Carbonaceous aerosols (CA) strongly impact regional and global climate through their light-absorbing and scattering properties, yet their effects remain uncertain in dust-influenced regions. We investigated the optical properties, source contributions, and radiative impacts of CA at two climatically distinct regions in northwestern India: an arid region (AR, Jodhpur; post-monsoon) and a semi-arid region (SAR, Kota; winter). Mean absorption & Aring;ngstr & ouml;m exponent (AAE) values were comparable between the two regions (AR: 1.416 +/- 0.173; SAR: 1.395 +/- 0.069), but temporal cluster analysis revealed source-specific variability, with lower AAE during traffic-dominated periods (similar to 1.30) and elevated AAE during solid fuel and biomass combustion (1.68 in AR and 1.52 in SAR). While equivalent BC (eBC) levels were higher in AR with a relatively uniform liquid-fuel contribution (BClf = 80.06 +/- 1.98 %), the mass absorption cross- of BC (MAC(BC)) in SAR was similar to 4.5X greater, driven by local solid fuel combustion and transported biomass burning emissions (BCsf = 34.61 +/- 6.88 %). Mie modelling indicated higher SSA in AR due to higher contribution of mineral dust, in contrast to SAR, where carbonaceous aerosols caused stronger absorption, forward scattering, and higher imaginary refractive index (k(OBD)). Although absorption enhancement (E-lambda) was slightly higher in AR (similar to 1.11 vs. similar to 0.99), SAR aerosols nearly doubled the warming potential (Delta RFE), with RFE values of similar to 0.87 W/m(2) in SAR versus similar to 0.43 W/m(2) in AR. These findings highlight strong source-specific and site-specific variability in aerosol absorption and radiative, emphasizing the need to integrate region-specific parameters into climate models and air quality assessments for data-scarce arid and semi-arid South Asian environments.

Ecosystem carbon use efficiency (CUE) is a key indicator of an ecosystem's capacity to function as a carbon sink. While previous studies have predominantly focused on how climate and resource availability affect CUE through physiological processes during the growing season, the role of canopy structure in regulating carbon and energy exchange, especially its interactions with winter climate processes and nitrogen use efficiency (NUE) in shaping ecosystem CUE in semi-arid grasslands, remains insufficiently understood. Here, we conducted a 5-year snow manipulation experiment in a temperate grassland to investigate the effects of deepened snow on ecosystem CUE. We measured ecosystem carbon fluxes, soil nitrogen concentration, species biomass, plants' nitrogen concentration, canopy height and cover and species composition. We found that deepened snow increased soil nitrogen availability, while the concurrent rise in soil moisture facilitated nutrient acquisition and utilization. Together, these changes supported greater biomass accumulation per unit of nitrogen uptake, thereby enhancing NUE. In addition, deepened snow favoured the dominance of C3 grasses, which generally exhibit higher NUE and greater height than C3 forbs, providing a second pathway that further elevated community-level NUE. The enhanced NUE, through both physiological efficiency and compositional shifts, promoted biomass production and facilitated the development of larger canopy volumes. Larger canopy volumes under deepened snow increased gross primary production through improved light interception, while the associated increase in autotrophic maintenance respiration was moderated by higher NUE. Besides, denser canopies reduced understorey temperatures throughout the day, particularly at night, thereby suppressing heterotrophic respiration. Ultimately, deepened snow increased ecosystem CUE by enhancing carbon uptake while limiting respiratory carbon losses. Synthesis. These findings demonstrated the crucial role of biophysical processes associated with canopy structure and NUE in regulating ecosystem CUE, which has been largely overlooked in previous studies. We also highlight the importance of winter processes in shaping carbon sequestration dynamics and their potential to modulate future grassland responses to climate change.

The morphology of sheep wool applied as organic fertilizer biodegraded in the soil was examined. The investigations were conducted in natural conditions for unwashed waste wool, which was rejected during sorting and then chopped into short segments and wool pellets. Different types of wool were mixed with soil and buried in experimental plots. The wool samples were periodically taken and analyzed for one year using Scanning Electron Microscopy (SEM) and Energy-dispersive X-ray Spectroscopy (EDS). During examinations, the changes in the fibers' morphology were observed. It was stated that cut wool and pellet are mechanically damaged, which significantly accelerates wool biodegradation and quickly destroys the whole fiber structure. On the contrary, for undamaged fibers biodegradation occurs slowly, layer by layer, in a predictable sequence. This finding has practical implications for the use of wool as an organic fertilizer, suggesting that the method of preparation can influence its biodegradation rate. (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(SEM)(sic)(sic)(sic)(sic)(sic)X(sic)(sic)(sic)(sic)(EDS)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic).

