The thermal coupling between the atmosphere and the subsurface on the Qinghai-Tibetan Plateau (QTP) governs permafrost stability, surface energy balance, and ecosystem processes, yet its spatiotemporal dynamics under accelerated warming are poorly understood. This study quantifies soil-atmosphere thermal coupling ((3) at the critical 0.1 m root-zone depth using in-situ data from 99 sites (1980-2020) and a machine learning framework. Results show significantly weaker coupling in permafrost (PF) zones (mean (3 = 0.42) than in seasonal frost (SF) zones (mean (3 = 0.50), confirming the powerful thermal buffering of permafrost. Critically, we find a widespread trend of weakening coupling (decreasing (3) at 66.7 % of sites, a phenomenon most pronounced in SF zones. Our driver analysis reveals that the spatial patterns of (3 are primarily controlled by surface insulation from summer rainfall and soil moisture. The temporal trends, however, are driven by a complex and counter-intuitive interplay. Paradoxically, rapid atmospheric warming is the strongest driver of a strengthening of coupling, likely due to the loss of insulative snow cover, while trends toward wetter conditions drive a weakening of coupling by enhancing surface insulation. Spatially explicit maps derived from our models pinpoint hotspots of accelerated decoupling in the eastern and southern QTP, while also identifying high-elevation PF regions where coupling is strengthening, signaling a loss of protective insulation and increased vulnerability to degradation. These findings highlight a dynamic and non-uniform response of land-atmosphere interactions to climate change, with profound implications for the QTP's cryosphere, hydrology, and ecosystems.

Light-absorbing carbonaceous aerosols, comprising black carbon (BC) and brown carbon (BrC), significantly influence air quality and radiative forcing. Unlike traditional approaches that use a fixed value of absorption & Aring;ngstrom exponent (AAE), this study investigated the absorption and optical properties of carbonaceous aerosols in Beijing for both local emission and regional transport events during a wintertime pollution event by using improved AAE results that employs wavelength-dependent AAE (WDA). By calculating the difference of BC AAE at different wavelengths using Mie theory and comparing the calculated results to actual measurements from an Aethalometer (AE31), a more accurate absorption coefficient of BrC can be derived. Through the analysis of air mass sources, local emission was found dominated the pollution events during this study, accounting for 81 % of all cases, while regional transport played a minor role. Carbonaceous aerosols exhibited a continuous increasing trend during midday, which may be attributed to the re-entrainment of nighttime-accumulated carbonaceous aerosols to the surface during the early planetary boundary layer (PBL) development phase, as the mixed layer rises, combined with the variation of PBL and anthropogenic activity. At night, variations in the PBL height, in addition to anthropogenic activities, effectively contributed to surface aerosol concentrations, leading to peak surface aerosol values during local pollution episodes. The diurnal variation of AAE470/880 exhibited a decreasing trend, with a total decrease of approximately 12 %. Furthermore, the BrC fraction showed a constant diurnal variation, suggesting that the declining AAE470/880 was primarily influenced by BC, possibly due to enhanced traffic contributions.

Conventional materials necessitate a layer-by-layer rolling or tamping process for subgrade backfill projects, which hampers their utility in confined spaces and environments where compaction is challenging. To address this issue, a self-compacting poured solidified mucky soil was prepared. To assess the suitability of this innovative material for subgrade, a suite of performance including flowability, bleeding rate, setting time, unconfined compressive strength (UCS), and deformation modulus were employed as evaluation criteria. The workability and mechanical properties of poured solidified mucky soil were compared. The durability and solidification mechanism were investigated. The results demonstrate that the 28-day UCS of poured solidified mucky soil with 20% curing agent content reaches 2.54 MPa. The increase of organic matter content is not conducive to the solidification process. When the curing temperature is 20 degrees C, the 28-day UCS of the poured solidified mucky soil with curing agent content not less than 12% is greater than 0.8 MPa. The three-dimensional network structure formed with calcium silicate hydrate, calcium aluminate hydrate, and ettringite is the main source of strength formation. The recommended mud moisture content is not exceed 85%, the curing agent content is 16%, and the curing temperature should not be lower than 20 degrees C.

