Soot deposition from wildfires decreases snow and ice albedo and increases the absorption of shortwave radiation, which advances and accelerates melt. Soot deposition also induces algal growth, which further decreases snow and ice albedo. In recent years, increasingly severe and widespread wildfire activity has occurred in western Canada in association with climate change. In the summers of 2017 and 2018, westerly winds transported smoke from extensive record-breaking wildfires in British Columbia eastward to the Canadian Rockies, where substantial amounts of soot were deposited on high mountain glaciers, snowfields, and icefields. Several studies have addressed the problem of soot deposition on snow and ice, but the spatiotemporal resolution applied has not been compatible with studying mountain icefields that are extensive but contain substantial internal variability and have dynamical albedos. This study evaluates spatial patterns in the albedo decrease and net shortwave radiation (K*) increase caused by soot from intense wildfires in Western Canada deposited on the Columbia Icefield (151 km(2)), Canadian Rockies, during 2017 and 2018. Twelve Sentinel-2 images were used to generate high spatial resolution albedo retrievals during four summers (2017 to 2020) using a MODIS bidirectional reflectance distribution function (BRDF) model, which was employed to model the snow and ice reflectance anisotropy. Remote sensing estimates were evaluated using site-measured albedo on the icefield's Athabasca Glacier tongue, resulting in a R-2, mean bias, and root mean square error (RMSE) of 0.68, 0.019, and 0.026, respectively. The biggest inter-annual spatially averaged soot-induced albedo declines were of 0.148 and 0.050 (2018 to 2020) for southeast-facing glaciers and the snow plateau, respectively. The highest inter-annual spatially-averaged soot-induced shortwave radiative forcing was 203 W/m(2) for southeast-facing glaciers (2018 to 2020) and 106 W/m(2) for the snow plateau (2017 to 2020). These findings indicate that snow albedo responded rapidly to and recovered rapidly from soot deposition. However, ice albedo remained low the year after fire, and this was likely related to a bio-albedo feedback involving microorganisms. Snow and ice K* were highest during low albedo years, especially for south-facing glaciers. These large-scale effects accelerated melt of the Columbia Icefield. The findings highlight the importance of using large-area high spatial resolution albedo estimates to analyze the effect of wildfire soot deposition on snow and ice albedo and K* on icefields, which is not possible using other approaches.

Black carbon (BC) aerosol has a strong radiative forcing effect and significantly affects human beings and the environment. Therefore, it is important to quantitatively calculate its direct radiative effect (BC DRE) at the surface (SFC) and the top of the atmosphere (TOA). Current studies mainly use empirical formula methods or broadband methods to calculate BC DRE. However, these two methods do not consider the differences of sky diffuse light ratios in different wavelength bands. To overcome this problem, a new scheme named the multiband synthetic method is proposed to calculate blue sky albedo at MODIS narrow bands, and then, the blue sky albedo at the whole shortwave band is synthesized with these separate narrowband blue sky albedos. Based on BC concentration measured in Xuzhou over two years (from May 2014 to July 2016), aerosol optical depth (AOD) and microphysical parameters provided by AERONET, and the black sky albedo (BSA) and white sky albedo (WSA) provided by Google Earth Engine (GEE) products, shortwave BC DRE was calculated numerically with the use of the 6S radiative transfer model. The range of BC DRE computed by the multiband synthetic method at the TOA and SFC are 0.84 +/- 0.08 to 3.27 +/- 1.01W/m(2) and -14.57 +/- 4.53 to -4.31 +/- 0.36W/m(2). The shortwave BC DRE calculated by the multiband synthetic method was higher than that calculated with the broadband method and empirical formula method by 0.11% to 0.36% (at the SFC), 0.14% to 1.4% (at the SFC) and 3.4% to 10.1% (at the TOA), 5.5% to 15.8% (at the TOA), respectively. The BC DREs calculated by these three methods have small differences at the SFC. However, the difference was large at the TOA. The results of this study suggest that it is important to consider the differences between different narrow bands when calculating the broadband shortwave blue sky albedo. (C) 2020 Elsevier B.V. All rights reserved.

