Biomass residues from the agricultural industry, logging and wood processing activities have become a valuable fuel source. If processed under pyrolysis combustion, several products are generated. Bio-oil and gases are essential alternatives to fossil coal-based fuels for energy and electricity production, whose need is constantly growing. Biochar, the porous carbon-based lightweight product, often ends up as a soil fertilizer. However, it can be applied in other industrial sectors, e.g., in plastics production or in modifying cementitious materials intended for construction needs. This work dealt with the application of small amounts of softwood-based biochar up to 2.0 wt.% on hydration kinetics and a wide range of physical and mechanical properties, such as water transport characteristics and flexural and compressive strengths of modified cement pastes. In the comparison with reference specimens, the biochar incorporation into cement pastes brought benefits like the reduction of open porosity, improvement of strength properties, and decreased capillary water absorption of 7-day and 28-day-cured cement pastes. Moreover, biochar-dosed cement pastes showed an increase in heat evolution during the hydration process, accompanied by higher consumption of clinker minerals. Considering all examined characteristics, the optimal dosage of softwood-derived biochar of 1.0 wt.% of Portland cement can be recommended.

High-intensity coal mining has induced a series of ecological and environmental problems issues, including surface subsidence, the development of ground cracks, and the deterioration of vegetation. The disruption of water circulation systems induced by mining, such as perched groundwater, groundwater of aeration zone, and phreatic water, is the root cause of vegetation withering. The aeration zone serves as a crucial nexus in the process of water cycling and exerts a significant influence on soil fertility. To explore the characteristics of soil moisture transport in subsidence areas under the mining disturbance, on-site monitoring of the size and morphology characteristics of subsidence areas and ground cracks was conducted in typical mining areas in Inner Mongolia, China. Subsequently, a typical soil moisture transport model was constructed in subsidence areas, the soil moisture transport patterns under the influence of different types of subsidence and cracks were analyzed, and the influence law of soil damage on soil moisture transport in the aerated zone was clarified. The results indicate that (1) Based on the occurrence and distribution characteristics of subsidence cracks, the subsidence area can be divided into tension zone, compression zone, and neutral zone; the ground cracks are divided into permanent tension cracks and dynamic cracks. (2) The drought stress effect of soil in the subsidence area is significant. Under the influence of soil structure variation, the water-holding capacity of the soil in the subsidence area decreases, and the soil moisture dissipation is strong. The soil moisture transport rate in the aeration zone of the subsidence area is ranked as follows: tension zone > neutral zone > compression zone. (3) Ground cracks can exacerbate the soil moisture transport rate in the aeration zone. After 15 d of crack appearance, the soil moisture transport reaches a relatively stable state, and the soil moisture transport rate in the surface layer of the crack is the fastest, and the loss of soil moisture is the most significant. The crack effect is not significant beyond 100 cm from the crack. This study provides a theoretical and data support for soil and vegetation remediation in mining subsidence areas.

It is well known that the mechanical properties and appearance of adobe materials degrade significantly during freeze-thaw cycles due to the unique moisture absorption characteristics of soil particles. In order to clarify the performance degradation mechanism of adobe materials under freeze-thaw cycles, the evolution law of the pore structure, attack products, and capillary absorption characteristics were systematically studied when experiencing 10, 20, and 30 freeze-thaw cycles. The results showed that the flocculent hydration product around the Yellow River sediments and aggregate particles gradually reduced during adobe materials subjected to freezethaw cycles. Volume expansion caused by the growth of ettringite in macropores and cracks led to the deterioration in pore structure and more water participated in the subsequent freeze-thaw cycles. The porosity and pore volume of adobe materials increased with the increasing of freeze-thaw cycles, and the harmful pores of 50-200 nm rose significantly. After 20 freeze-thaw cycles, harmful pores accounted for 62.3% of the total pore volume of adobe materials, which induced an enlarged moisture transport capacity, and thus the capillary absorption coefficient increased by 18.52 g/(m2 & sdot;s1/2). As a combined result of above factors, after 30 freeze-thaw cycles, the loss rates in mass and compressive strength of adobe materials were 6.2% and 15.4%, respectively.