Gold mine tailings (GMTs) pose significant environmental challenges, and while alkali-activated materials (AAMs) have been widely used as sustainable alternatives to Portland cement for stabilizing geotechnical materials, further research is needed to optimize their composition and performance, particularly by incorporating traditional industrial waste residues to develop composite alkali-activated materials (CAAMs) with improved mechanical properties and reduced environmental impact. Different CAAMs admixtures (i.e., 0%, 3%, 5%, and 8%) and gold mine tailings were prepared, and the samples were solidified under saturated water and no air. In order to investigate the mechanical characteristics of CAAMs-stabilized GMTs, laboratory direct shear tests were carried out on samples after curing them for 3, 7, 14, and 28 days, respectively. The test results showed that with the extension of curing time, the brittleness of the samples increased, and the stress-displacement curves for all the cured specimens changed from plateau type to peak type. Both curing time and CAAMs content are conducive to improving the shear strength of CAAMs-stabilized GMTs samples, but the increase rate decreased as the vertical confining stress increased. Furthermore, the influence of CAAMs content on shear strength increment was larger than that of curing periods. The exponential growth model could well describe the change of shear strength with the curing periods under different vertical stresses. The paper can provide theoretical support for the application of CAAMs to enhance the stability of tailings dams.

Construction spoil (CS), a prevalent type of construction and demolition waste, is characterized by high production volumes and substantial stockpiles. It contaminates water, soil, and air, and it can also trigger natural disasters such as landslides and debris flows. With the advent of alkali activation technology, utilizing CS as a precursor for alkali-activated materials (AAMs) or supplementary cementitious materials (SCMs) presents a novel approach for managing this waste. Currently, the low reactivity of CS remains a significant constraint to its high-value-added resource utilization in the field of construction materials. Researchers have attempted various methods to enhance its reactivity, including grinding, calcination, and the addition of fluxing agents. However, there is no consensus on the optimal calcination temperature and alkali concentration, which significantly limits the large-scale application of CS. This study investigates the effects of the calcination temperature and alkali concentration on the mechanical properties of CS-cement mortar specimens and the ion dissolution performance of CS in alkali solutions. Mortar strength tests and ICP ion dissolution tests are conducted to quantitatively assess the reactivity of CS. The results indicate that, compared to uncalcined CS, the ion dissolution performance of calcined CS is significantly enhanced. The dissolution amounts of active aluminum, silicon, and calcium are increased by up to 420.06%, 195.81%, and 256.00%, respectively. The optimal calcination temperature for CS is determined to be 750 degrees C, and the most suitable alkali concentration is found to be 6 M. Furthermore, since the Al O bond is weaker and more easily broken than the Si O bond, the dissolution amount and release rate of active aluminum components in calcined CS are substantially higher than those of active silicon components. This finding indicates significant limitations in using CS solely as a precursor, emphasizing that an adequate supply of silicon and calcium sources is essential when preparing CS-dominated AAMs.

This study focuses on the use of alkali-activated materials and geopolymer grouts in deep soilmixing. Three types of grouts, incorporating metakaolin and/or slag and activated with sodium silicate solution, were characterized at different scales to understand the development of their local structure and macroscopic properties. The performance of the soilmix was assessed by using combinations of the grouts and model soils with different clay contents. Feret's approach was used to understand the development of compressive strength at different water-to-solid ratios ranging from 0.65 to 1. The results suggested that incorporating calcium reduced the water sensitivity of the materials, which is crucial in soilmixing. Adding soils to grouts resulted in improved mechanical properties, due to the influence of the granular skeleton. Based on strength results, binary soilmix mixtures containing 75% of metakaolin and 25% of slag, with H2O/Na2O ratios ranging from 28 to 42 demonstrated potential use for soilmixing due to the synergistic reactivity of metakaolin and slag. The optimization of compositions is necessary for achieving the desired properties of soil mixtures with higher H2O/Na2O ratios.