Bedrock-soil layer slopes (BSLSs) are widely distributed in nature. The existence of the interface between bedrock and soil layer (IBSL) affects the failure modes of the BSLSs, and the seismic action makes the failure modes more complex. In order to accurately evaluate the safety and its corresponding main failure modes of BSLSs under seismic action, a system reliability method combined with the upper bound limit analysis method and Monte Carlo simulation (MCS) is proposed. Four types of failure modes and their corresponding factors of safety (Fs) were calculated by MATLAB program coding and validated with case in existing literature. The results show that overburden layer soil's strength, the IBSL's strength and geometric characteristic, and seismic action have significant effects on BSLSs' system reliability, failure modes and failure ranges. In addition, as the cohesion of the inclination angle of the IBSL and the horizontal seismic action increase, the failure range of the BSLS gradually approaches the IBSL, which means that the damage range becomes larger. However, with the increase of overburden layer soil's friction angle, IBSL's depth and strength, and vertical seismic actions, the failure range gradually approaches the surface of the BSLS, which means that the failure range becomes smaller.

The reasonable value of good gradation characteristic parameters is key in designing and optimising soil-rock mixed high fill embankment materials. Firstly, the DJSZ-150 dynamic-static large-scale triaxial testing instrument was used for triaxial compression shear tests on compacted skeleton structure soil-rock mixture standard specimens. The changes in strength and deformation indicators under different gradation parameters and confining pressure were analysed. Then, based on the Janbu empirical formula, relationships between parameters K, n, and (sigma 1-sigma 3)ult and the coefficient of uniformity Cu and coefficient of curvature Cc were explored. Empirical fitting formulas for Duncan-Chang model constants a and b were proposed, establishing an improved Duncan-Chang model for soil-rock mixtures considering gradation characteristics and stress states. Finally, based on significant differences in particle spatial distribution caused by gradation changes, three generalised models of matrix-block stone motion from different particle aggregation forms were proposed. Results indicate the standard specimen's strength and deformation indicators exhibit significant gradation effects and stress-state correlations. The improved Duncan-Chang model effectively simulates the stress-strain relationship curve under different gradations and confining pressure, with its characteristics explainable based on the matrix block stone motion generalised model.

Understanding soil organic carbon (SOC) distribution and its environmental controls in permafrost regions is essential for achieving carbon neutrality and mitigating climate change. This study examines the spatial pattern of SOC and its drivers in the Headwater Area of the Yellow River (HAYR), northeastern Qinghai-Xizang Plateau (QXP), a region highly susceptible to permafrost degradation. Field investigations at topsoils of 86 sites over three summers (2021-2023) provided data on SOC, vegetation structure, and soil properties. Moreover, the spatial distribution of key permafrost parameters was simulated: temperature at the top of permafrost (TTOP), active layer thickness (ALT), and maximum seasonal freezing depth (MSFD) using the TTOP model and Stefan Equation. Results reveal a distinct latitudinal SOC gradient (high south, low north), primarily mediated by vegetation structure, soil properties, and permafrost parameters. Vegetation coverage and above-ground biomass showed positive correlation with SOC, while soil bulk density (SBD) exhibited a negative correlation. Climate warming trends resulted in increased ALT and TTOP. Random Forest analysis identified SBD as the most important predictor of SOC variability, which explains 38.20% of the variance, followed by ALT and vegetation coverage. These findings likely enhance the understanding of carbon storage controls in vulnerable alpine permafrost ecosystems and provide insights to mitigate carbon release under climate change.

An analytical methodology was developed for the first time in this work enabling the simultaneous enantiomeric separation of the fungicide fenpropidin and its acid metabolite by Capillary Electrophoresis. A dual cyclodextrin system consisting of 4 % (w/v) captisol with 10 mM methyl-beta-cyclodextrin was employed in a 100 mM sodium acetate buffer at pH 4.0. Optimal experimental conditions (temperature 25 degrees C, separation voltage -25 kV, and hydrodynamic injection of 50 mbar x 10 s) allowed the simultaneous separation of the four enantiomers in <10.7 min with resolutions of 3.1 (fenpropidin) and 3.2 (its acid metabolite). Analytical characteristics of the method were evaluated and found adequate for the quantification of both chiral compounds with a linearity range from 0.75 to 70 mg L-1, good accuracy (trueness included 100 % recovery, precision with RSD<6 %), and limits of detection and quantification of 0.25 and 0.75 mg L-1, respectively, for the four enantiomers. No significant differences were found between the concentrations determined and labelled of fenpropidin in a commercial agrochemical formulation. The stability over time (0-42 days) of fenpropidin enantiomers using the commercial agrochemical formulation was evaluated in two sugar beet soils, revealing to be stable at any time in one sample, while in the other a decrease of 45 % was observed after 42 days. Individual and combined toxicity of fenpropidin and its metabolite was determined for the first time for marine organism Vibrio fischeri, demonstrating higher damage caused by parent compound. Synergistics and antagonists' interactions were observed at low and high effects levels of contaminants.