On December 18, 2023, a magnitude MS6.2 earthquake struck Jishishan County, Gansu Province, triggering over 40 seismic subsidence sites within a seismic intensity VI zone, 32 km from the epicenter.The earthquake caused tens of millions in economic losses to mountain photovoltaic power stations. Extensive geological surveys and comparisons with similar landslides (such as soil loosening, widespread cracks, and stepped displacements) triggered by the 1920 Haiyuan MS8.5 earthquake and the 1995 Yongdeng MS5.8 earthquake, this study preliminarily identifies one subsidence sites as a seismic-collapsed loess landslide. To investigate its disaster-causing mechanism: the dynamic triaxial test was conducted to assess the seismic subsidence potential of the loess at the site, and the maximum subsidence amount under different seismic loads were calculated by combining actual data from nearby bedrock stations with site amplification data from the active source; simulation of the destabilization evolution of seismic-collapsed loess landslides by large-scale shaking table tests; and a three-dimensional slope model was developed using finite element method to study the complex seismic conditions responsible for site damage. The research findings provide a theoretical foundation for further investigations into the disaster mechanisms of seismic-collapsed loess landslides.

Taurine (TAU) has recently been found to have an impactful role in regulating plant responses under abiotic stresses. This study presented the comparative effects of TAU seed priming and foliar spray application on chickpea plants exposed to hexavalent chromium. Taurine priming and foliar applications (1.6 and 2.4 mM) notably modulated morpho-physiological and biochemical responses of plants under Cr(VI) stress. Plants subjected to 25 mg kg-1 soil Cr in the form of potassium dichromate (K2Cr2O7) displayed a significant reduction in growth, chlorophyll, and uptake of essential nutrients (N, K, P, and Ca). Cr(VI) toxicity also resulted in a notable increase in osmolyte accumulation, lipid peroxidation, relative membrane permeability, ROS generation, antioxidant enzyme activities, antioxidant compounds, endogenous Cr levels, and aerial Cr translocation. Taurine abridged lipoxygenase activity to diminish lipid peroxidation owing to the overproduction of ROS initiated by a higher Cr content. The acquisition and assimilation of essential nutrients were augmented by the TAU-related decrease in leaf and root Cr levels. Consequently, TAU enhanced growth by mitigating oxidative damage, reducing Cr content in the aerial parts, and reinforcing the activities of antioxidant enzymes. Compared to foliar spray, TAU seed priming has demonstrated superior efficacy in mitigating Cr phytotoxicity in plants.

Bedrock-soil layer slopes (BSLSs) are widely distributed in nature. The existence of the interface between bedrock and soil layer (IBSL) affects the failure modes of the BSLSs, and the seismic action makes the failure modes more complex. In order to accurately evaluate the safety and its corresponding main failure modes of BSLSs under seismic action, a system reliability method combined with the upper bound limit analysis method and Monte Carlo simulation (MCS) is proposed. Four types of failure modes and their corresponding factors of safety (Fs) were calculated by MATLAB program coding and validated with case in existing literature. The results show that overburden layer soil's strength, the IBSL's strength and geometric characteristic, and seismic action have significant effects on BSLSs' system reliability, failure modes and failure ranges. In addition, as the cohesion of the inclination angle of the IBSL and the horizontal seismic action increase, the failure range of the BSLS gradually approaches the IBSL, which means that the damage range becomes larger. However, with the increase of overburden layer soil's friction angle, IBSL's depth and strength, and vertical seismic actions, the failure range gradually approaches the surface of the BSLS, which means that the failure range becomes smaller.

Correlations between the mechanical properties and surface scratch resistance of polylactic acid (PLA) are investigated via tensile and scratch tests on samples after degradation in soil for various times. The results show that the tensile yield strength of PLA is inversely proportional to the natural logarithm of the degradation time, and the scratch resistance and fracture toughness of PLA and the temperature rise near the indenter all increase and then decrease. The surface crystallinity of PLA also increases and then decreases, indicating that it and the scratch resistance are closely related. These findings provide useful information about how PLA behaves under degradation conditions. (c) 2025 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution-NonCommercial 4.0 International (CC BY-NC) license (https://creativecommons.org/licenses/by-nc/4.0/).

