The precise detection of water-ice distributions within the permanently shadowed regions (PSRs) of the lunar south polar region is of paramount importance. We applied a polarimetric method for water-ice detection (PM4W) that utilizes Mini-RF data. The PM4W method incorporates several key radar scattering properties with topographical and environmental characteristics to detect water-ice within the lunar south polar region of 87 degrees S-90 degrees S. The method successfully identified 1578 water-ice containing pixels (each representing a 30 m x 30 m area) in the lunar shallow subsurface (1-3 m) at the south polar region, of which 1445 (similar to 91%) are spatially clustered in 29 PSRs. When comparing Mini-RF with M3 (each point representing a 280 m x 280 m area) using a buffer-based fuzzy assessment method, we found a pixel consistency of 60% and area consistency of 11%, which can be attributed to the differences in spatial resolution, positioning accuracy, and depth sensitivity. Moreover, over 90% of the water-ice pixels detected by Mini-RF are located within PSRs, accounting for 0.025% of their total area. In contrast, only 68% of the pixels detected by M3 are within PSRs, covering 0.760% of the PSRs area, which is approximately 30 times greater than the Mini-RF detections. The finer spatial resolution of the Mini-RF enables it to reveal previously undetectable features that align with the environmental mechanisms of water-ice storage. Our work contributes to assessing the potential presence of water-ice in vital exploration areas, providing pertinent indications for future lunar probes to identify water-ice on the Moon directly.