Due to the serious environmental pollution generated by plastic packaging, chitosan (CS)-based biodegradable films are gradually gaining popularity. However, the limited antioxidant and bacteriostatic capabilities of CS, the poor mechanical properties and water resistance of pure CS films limit their widespread adoption in food packaging. In this study, new multifunctional bioactive packaging films containing monosaccharide-modified CS and polyvinyl alcohol (PVA) were prepared to address the shortcomings of pure CS films. Initially, Maillard reaction (MR) products were prepared by conjugating chitosan with galactose/mannose (CG/CM). The successful preparation of CG/CM was confirmed using UV spectroscopy, fluorescence spectroscopy, fourier transform infrared spectroscopy (FTIR) and high-performance gel permeation chromatography (HPGPC). At an 8 mg/mL concentration, the DPPH radical scavenging activities of CM and CG were 5 and 15 times higher than that of CS, respectively. At the maximum concentration of 200 mu g/mL, both CM and CG exhibited greater inhibitory effects on the growth of Staphylococcus aureus, Pseudomonas aeruginosa and Escherichia coli, compared to CS. Additionally, CM and CG demonstrated significantly stronger protection against oxidative damage in Vero cells than CS. These results indicate that CG and CM possess superior antioxidant and antibacterial capabilities in comparison to CS. Then, the effects of the MR on the structures and functional properties of chitosan-based films were extensively examined. Compared with pure CS films, the MR in the CG/CM films significantly changed the film microstructure, enhanced the UV-barrier property and water resistance, and only slightly reduced thermal stability. The MR reduced the tensile strength but increased the elongation at break. Meanwhile, the composite films hold good soil degradation ability. Moreover, the CG/CM films possessed excellent antioxidant and antibacterial properties and demonstrated superior fresh-keeping capacity in the preservation of strawberries and cherry tomatoes (effectively prolonged for at least 2 days or 3-6 days). Our study indicates that CG/CM films can be used as a promising biodegradable antioxidant and antibacterial biomaterial for food packaging.

In recent years, increasing wildfire activity in the western United States has led to significant emissions of smoke aerosols, impacting the atmospheric energy balance through their absorption and scattering properties. Single scattering albedo (SSA) is a key parameter that governs these radiative effects, but accurately retrieving SSA from satellites remains challenging due to limitations in sensor resolution, low sensitivity of traditional remote sensing methods, and uncertainties in radiative transfer modeling, particularly from surface reflectance and aerosol characterization. Smoke optical properties evolve rapidly after emission, influenced by fuel type, combustion conditions, and chemical aging. Accurate SSA retrieval near the source thus requires high-temporal-resolution satellite observations. Critical Reflectance (CR) method provides this capability by identifying a unique reflectance value at which top-of-atmosphere (TOA) reflectance becomes insensitive to aerosol loading and primarily reflects aerosol absorption. SSA can be retrieved from this critical reflectance. This study presents a geostationary-based CR method using the Advanced Baseline Imager (ABI) on GOES-R satellites. The approach leverages ABI's high temporal (5-10 min) and spatial (3 km) resolution, consistent viewing geometry, and wide coverage. A tailored look-up table, based on an AOD-dependent smoke model for North America, links CR to SSA. Case studies show strong agreement with AERONET measurements, with retrieval differences mostly within 0.01-well below AERONET's +/- 0.03 uncertainty. The method captures temporal and spatial variations in smoke absorption and demonstrates robustness across daylight hours. This GEO-based CR approach offers an effective tool for high-resolution SSA retrieval, contributing to improved aerosol radiative forcing estimates and climate modeling.

Sugar maple, an economically and ecologically important tree in the northern hardwood forest, has experienced regeneration failure that in the Northeast portion of the range has been variously attributed to soil acidification and resultant changes in soil chemistry, impacts of climate change, and effects of species composition. In a 5-year study spanning a latitudinal gradient in the state of New Hampshire, we examined evidence for these three hypotheses to explain sugar maple regeneration patterns. Overall, sugar maple seedling survival was highest in the two sites with lower sugar maple abundance. Alternatively, the two other sites with greater than 50% sugar maple relative dominance shared the following outcomes: higher seed production per area, greater foliar pest damage, lower seedling survival, lower sapling density, and higher canopy maple mortality, while the sites with lower dominance of maple had opposite outcomes. Based on field data and a common garden experiment, conspecific impacts on seedling survival were related to foliar pests and fungal pathogens rather than through soil feedbacks. These results lend support to other studies encouraging promotion of stand tree diversity and avoidance of monocultures.