The changes in aerosol optical and microphysical properties, and sub-band shortwave direct radiative forcing (DARF) in Beijing and Wuhan were compared at different haze levels in winters. The occurrence of haze is found to be governed by the wind circulation and boundary layer in Beijing where the ground wind speed and the height of boundary layer decreased significantly with the development of haze. Compared with the boundary layer and wind, the relative humidity has a stronger impact on haze in Wuhan. Especially, hygroscopic growth of aerosol particles is observed in Wuhan. The increase of fine-mode non-absorbing particles is the main characteristic of aerosol change during haze periods. With the development of haze, the larger increase in DARF at the top of atmosphere is found in Beijing, while the change in DARF at the atmosphere is more obvious in Wuhan. Efficiency of the DARF shows that the change of DARF depends highly on the single scattering albedo in Beijing due to the obvious enhancement of particle scattering, while it depends much more on particle radius over Wuhan. The increase in particle size can also change DARF proportion of each sub-band in shortwave that the DARF proportion in ultraviolet and visible decreased. However, the DARF proportion in near-infrared increased during haze, as the light in shorter wavelength is more sensitive to the change of the fine particle radius.

This paper provides an account of observed variations in Black carbon (BC) aerosol concentrations and their induced radiative forcing for the first time over Granada a measurement site in Southeastern Iberian Peninsula. Column-integrated BC concentrations were retrieved for the period 2005-2012. Monthly averages of BC concentrations (one standard deviation) ranged from higher values in January and December with 4.0 +/- 2.5 and 4 +/- 3 mg/m(2), respectively, to lower values in July and August with 1.6 +/- 1.2 and 2.0 +/- 0.5 mg/m(2), respectively. This reduction is not only observed in the average values, but also in the median, third and first quartiles. The average BC concentration in winter (3.8 +/- 0.6 mg/m(2)) was substantially higher than in summer (1.9 +/- 0.3 mg/m(2)), being the eight-year average of 2.9 +/- 0.9 mg/m(2). The reduction in the use of fossil fuels during the economic crisis contributed significantly to reduced atmospheric loadings of BC. According to our analysis this situation persisted until 2010. BC concentration values were analyzed in terms of air mass influence using cluster analysis. BC concentrations for cluster 1 (local and regional areas) showed high correlations with air masses frequency in winter and autumn. In these seasons BC sources were related to the intense road traffic and increased BC emissions from domestic heating. High BC concentrations were found in autumn just when air mass frequencies for cluster 3 (Mediterranean region) were more elevated, suggesting that air masses coming from that area transport biomass burning particles towards Granada. BC aerosol optical properties were retrieved from BC fraction using aerosol AERONET size volume distribution and Mie theory. A radiative transfer model (SBDART) was used to estimate the aerosol radiative forcing separately for composite aerosol (total aerosols) and exclusively for BC aerosols. The mean radiative forcing for composite aerosol was +23 +/- 6 W/m(2) (heating rate of +0.21 +/- 0.06 K/day) and +15 +/- 6 W/m(2) for BC aerosol (heating rate of +0.15 +/- 0.06 K/day). These values of radiative forcing and heating rate for BC aerosol represent-about 70% of their values for composite aerosol, which highlights the crucial role that BC aerosols play in modifying the radiation budget and climate. (C) 2017 Elsevier B.V. All rights reserved.

