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This study highlights the results of a palaeoecological analysis conducted on five permafrost peatlands in the northern tundra subzone along the Barents Sea coast in the European Arctic zone. The depth of the peat cores that were sampled was approximately 2 m. The analysis combined data on the main physical and chemical soil properties, radiocarbon dating, botanical composition, and mass fraction of polycyclic aromatic hydrocarbons (PAHs). The concentrations of 16 PAHs in peat organic layers ranged from 140 to 254 ng/g, with an average of 182 ng/g. The peatlands studied were dominated by PAHs with a low molecular weight: naphthalene, phenanthrene, fluoranthene, pyrene, chrysene. The vertical distribution patterns of PAHs along the peat profile in the active layer and permafrost were determined. PAHs migrating down the active layer profile encounter the permafrost barrier and accumulate at the boundary between active layer and permafrost layer. The deep permafrost layers accumulate large amounts of PAHs and PAH derivatives, which are products of lignin conversion during the decomposition of grassy and woody vegetation during the Holocene climate optima. The total toxic equivalency concentration (TEQ) was calculated. Peatlands from the Barents Sea coast have low toxicity for carcinogenic PAHs throughout the profile. TEQ ranged from a minimum of 0.1 ng/g to a maximum of 13.5 ng/g in all peatlands investigated. For further potential use in Arctic/sub-Arctic environmental studies, PAH indicator ratios were estimated. In all investigated sections and peatland horizons, the most characteristic ratios indicate the petrogenic (natural) origin of PAHs.

期刊论文 2025-11-01 DOI: 10.1016/j.marpolbul.2025.118370 ISSN: 0025-326X

A comprehensive series of tests, including dynamic triaxial, monotonic triaxial and unconfined compressive strength (UCS) tests, were carried out on reconstituted landfill waste material buried for over twenty years in a closed landfill site in Sydney, Australia. Waste materials collected from the landfill site were treated with varying percentages of cement, and both treated and untreated specimens were investigated to evaluate the influence of cement treatment. The study examined the dynamic properties of cement-treated landfill waste, including cumulative plastic deformation, resilient modulus, and damping ratio, and also analysed the impact of cyclic loading on post-cyclic shear strength in comparison to pre-cyclic shear strength. The UCS tests and monotonic triaxial tests demonstrated that untreated specimens subjected to monotonic loading exhibited a progressive increase in strength with rising axial strain, whereas cement-treated specimens reached a peak strength before experiencing a decline. During cyclic loading, with the inclusion of cement, a significant reduction in cumulative plastic deformation and damping ratio was observed, and this reduction was further enhanced with increasing cement content. Conversely, the resilient modulus showed substantial improvement with the addition of cement, and this enhancement was further amplified with increasing cement content. The formation of cementation bonds between particles curtails particle movement within the landfill waste material matrix and prevents interparticle sliding during cyclic loading, leading to lower plastic strains and damping ratio while increasing resilient modulus. Post-cyclic monotonic testing revealed that cyclic loading caused the partial breakage of the cementation bonds, resulting in reduced shear strength. This reduction was higher on samples treated with lower cement content. Overall, the findings of the research offer crucial insights into the possibility of cement-treated landfill waste as a railway subgrade, laying the groundwork for informed design decisions in developing transport infrastructure over closed landfill sites while using landfill waste materials available on site.