Biodegradability and eco-friendliness are the most importance topic to consider in the development of new products. Commercial hydrogels for agriculture applications are made from fully synthetic polymers, which is non-biodegradable and harmful to environment. The utilization of polysaccharide in hydrogels production has sparked the rise of biodegradable hydrogels (BHs). However, using it alone results in poor mechanical properties and very fast degradation. Therefore, combining it with other materials as a composite is necessary. This article reviewed the development of BHs in the last 5 years. Classifications, materials resources, preparation methods, biodegradability of BHs, seeds germination and plant growth performance are critically investigated. Fundamental concepts such as definitions and application methods of BHs are described. Finally, important conclusions and outlook have been mentioned at the end of this article.

Land degradation can cause food insecurities and can damage ecosystems. This study highlights the potential of cyanobacteria (Anabaena variabilis, Spirulina platensis, Scytonema javanicum, and Nostoc commune), along with bacteria (Bacillus sp. SSAU-2), and their consortia to form biological soil crust, restoring soil properties and promoting plant growth. The efficiency of soil improvement was characterized by physiochemical parameters such as phosphate solubilization, %TOC, pH, and salinity. Scanning electron microscopy and a pot experiment were utilized to observe the morphological and soil improvement studies. Bacterial inoculation resulted in significant improvements in soil fertility, such as exopolysaccharide, organic carbon, organic matter, phosphorus content, and total soil porosity. Cyanobacteria consortia were more effective than monocultures at improving soil fertility and promoting barley plant development. The potential value of selected cyanobacteria and bacterial consortia as a useful tool for the restoration of degraded land is demonstrated experimentally by this study.

Microbially induced carbonate precipitation (MICP) is an eco-friendly technique for weak soil reinforcement. In this study, Sporosacina pasteurii was used to strengthen silty sand after multigradient domestication in an artificial seawater environment. The efficiency of MICP was investigated by carrying out a series of macroscopic and microscopic tests on biocemented silty sand specimens. It was found that the salt ions in seawater impacted bacterial activity. The best activity of the bacterial solution in the seawater environment was achieved after five-gradient domestication, which was approximately 8% lower than that in the deionized water environment. The significant effects of domesticated bacteria on silty sand reinforcement were demonstrated by the content of precipitated carbonate and the unconfined compressive strength (UCS) of the treated specimens. The seawater positively impacted the MICP procedure due to the roles of calcium and magnesium ions, indicated by the X-ray diffraction spectra. The scanning electron microscopy (SEM) results showed that carbonate precipitations distributed primarily on the surfaces and near the contact points of the soil particles, contributing to the soil strength. The cementation solution concentration and injection rate significantly influenced the content and distribution of carbonate precipitations and UCS of the biocemented silty sand, and the values corresponding to good reinforcement efficiency were 1.0 mol/L and 1.0 mL/min, respectively. The results of consolidated undrained triaxial tests showed that the mechanical properties of treated specimens were influenced by biocementation cycles. It was found that the stress-strain behavior of biocemented samples changed from strain hardening to strain softening when the number of reinforcement cycles increased. The peak strength of silty sand was increased by 1.9-3 times after 5 times MICP treatment. The effect of biocementation cycles on the shear strength parameters could be represented by relating the effective friction angle and effective cohesion of biocemented silty sand to the carbonate content.

The issue of water-enriched surrounding rock induced by excavation disturbances in loess tunnels represents a significant challenge for the construction of loess tunnel projects. Based on the concepts of lime sac water absorption, expansion, and compaction, consolidation, and drainage of surrounding rock and soil, as well as active reinforcement, a tandem water-absorbing and compaction anchor with heat-expansion and compaction consolidation functionality has been developed. To facilitate the engineering design and application of this novel anchor, a consolidation equation for cylindrical heat source-consolidated soil was derived under conditions of equal strain and continuous seepage. Considering the impact of temperature in the thermal consolidation zone on soil permeability, an analytical solution for the average degree of consolidation of the surrounding soil after support with the water-absorbing and compaction anchor was provided. The correctness of the solution was verified through engineering examples, demonstrating the reasonableness of the theoretical calculation method used in this study. The analysis of consolidation effects in engineering examples demonstrates that the excess pore water pressure in the borehole wall area dissipates rapidly after reaming, exhibiting an exponential decay over time. By the 100th time step, the pore pressure decreases from 100 kPa to 63.2 kPa. As consolidation continues, by the 1000th time step, the pore pressure further reduces to 21.6 kPa. The region with significant changes in pore pressure amplitude is primarily located within the plastic zone of the reamed hole, while the rate of pore pressure change in the more distal elastic zone is generally lower. The consolidation process effectively dissipates the excess pore water pressure and converts it into effective stress in the soil, indicating a notable active reinforcement effect of the water-absorbing compaction anchor. Within the plastic zone, the attenuation rate of excess pore water pressure is 85%. Under different drainage conditions at the borehole wall, the dissipation rate of excess pore pressure in Model 1 (Assuming drainage conditions around the water absorbing anchor rod) is greater than that in Model 2 (Assuming that there is no drainage around the water absorbing anchor rod), with the average degree of consolidation in Model 1 being 22% higher than in Model 2. Under the conditions of Model 1, the active reinforcement effect of the water-absorbing compaction anchor is more pronounced, providing better reinforcement for the surrounding rock and soil. To ensure the reinforcement effect, the theoretical design should consider a certain surplus in the filling quality of the lime water-absorbing medium. The research findings are of significant importance for advancing the theoretical structural design and engineering practical application of this new type of anchor.

