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Carbonaceous particles play a crucial role in atmospheric radiative forcing. However, our understanding of the behavior and sources of carbonaceous particles in remote regions remains limited. The Tibetan Plateau (TP) is a typical remote region that receives long-range transport of carbonaceous particles from severely polluted areas such as South Asia. Based on carbon isotopic compositions ( Delta 14 C/ delta 13 C) of water -insoluble particulate carbon (IPC) in total suspended particle (TSP), PM 2.5 , and precipitation samples collected during 2020 - 22 at the Nam Co Station, a remote site in the inner TP, the following results were achieved: First, fossil fuel contributions ( f fossil ) to IPC in TSP samples (28.60 +/- 9.52 %) were higher than that of precipitation samples (23.11 +/- 8.60 %), and it is estimated that the scavenging ratio of IPC from non -fossil fuel sources was around 2 times that from fossil fuel combustion during the monsoon season. The f fossil of IPC in both TSP and PM 2.5 samples peaked during the monsoon season. Because heavy precipitation during the monsoon season scavenges large amounts of long-range transported carbonaceous particles, the contribution of local emissions from the TP largely outweighs that from South Asia during this season. The results of the IPC source apportionment based on Delta 14 C and delta 13 C in PM 2.5 samples showed that the highest contribution of liquid fossil fuel combustion also occurred in the monsoon season, reflecting increased human activities (e.g., tourism) on the TP during this period. The results of this study highlight the longer lifetime of fossil fuel -sourced IPC in the atmosphere than that of non -fossil fuel sources in the inner TP and the importance of local emissions from the TP during the monsoon season. The findings provide new knowledge for model improvement and mitigation of carbonaceous particles.

期刊论文 2024-04-20 DOI: 10.1016/j.scitotenv.2024.171321 ISSN: 0048-9697

Remote region is normally considered a receptor of long-range transported pollutants. Monitoring stations are important platforms for investigating the atmospheric environment of remote regions. However, the potential contribution of very local sources around these stations may produce important influences on its atmospheric environment, which is still barely studied. In this study, major ions of precipitation were investigated simultaneously at a typical remote station (Nam Co station) and other sites nearby on the Tibetan Plateau (TP) - the so-called The Third Pole in the world. The results showed that despite low values compared to those of other remote regions, the concentrations of major ions in precipitation of Nam Co station (e.g., Ca2+: 32.71 mu eq/L; SO42- : 1.73 mu eq/L) were significantly higher than those at a site around 2.2 Km away ( Ca2+: 11.47 mu eq/L; SO42- : 0.64 mu eq/L). This provides direct evidence that atmospheric environment at Nam Co station is significantly influenced by mineral dust and pollutants emitted from surface soil and anthropogenic pollutants of the station itself. Therefore, numbers of other related data reported on the station are influenced. For example, the aerosol concentration and some anthropogenic pollutants reported on Nam Co station should be overestimated. Meanwhile, it is suggested that it is cautious in selecting sites for monitoring the atmospheric environment at the remote station to reduce the potential influence from local sources.

期刊论文 2023-12-01 DOI: http://dx.doi.org/10.1007/s10661-023-12113-9 ISSN: 0167-6369

Carbonaceous particles play a crucial role in atmospheric radiative forcing. However, our understanding of the behavior and sources of carbonaceous particles in remote regions remains limited. The Tibetan Plateau (TP) is a typical remote region that receives long-range transport of carbonaceous particles from severely polluted areas such as South Asia. Based on carbon isotopic compositions ( Delta 14 C/ delta 13 C) of water -insoluble particulate carbon (IPC) in total suspended particle (TSP), PM 2.5 , and precipitation samples collected during 2020 - 22 at the Nam Co Station, a remote site in the inner TP, the following results were achieved: First, fossil fuel contributions ( f fossil ) to IPC in TSP samples (28.60 +/- 9.52 %) were higher than that of precipitation samples (23.11 +/- 8.60 %), and it is estimated that the scavenging ratio of IPC from non -fossil fuel sources was around 2 times that from fossil fuel combustion during the monsoon season. The f fossil of IPC in both TSP and PM 2.5 samples peaked during the monsoon season. Because heavy precipitation during the monsoon season scavenges large amounts of long-range transported carbonaceous particles, the contribution of local emissions from the TP largely outweighs that from South Asia during this season. The results of the IPC source apportionment based on Delta 14 C and delta 13 C in PM 2.5 samples showed that the highest contribution of liquid fossil fuel combustion also occurred in the monsoon season, reflecting increased human activities (e.g., tourism) on the TP during this period. The results of this study highlight the longer lifetime of fossil fuel -sourced IPC in the atmosphere than that of non -fossil fuel sources in the inner TP and the importance of local emissions from the TP during the monsoon season. The findings provide new knowledge for model improvement and mitigation of carbonaceous particles.

期刊论文 2021-12-01 DOI: http://dx.doi.org/10.1016/j.scitotenv.2024.171321 ISSN: 0048-9697
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