Black carbon (BC) exerts potential effect on climate, especially in the Tibetan Plateau (TP), where the cryosphere and environment are very sensitive to climate change. Although transport of atmospheric BC from South and East Asia to the TP has been comprehensively investigated, transport of BC from Central and West Asia (CWA) to the TP and its climate effect on the region have received little attention and are warrant investigation. Therefore, based on the observation and ERA-Interim reanalysis data, this study investigated transport of atmospheric BC from CWA to the TP, its seasonality and climate effect over the TP using WRF-Chem model. On an annual scale, BC from CWA contributes to 5.8% of total BC over the TP. Seasonally, the contribution rates were 5.1%, 5.9%, 6.2%, and 5.7% in spring, summer, autumn, and winter, respectively. The area-averaged surface radiative forcing over the TP induced by BC from CWA ranged from-0.14 to-0.04 W m(-2), with the largest and smallest negative radiative forcing occurring in autumn and winter, respectively. Affected by BC from CWA, the area-averaged surface temperature over the TP increased by 0.033 degrees C in summer, whereas it decreased by 0.002, 0.005, and 0.001 degrees C in spring, autumn and winter, respectively. In the atmosphere over the TP, the positive radiative forcing with values of 0.17, 0.20, 0.04, and 0.07 W m(-2) were induced by BC from CWA in spring, summer, autumn, and winter, respectively. At the top of the atmosphere over the TP, the calculated radiative forcing associated with BC from CWA were 0.08, 0.14,-0.1, and 0.03 W m(-2) in spring, summer, autumn, and winter, respectively. On an annual scale, the radiative forcing in the atmosphere and at the top of the atmosphere over the TP caused by BC from CWA were 0.12 W m(-2) and 0.04 W m(-2), respectively. This study enriched the theoretical connotation of transboundary transport of BC aerosols to the TP.

Air pollution is a grand challenge of our time due to its multitude of adverse impacts on environment and society, with the scale of impacts more severe in developing countries, including China. Thus, China has initiated and implemented strict air pollution control measures over last several years to reduce impacts of air pollution. Monitoring data from Jan 2015 to Dec 2019 on six criteria air pollutants (SO2, NO2, CO, O-3, PM2.5, and PM10) at eight sites in southwestern China were investigated to understand the situation and analyze the impacts of transboundary air pollutants in this region. In terms of seasonal variation, the maximum concentrations of air pollutants at these sites were observed in winter or spring season depending on individual site. For diurnal variation, surface ozone peaked in the afternoon while the other pollutants had a bimodal pattern with peaks in the morning and late afternoon. There was limited transport of domestic emissions of air pollutants in China to these sites. Local emissions enhanced the concentrations of air pollutants during some pollution events. Mostly, the transboundary transport of air pollution from South Asia and Southeast Asia was associated with high concentrations of most air pollutants observed in southwestern China. Since air pollutants can be transported to southwestern China over long distances from the source regions, it is necessary to conduct more research to properly attribute and quantify transboundary transport of air pollutants, which will provide more solid scientific guidance for air pollution management in southwestern China. (C) 2021 China University of Geosciences (Beijing) and Peking University. Production and hosting by Elsevier B.V.

Black carbon (BC) exerts potential effect on climate, especially in the Tibetan Plateau (TP), where the cryosphere and environment are very sensitive to climate change. Although transport of atmospheric BC from South and East Asia to the TP has been comprehensively investigated, transport of BC from Central and West Asia (CWA) to the TP and its climate effect on the region have received little attention and are warrant investigation. Therefore, based on the observation and ERA-Interim reanalysis data, this study investigated transport of atmospheric BC from CWA to the TP, its seasonality and climate effect over the TP using WRF-Chem model. On an annual scale, BC from CWA contributes to 5.8% of total BC over the TP. Seasonally, the contribution rates were 5.1%, 5.9%, 6.2%, and 5.7% in spring, summer, autumn, and winter, respectively. The area-averaged surface radiative forcing over the TP induced by BC from CWA ranged from-0.14 to-0.04 W m(-2), with the largest and smallest negative radiative forcing occurring in autumn and winter, respectively. Affected by BC from CWA, the area-averaged surface temperature over the TP increased by 0.033 degrees C in summer, whereas it decreased by 0.002, 0.005, and 0.001 degrees C in spring, autumn and winter, respectively. In the atmosphere over the TP, the positive radiative forcing with values of 0.17, 0.20, 0.04, and 0.07 W m(-2) were induced by BC from CWA in spring, summer, autumn, and winter, respectively. At the top of the atmosphere over the TP, the calculated radiative forcing associated with BC from CWA were 0.08, 0.14,-0.1, and 0.03 W m(-2) in spring, summer, autumn, and winter, respectively. On an annual scale, the radiative forcing in the atmosphere and at the top of the atmosphere over the TP caused by BC from CWA were 0.12 W m(-2) and 0.04 W m(-2), respectively. This study enriched the theoretical connotation of transboundary transport of BC aerosols to the TP.

