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Chromium is a heavy metal used in tanneries, leather industries, electroplating, and metallurgical operations, but improper disposal of waste from these industries leads to environmental contamination. Chromium exists primarily in trivalent and hexavalent forms, with hexavalent chromium (Cr (VI)) being highly toxic. Cr (VI) is carcinogenic, damages fish gills, and negatively impacts crops. Considering these negative impacts of Cr (VI), several physical, chemical, and biological remediation methods have been implemented at contaminated sites, but in most instances, these methods could be uneconomical, highly labor-intensive, and not sustainable. Therefore, a crucial goal is to implement an effective and sustainable remediation technique with consideration of actual site conditions. The aim is to develop a sustainable remediation strategy for a hexavalent chromiumcontaminated site in Ranipet, Tamil Nadu. The comprehensive risk assessment for the site has depicted hazard quotients greater than 1 for both onsite and offsite conditions, indicating the necessity of remediation. To address this, it is suggested to build permeable reactive filters (PRFs) packed with scrap iron filings to reduce Cr (VI) to Cr (III), and succeeding filters with locally produced waste coconut shell biochar to aid in adsorption. The use of waste here aims to eliminate the need to procure any commercially available materials for remediation, completely cutting down the environmental impact of raw material extraction or processing. A continuous chambered set-up packed with contaminated soil and PRFs with biochar and iron filings aided in the decrease of the peak concentration of Cr (VI) by 61 % as compared to a set-up without intervention. Moreover, the outlet concentration after 7 days reduced to 0.08 mg/L, which was 97.6 % less than that in the set-up without intervention.

期刊论文 2025-07-01 DOI: 10.1016/j.psep.2025.107268 ISSN: 0957-5820
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