Soft soil subgrades often present significant geotechnical challenges under cyclic loading conditions associated with major infrastructure developments. Moreover, there has been a growing interest in employing various recycled tire derivatives in civil engineering projects in recent years. To address these challenges sustainably, this study investigates the performance of granular piles incorporating recycled tire chips as a partial replacement for conventional aggregates. The objective is to evaluate the cyclic behavior of these tire chip-aggregate mixtures and determining the optimum mix for enhancing soft soil performance. A series of laboratory-scale, stress-controlled cyclic loading tests were conducted on granular piles encased with combi-grid under end-bearing conditions. The granular piles were constructed using five volumetric proportions of (tire chips: aggregates) (%) of 0:100, 25:75, 50:50, 75:25, and 100:0. The tests were performed with a cyclic loading amplitude (qcy) of 85 kPa and a frequency (fcy) of 1 Hz. Key performance indicators such as normalized cyclic induced settlement (Sc/Dp), normalized excess pore water pressure in soil bed (Pexc/Su), and pile-soil stress distribution in terms of stress concentration ratio (n) were analyzed to assess the effectiveness of the different mixtures. Results indicate that the ordinary granular pile (OGP) with (25 % tire chips + 75 % aggregates) offers an optimal balance between performance and sustainability. This mixture reduced cyclic-induced settlement by 86.7 % compared to the OGP with (0 % TC + 100 % AG), with only marginal losses in performance (12.3 % increase in settlement and 2.8 % reduction in stress transfer efficiency). Additionally, the use of combi-grid encasement significantly improved the overall performance of all granular pile configurations, enhancing stress concentration and reducing both settlement and excess pore water pressure. These findings demonstrate the viability of using recycled tire chips as a sustainable alternative in granular piles, offering both environmental and engineering benefits for soft soil improvement under cyclic loading.

This study was carried out to evaluate the interaction between terrestrial food crop plants and microplastics (MPs) with a focus on understanding their uptake, effects on growth, physiological, biochemical, and yield characteristics of two different cultivars of Solanum tuberosum L. i.e., Variety-1, Astrix (AL-4) and Variety-2, Harmes (WA-4). Polyethylene (PE), polystyrene (PS), and polypropylene (PP) spheres of size 5 mu m were applied to the soil at concentrations of 0 %, 1 %, and 5 %. Morphological parameters, including seed germination rate, shoot and root lengths, leaf area, and fresh and dry biomass of plants, got reduced significantly with the increase in MP concentration. PS MPs caused the most negative impact, particularly at 5 %, leading to the greatest decline in growth and Na, Mg, Zn, Cu, Ni, and Mn nutrient content. The highest DPPH scavenging activity was observed in the 5 % PS MPs treatment with approximately a 45.34 % increase from the control, indicating its potential to enhance antioxidant activity in response to stress caused by PS MPs. Both reducing and non-reducing sugar contents and total proteins were also decreased significantly. Vitamin C content exhibited a significant increase in response to MPs, with the highest levels recorded under 5 % PS MPs treatments. This suggests an adaptive antioxidant response to mitigate oxidative damage induced by MPs. SEM analysis revealed tissue infiltration of MP particles in shoots, leaves, and tubers of both varieties. Among MPs, PS had the most detrimental effects, followed by PP and PE, with higher concentrations increasing the negative impact.

Revealing regional-scale differences in microbial community structure and metabolic strategies across different land use types and soil types and how these differences relate to soil carbon (C) cycling function is crucial for understanding the mechanisms of soil organic carbon (SOC) sequestration in agroecosystems. However, our understanding of these knowledge still remains unclear. Here, we employed metagenomic methods to explore differences in microbial community structure, functional potential, and ecological strategies in calcareous soil and red soil, as well as the relationships among these factors and SOC stocks. The results showed that the bacterial absolute abundance and diversity were higher and the fungal absolute abundance and diversity were lower in calcareous soil than in red soil. This may be attributed to stochastic processes dominated the assembly of bacterial and fungal communities in calcareous soil and red soil, respectively. This in turn was closely related to soil pH and Ca2 + content. Linear discriminant analysis showed that genes related to microbial growth and reproduction (e.g., amino acid biosynthesis, central carbon metabolism, and membrane transport) were enriched in calcareous soil. While genes related to stress tolerance (e.g., bacterial chemotaxis, DNA damage repair, biofilm formation) were enriched in red soil. The great difference in soil properties between calcareous soil and red soil may be the cause of this result. Compared with red soil, the higher soil pH, SOC, and calcium and magnesium content in calcareous soil increased the bacterial absolute abundance and diversity, thus increasing the SOC sequestration potential of microorganisms, but also increased the decomposition of organic carbon by fungi, thus increasing the SOC loss potential. However, the bacterial absolute abundance and diversity were much higher than that of fungi. Therefore, soil carbon sequestration potential was still greater than its loss potential in karst agroecosystems. Agricultural disturbance intensity may be the main factor affecting these relationships. Overall, these findings advance our understanding of how soil microbial metabolic processes are related to SOC sequestration.