The Tibetan Plateau is the largest high altitude landform on Earth, with an area of over 2.5x10(6) km(2) and an average elevation of similar to 4000 m above sea level. With a unique multisphere environmental system, the Tibetan Plateau provides an important ecological sheltering function for China and other parts of Asia. The Tibetan Plateau is one of the world's most pristine regions, benefiting from a sparse population with negligible local influence on its environment. However, it is surrounded by some of the most polluted areas in the world, such as South Asia, East Asia, and Southeast Asia. With the atmospheric circulation, such pollutants may impact the Tibetan Plateau through long-range transport. Clearly, the scientific research on the transboundary transport of pollutants is not only important for the understanding of multisphere interactions on the earth surface, but also could meet the national strategic needs for ecological and environmental protection. Long-term monitoring combined with short-term intensive observation campaigns, were used to comprehensively summarize the latest research progress regarding the spatial-temporal distribution and transport mechanism of air pollutants, as well as their climate and ecological impacts, which were achieved during the Second Tibetan Plateau Scientific Expedition. With respect of historical trends reconstructed from environmental archives, e.g., glacial ice cores and lake sediments, the black carbon and heavy metals like mercury show a dramatic increase since 1950s, which reflect the enhanced emission of air pollutants in Asia. On-line observation data and WRF-Chem modeling indicate that upper air circulation and local mountain-valley breeze system are the main drivers of trans Himalaya air pollution from South Asia. A regional climate-chemistry model coupled with an aerosol-snow/ice feedback module was used to reveal the natural and anthropogenic light-absorbing aerosols' radiative effects over the Tibetan Plateau. Results indicated that the mineral dust both in the atmosphere and snow induced 0.1-0.5 degrees C warming over the western Tibetan Plateau and Kunlun Mountains in spring. Meanwhile, dust aerosols caused snow water equivalent to decrease by 5-25 mm over the western TP, Himalayas and Pamir Mountains in winter and spring. The radiative effects of BC-in-snow induced surface temperature increased by 0.1-1.5 degrees C and snow water equivalent decreased by 5-25 mm over the western Tibetan Plateau and Himalayas. According to the observations the black carbon and dust found in the snow and ice on the surfaces of glaciers were responsible for on average 20% of the albedo reduction within the TP region. Those atmospherically transported pollutants also have obvious negative impacts on the ecosystem in Tibetan Plateau. For example, bioaccumulation of DDTs have been found in Tibetan terrestrial and aquatic food chains, and newly emerging compounds such as polyfluoroalkyl substances and hexabromocyclodo-decanes have been widely detected in wild fish species. Therefore, the corresponding ecological risks are of great concern. In the future, it is necessary to quantify the extent of atmospherically transported pollution and model the pollutant fate under the future environmental scenarios as well as establish environmental and health risk.

We quantify the contributions from five domestic emission sectors (residential, industry, transportation, energy, and biomass burning) and emissions outside of China (non-China) to concentration and direct radiative forcing (DRF) of black carbon (BC) in China for year 2010 using a nested-grid version of the global chemical transport model (GEOS-Chem) coupled with a radiative transfer model. The Hemispheric Transport of Air Pollution (HTAP) anthropogenic emissions of BC for year 2010 are used in this study. Simulated surface-layer BC concentrations in China have strong seasonal variations, which exceed 9 mu g m(-3) in winter and are about 1-5 mu g m(-3) in summer in the North China Plain and the Sichuan Basin. Residential sector is simulated to have the largest contribution to surface BC concentrations, by 5 -7 mu g m(-3) in winter and by 1-3 mu g m(-3) in summer, reflecting the large emissions from winter heating and the enhanced wet deposition during summer monsoon. The contribution from industry sector is the second largest and shows relatively small seasonal variations; the emissions from industry sector contribute 1-3 mu g m(-3) to BC concentrations in the North China Plain and the Sichuan Basin. The contribution from transportation sector is the third largest, followed by that from biomass burning and energy sectors. The non-China emissions mainly influence the surface-layer concentrations of BC in western China; about 70% of surface-layer BC concentration in the Tibet Plateau is attributed to transboundary transport. Averaged over all of China, the all-sky DRF of BC at the top of the atmosphere (TOA) is simulated to be 1.22 W m(-2). Sensitivity simulations show that the TOA BC direct radiative forcings from the five domestic emission sectors of residential, industry, energy, transportation, biomass burning, and non-China emissions are 0.44, 0.27, 0.01, 0.12, 0.04, and 030 W m(-2), respectively. The domestic and non-China emissions contribute 75% and 25% to BC DRF in China, respectively. These results have important implications for taking measures to reduce BC emissions to mitigate near-term climate warming and to improve air quality in China. (C) 2015 The Authors. Published by Elsevier Ltd.