Brown carbon (BrC) aerosols have important warming effects on Earth's radiative forcing. However, information on the evolution of the light-absorption properties of BrC aerosols in the Asian outflow region is limited. In this study, we evaluated the light-absorption properties of BrC using in-situ filter measurements and sky radiometer observations of the ground-based remote sensing network SKYradiometer NETwork (SKYNET) made on Fukue Island, western Japan in 2018. The light-absorption coefficient of BrC obtained from filter measurements had a temporal trend similar to that of the ambient concentration of black carbon (BC), indicating that BrC and BC have common combustion sources. The absorption Angstrom exponent in the wavelength range of 340-870 nm derived from the SKYNET observations was 15% higher in spring (1.81 +/- 0.30) than through the whole year (1.53 +/- 0.50), suggesting that the Asian outflow carries light-absorbing aerosols to Fukue Island and the western North Pacific. After eliminating the contributions of BC, the absorption Angstrom exponent of BrC alone obtained from filter observations had a positive Spearman correlation (r(s) = 0.77, p < 0.1) with that derived from SKYNET observations but 33% higher values, indicating that the light-absorption properties of BrC were suc-cessfully captured using the two methods. Using the atmospheric transport model FLEXPART and fire hotspots obtained from the Visible Infrared Imaging Radiometer Suite product, we identified a high-BrC event related to an air mass originating from regions with consistent fossil fuel combustion and sporadic open biomass burning in central East China. The results of the study may help to clarify the dynamics and climatic effects of BrC aerosols in East Asia. (C) 2021 Elsevier B.V. All rights reserved.

Aerosol radiative forcing (ARE) over intense mining area in Indian monsoon trough region, computed based on the aerosol optical properties obtained through Prede (POM-1L) sky radiometer and radiative transfer model, are analysed for the year 2011 based on 21 clear sky days spread through seasons. Due to active mining and varied minerals ARF is expected to be significantly modulated by single scattering albedo (SSA). Our studies show that radiative forcing normalized by aerosol optical depth (ADD) is highly correlated with SSA (0.96) while ARF at the surface with AOD by 0.92. Our results indicate that for a given AOD, limits or range of ARF are determined by SSA, hence endorses the need to obtain SSA accurately, preferably derived through observations concurrent with AOD. Noticeably, ARE at the top-of the atmosphere is well connected to SSA (r = 0.77) than AOD (r = 0.6). Relation between observed black carbon and SSA are investigated. A possible over estimation of SSA by the inversion algorithm, SKYRAD.pack 4.2, used in the current study is also discussed. Choice of atmospheric profiles deviating from tropical to mid altitude summer or winter does not appear to be sensitive in ARE calculation by SBDART. Based on the 21 clear sky days, a multiple linear regression equation is obtained for ARF(bot) as a function of AOD and SSA with a bias of +/- 2.7 Wm(-2). This equation is verified with an independent data set of seasonal mean AOD and SSA to calculate seasonal ARF that compares well with the modeled ARE within +/- 4 Wm(-2). (C) 2013 Elsevier Ltd. All rights reserved.

Black carbon (BC), brown carbon (BrC), and mineral dust (DU) are three major light absorbing aerosols, playing important roles in climate change. Better knowledge of their concentrations is necessary for more accurate estimates of their radiative forcing effects of climate. We present a method to retrieve columnar contents of BC, BrC, and DU simultaneously from spectral refractive indices and spectral single scattering albedo obtained from the sun-sky radiometer measurements. Then, this method is applied to investigate the columnar volume fractions and mass concentrations of BC, BrC, and DU in Beijing, China, based on measurements obtained from 2009 to 2010. Results show that among the three absorbing aerosols, DU dominates the largest volume fraction in the total aerosol volume (20-45%), followed by BrC (5-25%), and BC (30%), while during June-September, the DU fraction is generally lower than 30%. BC is characterized by low levels throughout the year. The monthly mean BC columnar mass concentration ([BC]) ranges from 2.7 to 7.3 mg/m(2) with winter slightly higher than other seasons. As a preliminary validation, we compare our retrieved [BC] with in situ measurements. Similar day-to-day variation trends and good correlations are found between the retrieved [BC] and in situ measurements.

The column-integrated optical and radiative properties of aerosols in the downwind area of East Asia were investigated based on sun/sky radiometer measurements performed from February 2004 to June 2005 at Gwangju (35.23A degrees N, 126.84A degrees E) and Anmyeon (36.54A degrees N, 126.33A degrees E), Korea. The observed aerosol data were analyzed for differences among three seasons: spring (March-May), summer (June-August), and autumn/winter (September-February). The data were also categorized into five types depending on the air mass origin in arriving in the measurement sites: (a) from a northerly direction in spring (S-N), (b) from a westerly direction in spring (S-W), (c) cases with a low ngstrom exponent (< 0.8) in spring (dust), (d) from a northerly direction in autumn/winter (AW(N)), and (e) from a westerly direction during other seasons (AW(W)). The highest ngstrom exponents (alpha) at Gwangju and Anmyeon were 1.43 A +/- 0.30 and 1.49 A +/- 0.20, respectively, observed in summer. The lowest column-mean single-scattering albedo (omega) at 440 nm observed at Gwangju and Anmyeon were 0.89 A +/- 0.02 and 0.88 A +/- 0.02, respectively, during a period marked by the advection of dust from the Asian continent. The highest omega values at Gwangju and Anmyeon were 0.95 A +/- 0.02 and 0.96 A +/- 0.02, respectively, observed in summer. Variations in the aerosol radiative-forcing efficiency (beta) were related to the conditions of the air mass origin. The forcing efficiency in summer was -131.7 and -125.6 W m(-2) at the surface in Gwangju and Anmyeon, respectively. These values are lower than those under the atmospheric conditions of spring and autumn/winter. The highest forcing efficiencies in autumn/winter were -214.3 and -255.9 W m(-2) at the surface in Gwangju and Anmyeon, respectively, when the air mass was transported from westerly directions.