Selenium fertilizers (Se-fertilizers) were applied to promote the growth of plant and improve the Se content in crops. However, traditional Se-fertilizers have low utilization efficiency of Se due to adsorption or leaching. Herein, Alg-g-Polyacrylamide/Se orange peel polysaccharide (AP/SeOPP) hydrogel was prepared and characterized by FT-IR, SEM, XRD and XPS. The swelling behaviors of AP8/SeOPP3 in different saline solution were investigated. Meanwhile, the rheological properties of AP8/SeOPP3 were studied. The water-retention ratio of AP8/SeOPP3 at -0.08 MPa were 84.9 %. The water-holding capacities of soil with AP8/SeOPP3 (1 wt%) was 33.8 % at 20th day. The pot experiments showed that the Se content of Chinese cabbage treated by AP8/SeOPP3 of 2 wt% was 2.67 mg/kg. Compared with control treatment, the average stem height and fresh weight of Chinese cabbage fertilizered by AP8/SeOPP3 were higher than that treated by AP8 hydrogel. The release mechanism indicated that there was the ion exchange between Cl-, PO43- , SO42- in sandy soil and SeO32- in AP8/ SeOPP3 hydrogel. This work provides a feasible strategy for promoting vegetable growth and achieving Seenrichment of crops in arid and semi-arid region.

Hydrogel is a three-dimensional polymer that can absorb large amounts of reagents while maintaining structural integrity. This material has been applied in many fields especially in smart agriculture. To improve the economic viability, the reusability of hydrogels in agricultural engineering over multiple cycles of adsorption and desorption is an urgent requirement. This can be solved if the crosslinker is used properly. Therefore, in this work, a series of porous semi-interpenetrating polymer network (IPN) hydrogels based on linear polyacrylamide, acrylamide, maleic acid, and N,N'-methylenebisacrylamide (MBA) were synthesized. The hydrogels were evaluated for the impact of MBA content on the characteristics and applicability as a urea fertilizer carrier. The chemical composition, morphology, mechanical, and rheological properties, swelling behavior, urea absorption, and desorption of hydrogels with crosslinker content in the range of 0.5%-2.0% were investigated. The porous structure was confirmed by scanning electron microscopy images. Changing the MBA content significantly affected all characteristics of the hydrogels. In particular, increasing the MBA content decreased the equilibrium swelling ratios in all investigated environments. The maximum amount of urea loaded into the hydrogel was also reduced from 435.88 to 188.50 mg/g. This increase also changed the swelling mechanism from non-Fickian to Fickian, whereas the urea release mechanism changed from Fickian to non-Fickian. Finally, the hydrogels demonstrated stability in soil over multiple cycles of water absorption and release. This study provides valuable insights into designing a semi-IPN hydrogel with desired properties that meet the application requirements of modern farming techniques.

Bridge abutments are often damaged by girder impacts during major earthquakes. Very limited studies have been conducted. None of the past studies have incorporated abutment damage as an integrated system, i.e. the interaction between the deck and the back wall as well as between abutment and backfill. First, the reliability of the numerical model for damage assessment is validated with the result obtained from the shaking table test. Second, numerical simulations of the impact effect were carried out on four abutments with different shapes and dimensions of wing wall. The developed numerical models can simulate the nonlinear backfill soil, the backfill-back wall interface, and damage to reinforced concrete with the strain rate effect of the concrete and steel reinforcement. Parametric studies were conducted on the influence of the nonlinearity of the backfill soil, back wall-to-backfill friction, constitutive law of concrete, hourglass ratio, and impact energy. The results show that the nonlinear behaviour of the backfill soil and wing wall plays a significant role in the impact force on the back wall behaviour. Since poundings can be repetitive, this study confirms that the velocity of the initial impact of a bridge deck can precisely predict the severity of abutment damage.