The flexible joints and segmental lining serve as effective seismic measures for tunnel in high-intensity seismic area. However, the tunnel axial deformation at flexible joints has not been fully incorporated into analytical models. This study presents a novel mechanical model for flexible joints that considers tension (compression)shear-rotation deformations, replacing the traditional shear-rotation springs model. An improved semi-analytical solution has been developed for the longitudinal response of a tunnel featuring a three-way flexible joint mechanical model subjected to fault movement. The nonlinear elastic-plastic foundation spring, the soil-lining tangential interaction, and the axial force of tunnel lining have been considered to improve the applicability and precision of proposed method. The proposed solution is compared with existing models, such as short beams connected by shear and rotation springs, by examining the predictions against numerical simulations. The results indicate that the predictions of the proposed model align much more closely with the outcomes of the numerical simulations than those of the existing models. For the working conditions selected in 4, neglecting the tension-compression deformation at flexible joints an 81.8% error in the peak axial force of the tunnel and a 20.2% error in the peak bending moment. The reason is that ignoring the axial deformation of these joints results in a larger calculated axial force on the lining, which subsequently leads to increased bending moment and shear force. Finally, a parameter sensitivity analysis is conducted to investigate the effect of various factors, including flexible joint stiffness, segmental lining length, and the length of the tunnel fortification zone.

Solidified soil (SS) is widely applied for resource utilization of excavated soil (ES), however the waste solidified soil (WSS) may pose environmental hazards in future because of its high pH (>10). WSS is unsuitable for landfill but can be raw materials for preparing recycled solidified soil (RSS) with better mechanical properties than SS. This investigation used OPC and alkali-activated slag (AAS) as binders to solidify ES and WSS and prepare RSS. The mechanical properties of RSS were experimentally verified to be better than SS, increased by over 76 %. The mechanism is that the clay particles in WSS have been solidified to form sand-like particles or adhere to natural sand, resulting in increasing content of sand-sized particles, and the residual clay particles undergo cation exchange under the high pH and Ca2 + content, resulting in a decrease in zeta potential, reducing diffusion layer thickness. As a result, the flowability of RSS increases under the same liquid to solid ratio. The residual unreacted binder particles and high pH in WSS are beneficial for the early and final compressive strength increase of RSS, which allows preparing RSS with lower cost and carbon emission. Finally, the utilization of WSS has significant environmental benefits.

Aerosol optical properties and radiative forcing critically influence Earth's climate, particularly in semi-arid regions. This study investigates these properties in Yinchuan, Northwest China, focusing on aerosol optical depth (AOD), single-scattering albedo (SSA), & Aring;ngstr & ouml;m Index, and direct radiative forcing (DRF) using 2023 CE-318 sun photometer data, HYSPLIT trajectory analysis, and the SBDART model. Spring AOD peaks at 0.58 +/- 0.15 (500 nm) due to desert dust, with coarse-mode particles dominating, while summer SSA reaches 0.94, driven by fine-mode aerosols. Internal mixing of dust and anthropogenic aerosols significantly alters DRF through enhanced absorption, with spring surface DRF at -101 +/- 22W m-2 indicating strong cooling and internal mixing increasing atmospheric DRF to 52.25W m-2. These findings elucidate dust-anthropogenic interactions' impact on optical properties and radiative forcing, offering critical observations for semi-arid climate research.

The construction of high-speed railway in Southwest China must traverse extensive regions of red mudstone. However, due to the humid subtropical monsoon climate in Southwest region, the red mudstone is often exposed to a high-water content or saturated state for extended time, and the poor mechanical properties under such condition cannot satisfy the requirements of high-speed railway subgrade. This paper proposes the use of lime and cement to improve the saturated unconfined compression strength (UCS) of the red mudstone fill material. Comprehensive tests, including UCS tests and scanning electron microscopy, were conducted on cement-lime modified red mudstone. Results show that lime stabilisation can significantly enhance the UCS and elastic modulus with the increase of dry density and modifier content. For the specimens with 4% lime and 6% cement, both peak strength and elastic modulus of the modified samples are more than 10 times higher than those of the untreated ones. The modulus exhibits nonlinear degradation with the development of shear stress, but the degradation can be improved with the increase of dry density and modifier content. At 60% of initial tangent modulus, the corresponding stress for untreated soil, lime stabilised and cement-lime modified filler are 0.74, 0.92 and 0.99. As for the energy evolution, the increasing dry density can enhance elastic and dissipated energies through denser particle arrangements, while a higher modifier content raises total energy. When the cement content is 6%, the total energy is more than 8 times higher than that of the untreated material, reflecting increased brittleness to a sudden fracture. The improvements are attributed to the formation of acicular and platy hydration products, which can tighten the pore structure. The study underscores the importance of lime and cement in ensuring subgrade stability for high-speed railways in Southwest China's red bed regions.