期刊论文 2025-10-01 DOI: 10.1016/j.soildyn.2025.109525 ISSN: 0267-7261

Permafrost thaw represents one of Earth's largest climate feedback risks, potentially releasing vast carbon (C) stores as greenhouse gases (GHG). However, our ability to predict emissions remains limited by poor understanding of how changing organic matter (OM) composition affects microbial carbon processing. We test a metabolism-centered redox framework, which views microbial processes as coupled oxidative-reductive reactions, to mechanistically explain how organic matter metabolite quality controls greenhouse gas production in permafrost-affected peatland ecosystems. Rather than relying solely on geochemical redox measurements, our approach examines how microbes balance electron flow through metabolic pathways. Using active layer peat (9-19 cm) from contrasting environments (bog and fen), we employed multi-omics approaches, including metabolomics, metagenomics, and metatranscriptomics, to link OM chemistry to microbial function. Our results reveal distinct dissolved organic matter metabolite composition, with fen systems enriched in compounds with higher substrate quality (low molecular weight (MW) sugars with high H:C ratios and low aromaticity) and bog systems dominated by compounds with lower substrate quality (high MW phenols with lower H:C ratios and higher aromaticity). In fen samples, these sugar-like compounds correlated with higher oxidative metabolism and methanogenesis, supported by increased glycolysis gene expression. Initially, electrons from increased oxidative metabolism were balanced through nitrate and sulfate reduction, but as these electron acceptors were depleted, methanogenesis increased to maintain redox balance. Fen samples showed rapid degradation of both high- and low-substrate-quality compounds, suggesting sufficient energy for efficient C cycling. Conversely, bog samples exhibited more polyphenolic compounds, lower glycolysis activity, and higher stress-related gene expression, suggesting energy was diverted towards cell maintenance under acidic conditions rather than C processing. This approach suggests that predicting greenhouse gas emissions requires an understanding of how organic matter quality shapes microbial energy allocation strategies, providing a mechanistic framework for improving emission predictions from permafrost-affected peatlands and similar ecosystems.

期刊论文 2025-08-07 DOI: 10.1111/gcb.70390 ISSN: 1354-1013

Mastering the mechanical properties of frozen soil under complex stress states in cold regions and establishing accurate constitutive models to predict the nonlinear stress-strain relationship of the soil under multi-factor coupling are key to ensuring the stability and safety of engineering projects. In this study, true triaxial tests were conducted on roadbed peat soil in seasonally frozen regions under different temperatures, confining pressures, and b-values. Based on analysis of the deviatoric stress-major principal strain curve, the variation patterns of the intermediate principal stress, volumetric strain and minor principal strain deformation characteristics, and anisotropy of deformation, as well as verification of the failure point strength criterion, an intelligent constitutive model that describes the soil's stress-strain behavior was established using the Transformer network, integrated with prior information, and the robustness and generalization ability of the model were evaluated. The results indicate that the deviatoric stress is positively correlated with the confining pressure and the b-value, and it is negatively correlated with the freezing temperature. The variation in the intermediate principal stress exhibits a significant nonlinear growth characteristic. The soil exhibits expansion deformation in the direction of the minor principal stress, and the volumetric strain exhibits shear shrinkage. The anisotropy of the specimen induced by stress is negatively correlated with temperature and positively correlated with the bvalue. Three strength criteria were used to validate the failure point of the sample, and it was found that the spatially mobilized plane strength criterion is the most suitable for describing the failure behavior of frozen peat soil. A path-dependent physics-informed Transformer model that considers the physical constraints and stress paths was established. This model can effectively predict the stress-strain characteristics of soil under different working conditions. The prediction correlation of the model under the Markov chain Monte Carlo strategy was used as an evaluation metric for the original model's robustness, and the analysis results demonstrate that the improved model has good robustness. The validation dataset was input to the trained model, and it was found that the model still exhibits a good prediction accuracy, demonstrating its strong generalization ability. The research results provide a deeper understanding of the mechanical properties of frozen peat soil under true triaxial stress states, and the established intelligent constitutive model provides theoretical support for preventing engineering disasters and for early disaster warning.