Earthquakes are common geological disasters, and slopes under seismic loading can trigger coseismic landslides, while also becoming unstable due to accumulated damage caused by the seismic activity. Reinforced soil slopes are widely used as seismic-resistant geotechnical systems. However, traditional geosynthetics cannot sense internal damage in reinforced soil systems, and existing in-situ distributed monitoring technologies are not suitable for seismic conditions, thus limiting accurate post-earthquake stability assessments of slopes. This study presents, for the first time, the use of a batch molding process to fabricate self-sensing piezoelectric geogrids (SPGG) for distributed monitoring of soil behavior under seismic conditions. The SPGG's reinforcement and damage sensing abilities were verified through model experiments. Results show that SPGG significantly enhances soil seismic resistance and can detect soil failure locations through voltage distortions. Additionally, the tensile deformation of the reinforcement material can be quantified with sub-centimeter precision by tracking impedance changes, enabling high-precision distributed monitoring of reinforced soil under seismic conditions. Notably, when integrated with wireless transmission technology, the SPGG-based monitoring system offers a promising solution for real-time monitoring and early warning in road infrastructure, where rapid detection and response to seismic hazards are critical for mitigating catastrophic outcomes.

Root-knot nematodes (RKN) severely reduce watermelon yields worldwide, despite its nutraceutical value. This study investigated the effects of rock dust (RD) and poultry manure (PM) amendments, applied singly or in combination, on RKN suppression and watermelon fruit yield enhancement. A two-trial field experiment was conducted utilizing a randomized complete block design with three replicates. The treatments included RD and PM each applied at 0, 2.5, or 5 t/ha and combined applications of RD and PM at 2.5 or 5 t/ha each. At 60-66 days post-inoculation, root galling and RKN population density were assessed alongside root-shoot weight. The results indicated that root galling in watermelons was reduced by 60-85 % and 67-89 % in the combined RD- and PMtreated plots across the 1st and 2nd trials, respectively, in contrast to the control plots. Likewise, the RKN population was suppressed by 94-99 % in treated plots in both trials, differing from the control plots. Notably, watermelon fruit yield was significantly higher (p < 0.05) in combined RD and PM treated plots, ranging from 24.7 to 33.7 t/ha and 34.6-46.5 t/ha in the 1st and 2nd trials, respectively, compared to control plots with 13.5 t/ha in the 1st trial compared to and 20.9 t/ha yield in the 2nd trial. In conclusion, our study indicates that coapplication of RD and PM effectively reduced RKN damage and enhanced watermelon fruit yield, providing a sustainable strategy for watermelon production.

Char and soot represent distinct types of elemental carbon (EC) with varying sources and physicochemical properties. However, quantitative studies in sources, atmospheric processes and light-absorbing capabilities between them remain scarce, greatly limiting the understanding of EC's climatic and environmental impacts. For in-depth analysis, concentrations, mass absorption efficiency (MAE) and stable carbon isotope were analyzed based on hourly samples collected during winter 2021 in Nanjing, China. Combining measurements, atmospheric transport model and radiative transfer model were employed to quantify the discrepancies between char-EC and soot-EC. The mass concentration ratio of char-EC to soot-EC (R-C/S) was 1.4 +/- 0.6 (mean +/- standard deviation), showing significant dependence on both source types and atmospheric processes. Case studies revealed that lower R-C/S may indicate enhanced fossil fuel contributions, and/or considerable proportions from long-range transport. Char-EC exhibited a stronger light-absorbing capability than soot-EC, as MAE(char) (7.8 +/- 6.7 m(2)g(-1)) was significantly higher than MAE(soot) (5.4 +/- 3.4 m(2)g(-1))(p < 0.001). Notably, MAE(char) was three times higher than MAE(soot) in fossil fuel emissions, while both were comparable in biomass burning emissions. Furthermore, MAE(soot) increased with aging processes, whereas MAE(char) exhibited a more complex trend due to combined effects of changes in coatings and morphology. Simulations of direct radiative forcing (DRF) for five sites indicated that neglecting the char-EC/soot-EC differentiation could cause a 10 % underestimation of EC's DRF, which further limit accurate assessments of regional air pollution and climate effects. This study underscores the necessity for separate parameterization of two types of EC for pollution mitigation and climate change evaluation.