To investigate the effect of interface temperature on the soil-reinforcement interaction mechanism, a series of pullout tests were conducted considering different types of reinforcement (geogrid and non-woven geotextile), backfill (dry sand, wet sand, and clay), and six interface temperatures. The test results indicate that at interface temperatures of 0 degrees C and above, reinforcement failure didn't occur during the pullout tests, whereas it predominantly occurred at subzero temperatures. Besides, the pullout resistance for the same soil-reinforcement interface gradually decreased as the interface temperature rose. At a given positive interface temperature, the pullout resistance between wet sand and reinforcement was significantly higher than that of the clayreinforcement interface but lower than that of the dry sand-reinforcement interface. Compared with geotextile reinforcements, geogrids were more difficult to pull out under the same interface temperature and backfill conditions. In addition, the lag effect in the transfer of tensile forces within the reinforcements was significantly influenced by the type of soil-reinforcement interface and the interface temperature. Finally, the progressive deformation mechanism along the reinforcement length at different interface temperatures was analyzed based on the strain distribution in the reinforcement.

An analytical methodology was developed for the first time in this work enabling the simultaneous enantiomeric separation of the fungicide fenpropidin and its acid metabolite by Capillary Electrophoresis. A dual cyclodextrin system consisting of 4 % (w/v) captisol with 10 mM methyl-beta-cyclodextrin was employed in a 100 mM sodium acetate buffer at pH 4.0. Optimal experimental conditions (temperature 25 degrees C, separation voltage -25 kV, and hydrodynamic injection of 50 mbar x 10 s) allowed the simultaneous separation of the four enantiomers in <10.7 min with resolutions of 3.1 (fenpropidin) and 3.2 (its acid metabolite). Analytical characteristics of the method were evaluated and found adequate for the quantification of both chiral compounds with a linearity range from 0.75 to 70 mg L-1, good accuracy (trueness included 100 % recovery, precision with RSD<6 %), and limits of detection and quantification of 0.25 and 0.75 mg L-1, respectively, for the four enantiomers. No significant differences were found between the concentrations determined and labelled of fenpropidin in a commercial agrochemical formulation. The stability over time (0-42 days) of fenpropidin enantiomers using the commercial agrochemical formulation was evaluated in two sugar beet soils, revealing to be stable at any time in one sample, while in the other a decrease of 45 % was observed after 42 days. Individual and combined toxicity of fenpropidin and its metabolite was determined for the first time for marine organism Vibrio fischeri, demonstrating higher damage caused by parent compound. Synergistics and antagonists' interactions were observed at low and high effects levels of contaminants.

Vegetation greening across the Tibetan Plateau, a critical ecological response to climate warming and land-cover change, affects soil hydrothermal regimes, altering soil moisture (SM) and soil temperature (ST) dynamics. However, its effects on SM-ST coupling remain poorly understood. Using integrated field measurements from a vegetation-soil (V-S) network, reanalysis, and physics-based simulations, we quantify responses of SM, ST, and their coupling to vegetation changes across the Upper Brahmaputra (UB) basin, southern Tibetan Plateau. Results show that strong positive SM-ST correlations occur throughout 0-289 cm soil layers across the basin, consistent with the monsoon-driven co-occurrence of rainy and warm seasons. Spatially, SM-ST coupling strength exhibits pronounced spatial heterogeneity, demonstrating strongest coupling in central basin areas with weaker intensities in eastern and western regions. Overall, vegetation greening consistently induces soil warming and drying: as leaf area index (LAI) increases from 20 % to 180 % of its natural levels, SM (0-160 cm) declines by 15 % to 29 % due to enhanced evapotranspiration and root water uptake. Mean ST simultaneously increases by 1.4 +/- 0.9 degrees C. Crucially, sparsely vegetated regions sustain warming (1.4-2.1 degrees C), while densely vegetated areas transition from initial warming to gradual cooling. These findings advance our understanding of soil hydrothermal dynamics and their broader environmental impacts, improving climate model parameterizations and informing sustainable land management strategies in high-altitude ecosystems.