期刊论文 2025-08-01 DOI: 10.1016/j.coldregions.2025.104496 ISSN: 0165-232X

Widespread changes to near-surface permafrost in northern ecosystems are occurring through gradual top-down thaw and more abrupt localized thermokarst development. Both thaw types are associated with a loss of ecosystem services, including soil hydrothermal and mechanical stability and long-term carbon storage. Here, we analyzed relationships between the vascular understory, basal moss layer, active layer thickness (ALT), and greenhouse gas fluxes along a thaw gradient from permafrost peat plateau to thaw bog in Interior Alaska. We used ALT to define four distinct stages of thaw: Stable, Early, Intermediate, and Advanced, and we identified key plant taxa that serve as reliable indicators of each stage. Advanced thaw, with a thicker active layer and more developed thermokarst features, was associated with increased abundance of graminoids and Sphagnum mosses but decreased plant species richness and ericoid abundance, as well as a substantial increase in methane emissions. Early thaw, characterized by active layer thickening without thermokarst development, coincided with decreased ericoid cover and plant species richness and an increase in CH4 emissions. Our findings suggest that early stages of thaw, prior to the formation of thermokarst features, are associated with distinct vegetation and soil moisture changes that lead to abrupt increases in methane emissions, which then are perpetuated through ground surface subsidence and collapse scar bog formation. Current modeling of permafrost peatlands will underestimate carbon emissions from thawing permafrost unless these linkages between plant community, nonlinear active layer dynamics, and carbon fluxes of emerging thaw features are integrated into modeling frameworks.

期刊论文 2025-07-22 DOI: 10.1029/2024JG008639 ISSN: 2169-8953

Sodium hydroxide (NaOH)-sodium silicate-GGBS (ground granulated blast furnace slag) effectively stabilises sulfate-bearing soils by controlling swelling and enhancing strength. However, its dynamic behaviour under cyclic loading remains poorly understood. This study employed GGBS activated by sodium silicate and sodium hydroxide to stabilise sulfate-bearing soils. The dynamic mechanical properties, mineralogy, and microstructure were investigated. The results showed that the permanent strain (epsilon(p)) of sodium hydroxide-sodium silicate-GGBS-stabilised soil, with a ratio of sodium silicate to GGBS ranging from 1:9 to 3:7 after soaking (0.74%-1.3%), was lower than that of soil stabilised with cement after soaking (2.06%). The resilient modulus (E-d) and energy dissipation (W) of sodium hydroxide-sodium silicate-GGBS-stabilised soil did not change as the ratio of sodium silicate to GGBS increased. Compared to cement (E-d = 2.58 MPa, W = 19.96 kJ/m(3)), sulfate-bearing soil stabilised with sodium hydroxide-sodium silicate-GGBS exhibited better E-d (4.84 MPa) and lower W (15.93 kJ/m(3)) at a ratio of sodium silicate to GGBS of 2:8. Ettringite was absent in sodium hydroxide-sodium silicate-GGBS-stabilised soils but dominated pore spaces in cement-stabilised soil after soaking. Microscopic defects caused by soil swelling were observed through microscopic analysis, which had a significant negative impact on the dynamic mechanical properties of sulfate-bearing soils. This affected the application of sulfate-bearing soil in geotechnical engineering.

期刊论文 2025-05-30 DOI: 10.1680/jcoma.24.00124 ISSN: 1747-650X

Controlled low-strength material (CLSM) is a flowable, self-leveling backfill material used as an alternative to compacted soil for backfilling trenches, retaining walls, underground cavities, and in pavement construction. This study aims to investigate the permanent deformation of CLSM reinforced with basalt fibers. Basalt fibers with lengths of 6 and 24 mm are incorporated into CLSM mixtures to assess their impact on flowability, setting times, and mechanical properties. Mechanical testing indicates that longer fibers improve tensile strength through a bridging effect. Repeated load triaxial tests are conducted to evaluate the permanent strain behavior under repeated loading. The results show that permanent strain increases with the deviator stress and number of loading cycles. A regression model accounting for the number of loading cycles and deviator stress provides accurate permanent-strain predictions, and the permanent strain behaviors are classified based on the refined shakedown theory. Therefore, the basalt-fiber-reinforced CLSM suggested in this study may be suitable for pavement base material due to its relatively low permanent strain under typical stress conditions.