The existence of rock weathering products has an important effect on the infiltration of water in the soil. Understanding the mechanism of water infiltration in a mixed soil and weathered rock debris medium is highly important for soil science and hydrology. The purpose of this study is to explore the effects of mudstone hydrolysis on water infiltration in the soil under different mixing ratios (0-70 %) of weathered mudstone contents. Soil column experiments and numerical modelling were used to study the processes of hydrolysis of weathered mudstone and water infiltration in the mixed medium. The results revealed that water immersion can cause the dense mudstone surface to fall off, thus forming pores, and that the amount of these pores first increase but then decrease over time. The disintegration of post-hydrolysis mudstone debris occurs mainly among particles ranging from 2-2000 mu m, predominantly transforming sand particles into finer fractions. Increasing the mudstone content in the soil from 0 % to 50 % enhances the infiltration rate and cumulative infiltration volume. However, when the mudstone content exceeds 50 %, these parameters decrease. The mudstone weathering products promote water infiltration in the soil within a certain range of mudstone contents, but as the ratio of weathered products increases, excessive amounts of mudstone hinder the movement of water in the soil. The identified transformation phenomenon suggests that the infiltration capacity of mixed soil will not scale linearly with mudstone content. The findings enable some mitigation strategies of geologic hazards based on the hydrological stability in heterogeneous environments.

Moderate-size earthquakes, and the presence of water saturated soil in the near surface can trigger the liquefaction geohazard causing buildings to settle / tilt or collapse, damaging bridges, dams, and roads. A number of paleo-seismic research have focused on the Himalayan area as a potential site for liquefaction. The present study site is in the south of the tectonically active Himalayan foothills and lies in earthquake Seismic Zone III. Therefore, the region can experience earthquakes from nearby regions and can potentially damage civil infrastructures due to liquefaction. The objective of this paper is to determine the susceptibility of alluvial soil deposits to liquefaction for seismic hazard and risk mitigation. Liquefaction geohazard study of alluvial deposits was carried out using shear wave velocity (Vs) profiling. Preliminary assessment of the soil is made by building the average shear wave velocity map up to 30 m depth (Vs30) and by constructing the corrected shear wave velocity (V-s1) maps. It was observed from the Vs30 map that a major portion of the studied area lies in Site Class CD and only a small portion lies in Site Class D. Moreover, it is also noticed from the V(s1 )map that a smaller of the area has V(s1 )lower than the upper limit of V-s1(& lowast; )(215 m/s) below which liquefaction may occur. The region showing lower values of V(s1 )is further examined for liquefaction hazard as per the guidelines given by Andrus et al. (2004). Resistance of the soil to liquefaction, stated as cyclic resistance ratio (CRR), and the magnitude of cyclic loading on the soil induced by the earthquake shaking, stated as cyclic stress ratio (CSR) are computed for the area. Several maps of factor of safety (FS) for different depths are prepared by taking the ratio of CSR and CRR. When FS < 1, the soil is considered prone to liquefaction. Furthermore, susceptibility of soil to liquefaction against different peak horizontal ground surface acceleration (PHGSA) and varying depth of water table is also evaluated in terms of factor of safety. It is observed from this study that for lower levels of PHGSA (up to 0.175 g) the soil can be considered safe. However, the soil becomes more vulnerable to liquefaction when PHGSA is above 0.175 g and with rising water table. The comparison of the factor of safety (FS) obtained using the SPT-N method and the Vs-derived approach shows consistent results, with both methods confirming the absence of liquefaction in the studied soil layers.

In performance-based design, it is crucial to understand deformation characteristics of geocell layers in soil under footing loads. To explore this, a series of laboratory loading tests were carried out to investigate the influence of varying parameters on the strain levels within the geocell layer in a sandy soil under axial strip footing loading. The results were analyzed in terms of maximum strain levels, strain variation along the geocell layer and the correlation between horizontal and vertical strains. In this study, the maximum observed strain levels for geocellreinforced strip footing systems reached 2.3 % for horizontal (tensile) strain and 1.4 % for vertical (compressive) strain. Furthermore, most strain levels were concentrated within a distance of 1.5 times the footing width from the axis of strip footing. In geocell-reinforced footing systems, the interaction between horizontal and vertical strains becomes a key factor, with the ratio of horizontal to vertical cell wall strains ranging approximately from 1 to 2.5. The outcomes of this study are expected to contribute to the practical applications of geocell-reinforced footing systems.