Calcium carbide residue (CCR), a calcium-rich industrial waste, shows promise in improving mechanical properties of weak soils when used alone or in combination with pozzolanic materials and alkaline activators. This study comprehensively investigated the mechanical performance and stabilisation mechanism of CCR, CCR-fly ash, and alkaline-activated CCR-fly ash on kaolin clay, aiming to clarify their differences in mechanisms, identify their limitations, and promote effective application. The contribution of CCR, fly ash, alkaline activator, and initial water content of soil on enhancing soil strength was quantitively assessed through signal-to-noise ratio and analysis of variance (ANOVA) based on the Taguchi method. The stabilisation mechanism of different CCR-based materials was investigated by assessing the morphological and mineralogical features of stabilised samples. Taguchi analysis revealed that the development of soil strength was primarily influenced by initial water content in the early curing stage, while the contribution of fly ash became larger over time. Variation in CCR content had a limited effect on soil strength across all curing periods, as indicated by low contribution values and low statistical significance in ANOVA. The microstructural analyses revealed a low degree of formation of C-S-H and CA-H gels in soil stabilised with CCR alone and CCR combined with fly ash, while alkaline activated CCR-fly ash stabilised soil exhibited the coexistence of C-A-S-H and N-A-S-H gels. Taguchi superposition model was effectively used to estimate compressive strength results and supported the determination of suitable CCR-based materials for specific strength requirements.
As a renewable energy source, biomass has the potential to replace non-renewable, fossil fuels. However, the disposal of the waste biomass ash (generated during energy generation) needs to be studied. While prior studies attempted to utilise composite additives containing biomass ash for soil, the introduction of other additives, such as cement, was an environmental burden. By employing biomass ash composition as the sole additive for strengthening purple soil under various curing conditions using high-temperature treatment, this study maximised its utilisation. The results showed that the unconfined compressive strength (UCS) varied across different curing conditions as the biomass ash content increased. After high temperature treatment at 800 degrees C, the biomass ash consistently reinforced purple soil under all the curing conditions. However, the biomass ash stabilisation mechanism differed between dry and humid curing conditions. Under dry curing conditions, the UCS increase depended on the cementing effect of soluble salt and/or insoluble calcite; under humid curing conditions, the UCS change was attributed to the damage to clay minerals, contact mode, and cementing effects of multiple components. Therefore, the 800 degrees C temperature-treated biomass ash can be used alone to reinforce purple soil, inhibiting the soil-water loss. This study presents a novel avenue for utilising waste, biomass ash, with considerable implications for environmental protection and soil stabilisation.