The influence of Arctic vegetation on albedo, latent and sensible heat fluxes, and active layer thickness is a crucial link between boundary layer climate and permafrost in the context of climate change. Shrubs have been observed to lower the albedo as compared to lichen or graminoid-tundra. Despite its importance, the quantification of the effect of shrubification on summer albedo has not been addressed in much detail. We manipulated shrub density and height in an Arctic dwarf birch (Betula nana) shrub canopy to test the effect on shortwave radiative fluxes and on the normalized difference vegetation index (NDVI), a proxy for vegetation productivity used in satellite-based studies. Additionally, we parametrised and validated the 3D radiative transfer model DART to simulate the amount of solar radiation reflected and transmitted by an Arctic shrub canopy. We compared results of model runs of different complexities to measured data from North-East Siberia. We achieved comparably good results with simple turbid medium approaches, including both leaf and branch optical property media, and detailed object based model parameterisations. It was important to explicitly parameterise branches as they accounted for up to 71% of the total canopy absorption and thus contributed significantly to soil shading. Increasing leaf biomass resulted in a significant increase of the NDVI, decrease of transmitted photosynthetically active radiation, and repartitioning of the absorption of shortwave radiation by the canopy components. However, experimental and modelling results show that canopy broadband nadir reflectance and albedo are not significantly decreasing with increasing shrub biomass. We conclude that the leaf to branch ratio, canopy background, and vegetation type replaced by shrubs need to be considered when predicting feedbacks of shrubification to summer albedo, permafrost thaw, and climate warming. (C) 2014 Elsevier Inc. All rights reserved.

Optical characterization of aerosol was performed by assessing the columnar aerosol optical depth (AM) and angstrom wavelength exponent (alpha) using data from the Microtops II Sunphotometer. The data were collected on cloud free days over Goa, a coastal site along the west coast of India, from January to December 2008. Along with the composite aerosol, the black carbon (BC) mass concentration from the Aethalometer was also analyzed. The AOD(0.500) (mu m) and angstrom wavelength exponent (alpha) were in the range of 026 to 0.7 and 0.52 to 1.33, respectively, indicative of a significant seasonal shift in aerosol characteristics during the study period. The monthly mean AOD(0.500) (mu m) exhibited a bi-modal distribution, with a primary peak in April (0.7) and a secondary peak in October (0.54), whereas the minimum of 026 was observed in May. The monthly mean BC mass concentration varied between 0.31 mu g/m(3) and 4.5 mu g/m(3), and the single scattering albedo (SSA), estimated using the OPAC model, ranged from 0.87 to 0.97. Modeled aerosol optical properties were used to estimate the direct aerosol shortwave radiative forcing (DASRF) in the wavelength range 0.25 mu m4.0 mu m. The monthly mean forcing at the surface, at the top of the atmosphere (TOA) and in the atmosphere varied between - 14.1 W m(-2) and -35.6 W m(-2), -6.7 W m(-2) and -13.4 W m(-2) and 5.5 W m(-2) to 22.5 W m(-2), respectively. These results indicate that the annual SSA cycle in the atmosphere is regulated by BC (absorbing aerosol), resulting in a positive forcing; however, the surface forcing was governed by the natural aerosol scattering, which yielded a negative forcing. These two conditions neutralized, resulting in a negative forcing at the TOA that remains nearly constant throughout the year. (C) 2013 Elsevier BY. All rights reserved.

Aerosols reduce the surface reaching solar flux by scattering the incoming solar radiation out to space. Various model studies on climate change suggest that surface cooling induced by aerosol scattering is the largest source of uncertainty in predicting the future climate. In the present study measurements of aerosol optical depth (AOD) and its direct radiative forcing efficiency has been presented over a typical tropical urban environment namely Hyderabad during December, 2003. Measurements of AOD have been carried out using MICROTOPS-II sunphotometer, black carbon aerosol mass concentration using Aethalometer, total aerosol mass concentration using channel Quartz Crystal Microbalance (QCM) Impactor Particle analyser and direct normal solar irradiance using Multifilter Rotating Shadow Band Radiometer (MFRSR). Diurnal variation of AOD showed high values during afternoon hours. The fraction of BC estimated to be similar to 9% in the total aerosol mass concentration over the study area. Results of the study suggest -62.5 Wm(-2) reduction in the ground reaching shortwave flux for every 0.1 increase in aerosol optical depth. The results have been discussed in the paper. (C) 2004 Elsevier Ltd. All rights reserved.