期刊论文 2025-05-01 DOI: 10.1016/j.trgeo.2025.101570 ISSN: 2214-3912

Subarctic palsa mires are natural indicators of the status of permafrost in its sporadic distribution zone. Estimation of the rate of their thawing can become an auxiliary indicator to predict climate shifts. The formation, growth, and degradation of palsas are dynamic processes that depend on seasonal weather fluctuations and local environmental factors. Therefore, accurate forecasts of palsas conditions and related ecosystem shifts must be based on a broad set of attributes of palsas from different regions of the Northern Hemisphere. With this in mind, we studied two palsa mires sites on the Kola Peninsula, for which no thorough descriptions were previously available. The first site, Chavanga, is at the southern limit of the permafrost zone under unfavorable climatic conditions and is a collapsing relic. The second site, Ponoy, in contrast, is within the sporadic permafrost zone with relatively cold and dry conditions. Our dataset was created by combining several methods to produce detailed spatial models of permafrost for the studied palsa mires. We used 3D ground-penetrating radar (GPR) survey, UAV-based orthophoto maps, peat thermometry, time-domain reflectometry, and manual sampling. We developed two integrated geospatial models that describe the active layer, the configuration of the palsa frozen core, and its thermal state and identify the zones of the most intense thawing. These observations revealed a significant thermal effect of the groundwater flow and its critical role in the palsas segmentation and rapid collapse. We have investigated a regulating effect of micromorphological features of palsa mounds such as heights, slope, depressions, and mire mineral bed through groundwater drainage. As a result, two new scenarios for the palsa degradation process have been developed, emphasizing the influence of environmental factors on the permafrost condition.

期刊论文 2025-04-06 DOI: 10.1002/ppp.2276 ISSN: 1045-6740

Vulnerability of peat plateaus to global warming was analyzed in northeastern European Russia. A laboratory experiment on artificial incubation of peat was carried out to analyze the resilience of organic matter of frozen peat bogs (palsas) to decomposition. The rate of mineralization of peat organic matter was calculated from data on the CO2 and CH4 emissions from the peat incubated at a temperature of +4 degrees C under artificial aerobic and anaerobic conditions during 1300 days. Peat samples were taken from the active layer (AL), transitional layer (TL), and permafrost layer (PL). The delta 13C and delta 15N isotopes and the C/N, O/C, and H/C ratios were determined as indicators of change in the decomposition rate of organic matter. By the 1300th day of the experiment under aerobic conditions, the total CO2 amount released from the analyzed samples (per 1 g of carbon) was 10.24-37.4 mg C g-1 (on average, 25.76 mg C g-1), while under anaerobic conditions, it was only 2.1-3.38 mg C g-1 (on average, 3.15 mg C g-1). The CH4 emission was detected only in the peat from the transitional layer in very small quantities. The incubation experiment results support the hypothesis that peat plateaus are resilient, especially under anaerobic conditions, regardless the ongoing climate warming.

期刊论文 2025-03-01 DOI: 10.1134/S1064229324604189 ISSN: 1064-2293

Soil liquefaction poses a significant risk to both human lives and property security. Recent in-situ cases have shown that clayey sand can experience multiple liquefaction events during mainshock-aftershock sequences, known as repeated liquefaction. While existing studies have focused on the cyclic behavior of initial liquefaction events, there is a lack of research on the mechanisms and cyclic response of repeated liquefaction in clayey sand. The factors that control repeated liquefaction in clayey sand are still not fully understood. In this study, a series of cyclic triaxial tests were conducted on sand with varying clay content (0 %, 5 %, 10 %, 15 %, and 20 %) under earthquake sequences. The test results showed that the liquefaction resistance initially decreased significantly and then increased with the number of liquefaction events. Sands with higher clay content exhibited earlier recovery of resistance during continuous liquefaction events. The analysis of the test results revealed that the repeated liquefaction resistance of clayey sand was quite intricate. Sands with a relative density (after reconsolidation) below 80 % were primarily influenced by the degree of stress-induced anisotropy, while sands with a relative density above 80 % were mainly affected by relative density.

期刊论文 2025-03-01 DOI: 10.1016/j.soildyn.2024.109188 ISSN: 0267-7261
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