the performance of interfacial mechanical properties under various test conditions, revealing interface effects and exploring the impact of different factors on these effects. The results indicate that the interface strengthens the friction angle of soil but weakens cohesion, especially impacting the cohesion, thereby reducing the shear strength of soil. The increase in dry density diminishes the enhancement effect on friction angle caused by the interface while amplifying the degradation effect on cohesion. Elevated water content has a weak influence on the enhancement effect of friction angle but diminishes the degradation effect of cohesion. Load doesn't change the impact of dry density on the interface effect but amplifies the impact of water content. The impact of various factors on interfacial shear strength manifests as follows: load > average dry density > water content. The interaction among these factors demonstrates average dry density + load > water content + load > average dry density + water content. The study indicates that the construction of loess subgrades based on the standard of maximum dry density and optimum water content may not align with the conditions required for achieving optimal stability at the cut-fill interface. These research findings reveal the crucial role of various factors in comprehensive impact of interfacial effect, offering essential support for ensuring the stability of cut-fill interfaces.
Gully erosion damages land resources and endangers human productivity and life, making it a key issue in global research on soil erosion nowadays. Gully headcut retreat (GHR) is the main form of gully erosion. Tiny concave features can be found in many retreating gully heads worldwide, and they are referred to as niche terrain in this study. To investigate the association between niche terrain and GHR, relevant research was reviewed on niches and stability analysis of gully heads with niches was modelled and analysed. Studies have shown that not all niches worldwide are identical due to regional differences in internal material-external environmental conditions. Special soil properties, joints, and cracks are the internal material conditions that lead to the formation of niche. External conditions include climate conditions, vegetation conditions, and topography. Water is the driving force for the formation of niche, while vegetation and topography are key factors. Niches can be regarded as the initial stage of GHR in areas where gully erosion is intense. In general, GHR is a composite cyclical process dominated by hydraulic erosion in the early stage and gravitational erosion in the late stage, including niche formation, inward concave formation, free face formation, overhanging soil collapse, and niche reformation. In this study, a model of gully head stability is applied, and it is found that the stability-based factor of safety decreases exponentially with increasing niche height and crack depth, increases exponentially with increasing niche angle, and decreases quadratically with increasing catchment slope. Summarizing the common characteristics of niche terrains worldwide can facilitate the study of the evolution of gully erosion globally. Niches can be regarded as the initial stage of gully head retreat. The mechanism of niches varies with regional internal material-external environmental conditions. Gully head retreat is a composite cycle process dominated by early hydraulic erosion and later gravity erosion. image
As a vital freshwater resource for one-sixth of the world's population, snowmelt provides great convenience for residents in terms of livelihood and production, agricultural irrigation, and hydroelectric power generation. However, snowmelt can also have an important impact on the formation of surface runoff and the process of soil erosion. In contrast to glacier melt, snowmelt erosion has received relatively little attention in the past. This paper reviewed the generation of snowmelt runoff, the characteristics of erosion and sediment yield during snowmelt, the snowmelt erosion mechanism, and the applications of snowmelt modeling. The published results of sediment yield driven from snowmelt runoff ranged from 1 to 300 t km-2 a-1, with the largest value of 1114 t km-2 a-1. Snowmelt erosion is extremely sensitive to warming climate. With global warming, there is a trend towards earlier snowmelt periods and a significant increase in runoff volume, as well as a significant increase in sediment yield from snowmelt in most of the study cases. Moreover, snowmelt erosion compared to rainfall erosion has more complex mechanistic processes which can be influenced by various factors such as snowfall, freeze-thaw, topography, etc. In particular, the occurrence of rain-on-snow events will lead to more severe soil erosion. In addition, current studies of sediment yield from snowmelt erosion account for a small percentage of snowmelt, and snowmelt erosion modeling is rarely applied in practical studies. In future research, the field monitoring of snowmelt erosion in the context of climate change needs to be further strengthened and the effects of multiple factors on snowmelt erosion need to be investigated. The inclusion of rain-on-snow and specific erosion types in the model will improve the applicability of models under climate change scenarios and in multiscale environments. This paper is intended to show the achievements as well as the limitations of snowmelt erosion research, while suggesting future research directions that need to be further explored and developed for better understanding and forecasting of snowmelt erosion.