This paper discusses information collected from original articles published between 1992 and 2022 regarding heavy metals (HMs) contamination in various environments across Mexico. The primary aim of this work was to identify the Mexican states where concentrations of HMs have been reported to exceed the maximum permissible limits for several types of soil, water, and sediment according to Mexican standards NOM-147-SEMARNAT/SSA1-2004, NOM-127-SSA1-2021, as well as international standards. The data collected indicates that 25 states in Mexico have reported at least one metal exceeding the maximum permissible limits in soil. Among these, Zacatecas, Nuevo Leon and Chihuahua had the highest number of HMs exceeding the standards. For sediment contamination, 26 states exceeded the permissible limits, with San Luis Potos & iacute; and Guerrero showing the highest number of HMs above the standards. Additionally, 26 states have reports of HMs exceeding the permissible limits in water, with Guanajuato and Guerrero having the highest number of HMs. Interestingly, the most frequent metals reported as soil contaminants are Cu, Fe, Pb and Zn; in sediment, they are Cd, Cr, Cu, Fe, Pb and Zn; and in water, they are Cd, Cr, Cu, Fe, Mn, Pb and Zn. The compiled information indicates that the primary anthropogenic sources of HMs release in Mexico include industrial activities, urban wastewater, mining, and agricultural practices. Furthermore, the data analyzed highlights several serious health risks associated with exposure to HMs, including cancer, central nervous system damage, DNA damage, and issues related to kidneys and lungs. This paper provides a comprehensive overview of HMs contamination in Mexico as well as the health challenges that arise from this contamination..

Cracking of soils associated with subsidence is a complex and multiparametric problem. Local soil conditions could be responsible for the dramatic differential settlements and fissures manifest when the water pumping reduces the volume of the compressible strata. This situation is of extreme importance due to the level of damage to urban infrastructure and buried facilities (gas, water, and drainage) as well as to housing structures. In this research, using a simple geotechnical model of subsidence (finite element method, Mohr-Coulomb criterion) parametric combinations of materials and basement geometry are tested to define the geotechnical settings more susceptible to deformation and derived cracking. These approximations are compared with measurements and field surveys in Mexico City to validate the hypothesis. Defining the zones that are more susceptible to respond with cracking due to the phenomenon of subsidence can be especially important when designing urban development programs, restoration campaigns for buried pipes, even for construction and operation of new pumping wells.

This study investigates the historical variability in annual average precipitation in the northwest region of Mexico, aiming to evaluate the cumulative impact of precipitation on soil degradation and associated risks posed by rainfall. Despite being known as The Agricultural Heart of Mexico, the region's soil has experienced significant damage to its granulometric structure due to unpredictable rainfall patterns attributed to climate change. Sixteen historical series of average annual rainfall were analyzed as stationary stochastic processes for spectral analysis. The results revealed exponential decay curves in each radial spectrum, indicating a linear relationship between frequency and amplitude. These curves identified initial impulses correlated with moments of severity for structural damages caused by rainfall-induced degradation. The degradation process, exacerbated by water stress, accelerates, as evidenced by maps illustrating approximately 75% soil damage. In the context of climate change and the uncertainty surrounding soil responses to extreme meteorological events, understanding this phenomenon becomes crucial. Recognizing the dynamic nature of soil responses to environmental stressors is essential for effective soil management. Emphasizing the need to employ numerical processes tailored to new environmental considerations related to observed soil damages is crucial for sustainable soil management practices in any region.

Black carbon (BC) is a strong radiative forcer. Because of its multiple effects on climate change, BC has been located as the second important impact factor of climate change only after carbon dioxide. Sources of BC include mainly diesel vehicles and biomass burning. Mexico's pledges before the Paris Agreement are, between others, the reduction of BC emissions to up to 51% by 2030 compared with those in 2000. In order to know the exact contribution of BC to the emission inventory of Mexico it is necessary to estimate several BC properties, such as its radiative forcing and its effects on the radiative heating of the atmosphere, among others. In this work, a technique based on the available remote-sensing and ground-based data along with the Optical Properties of Aerosols and Clouds (OPAC) and the Santa Barbara DISORT Atmospheric Radiative Transfer (SBDART) algoritluns were used to estimate black carbon radiative forcing in the south of Mexico City during 2015. Land-based measurements were taken from a recently created monitoring network, the Aerosol Robotic Network (AERONET), and satellite measurements were obtained from the Moderate Resolution Imaging Spectroradiometer) (MODIS). Black carbon monthly concentrations along 2015 were between 1.9 and 4.1 mu g/m(3). Results show that monthly average radiative forcing on the top of the atmosphere over south Mexico City during 2015 was +30.2 +/- 6.2 W/m(2). November, December and January presented the highest radiative forcing values (+34.9. +46.9, +34.0, respectively). In addition, estimates of atmospheric heating show an average annual value of 0.85 +/- 0.22 W/m(2). Values of Angstrom > 1, as obtained in this work, indicate that aerosols are of the urban type and freshly emitted. Also, low single scattering albedo values in increasing wavelengths show that aerosols are mainly from urban-industrial aerosols.

A black carbon (BC) emission inventory for Mexico is presented. Estimate was performed by using two approaches, based on fuel consumption and emission factors in a top-down scheme, and the second from PM25 emission data and its correlation with black carbon by source category, assuming that black carbon = elemental carbon. Results show that black carbon emissions are in interval 53-473 Gg using the fuel consumption approach and between 62 and 89 using the sector method. Black carbon key sources come from biomass burning in the rural sector, with 47 percent share to the National total. Mobile sources emissions account to 16% to the total. An opportunity to reduce, in the short-term, carbon dioxide equivalent (CO2-eq) emissions by reducing black carbon emissions would be obtained in reducing emissions mainly from biomass burning in rural housing sector and diesel emissions in the transport sector with important co-benefits in direct radiative forcing, public health and air quality. (C) 2014 Elsevier B.V. All rights reserved.