The largest permafrost area in China is on the Qinghai-Tibetan Plateau (QTP), and the nitrogen biogeochemical cycles in this area have received significant attention. However, there is insufficient knowledge of the available soil nitrogen and microbial biomass nitrogen (MBN) dynamics in this region, which hinders our understanding of the changes in the ecosystem and the effects of climate change on the nitrogen dynamics in the future. In this study, we determined the monthly changes in ammonium nitrogen, nitrate nitrogen, dissolved organic nitrogen (DON), and MBN contents of the topsoil (at depths of 0-20 cm) from April 2016 to March 2017 in the permafrost region on the QTP. The results show that soil NH4+-N and DON contents decreased during the growing season, while soil NO3--N content increased during the growing season and in the middle of the winter. The soil MBN contents increased at the beginning of the growing season and decreased during peak growth period, despite significant variations among the different sites. The soil temperature was positively correlated with soil NO3--N content but it was negatively correlated with the NH4+-N and DON contents. The soil moisture was positively correlated with the soil NO3--N, DON, and MBN contents. The primary factor affecting the seasonal patterns in soil NO3--N and DON contents was soil moisture. Soil moisture and plant growth also affected soil MBN via nutrient competition. The nutrient uptake by plants overwhelmed effect of temperature on the MBN in growing season. These findings improve our understanding of the nitrogen biochemical cycles and their response to future climate change.

The largest permafrost area in China is on the Qinghai-Tibetan Plateau (QTP), and the nitrogen biogeochemical cycles in this area have received significant attention. However, there is insufficient knowledge of the available soil nitrogen and microbial biomass nitrogen (MBN) dynamics in this region, which hinders our understanding of the changes in the ecosystem and the effects of climate change on the nitrogen dynamics in the future. In this study, we determined the monthly changes in ammonium nitrogen, nitrate nitrogen, dissolved organic nitrogen (DON), and MBN contents of the topsoil (at depths of 0-20 cm) from April 2016 to March 2017 in the permafrost region on the QTP. The results show that soil NH4+-N and DON contents decreased during the growing season, while soil NO3--N content increased during the growing season and in the middle of the winter. The soil MBN contents increased at the beginning of the growing season and decreased during peak growth period, despite significant variations among the different sites. The soil temperature was positively correlated with soil NO3--N content but it was negatively correlated with the NH4+-N and DON contents. The soil moisture was positively correlated with the soil NO3--N, DON, and MBN contents. The primary factor affecting the seasonal patterns in soil NO3--N and DON contents was soil moisture. Soil moisture and plant growth also affected soil MBN via nutrient competition. The nutrient uptake by plants overwhelmed effect of temperature on the MBN in growing season. These findings improve our understanding of the nitrogen biochemical cycles and their response to future climate change.

Field observations have suggested that particulate nitrate can promote the aging of black carbon (BC), yet the mechanisms of the aging process and its impacts on BC's light absorption are undetermined. Here we performed laboratory simulation of internal mixing of flame-generated BC aggregates with ammonium nitrate. Variations in particle size, mass, coating thickness, effective density, dynamic shape factor, and optical properties were determined online by a suite of instruments. With the development of coatings, the particle size initially decreased until reaching a coating thickness of similar to 10 nm and then started increasing, accompanied by an increase in effective density and a decrease in dynamic shape factor, reflecting the transformation of BC particles from highly fractal to near-spherical morphology. This is partially attributable to the restructuring of BC cores to more compact forms. Exposing coated particles to elevated relative humidity (RH) led to additional BC morphology changes, even after drying. Particle light absorption and scattering were also amplified with ammonium nitrate coating, increasing with coating thickness and RH. For BC particles with a 17.8 nm coating, absorption and scattering were increased by 1.5- and 7.9-fold when cycled through 70% RH (5-70-5% RH), respectively. The irreversible restructuring of the BC core caused by condensation of ammonium nitrate and water altered both absorption and scattering, with a magnitude comparable to or even exceeding the effects of increased coating. Results show that ammonium nitrate is among the most efficient coating materials with respect to modifying BC morphology and optical properties compared with other inorganic and organic species investigated previously. Accordingly, mitigation of nitrate aerosols is necessary for the benefits of both air pollution control and reducing the impacts of BC on visibility impairment and radiative forcing on climate change. Our results also pointed out that the effect of BC core restructuring needs to be considered when evaluating BC's light absorption enhancement. (C) 2020 Elsevier Ltd. All rights reserved.

The fate of permafrost carbon upon thaw will drive feedbacks to climate warming. Here we consider the character and context of dissolved organic carbon (DOC) in yedoma permafrost cores from up to 20m depth in central Alaska. We observed high DOC concentrations (4 to 129mM) and consistent low molecular weight organic acid concentrations in three cores. We estimate a DOC production rate of 12 mu molDOCm(-2)yr(-1) based on model ages of up to similar to 200kyr derived from uranium isotopes. Acetate C accounted for 241% of DOC in all samples. This proportion suggests long-term anaerobiosis and is likely to influence thaw outcomes due to biolability of acetate upon release in many environments. The combination of uranium isotopes, ammonium concentrations, and calcium concentrations explained 86% of the variation in thaw water DOC concentrations, suggesting that DOC production may be related to both reducing conditions and mineral dissolution over time.

We use GEOS-Chem chemical transport model simulations of sulfate-ammonium aerosol data from the NASA ARCTAS and NOAA ARCPAC aircraft campaigns in the North American Arctic in April 2008, together with longer-term data from surface sites, to better understand aerosol sources in the Arctic in winter-spring and the implications for aerosol acidity. Arctic pollution is dominated by transport from mid-latitudes, and we test the relevant ammonia and sulfur dioxide emission inventories in the model by comparison with wet deposition flux data over the source continents. We find that a complicated mix of natural and anthropogenic sources with different vertical signatures is responsible for sulfate concentrations in the Arctic. East Asian pollution influence is weak in winter but becomes important in spring through transport in the free troposphere. European influence is important at all altitudes but never dominant. West Asia (non-Arctic Russia and Kazakhstan) is the largest contributor to Arctic sulfate in surface air in winter, reflecting a southward extension of the Arctic front over that region. Ammonium in Arctic spring mostly originates from anthropogenic sources in East Asia and Europe, with added contribution from boreal fires, resulting in a more neutralized aerosol in the free troposphere than at the surface. The ARCMS and ARCPAC data indicate a median aerosol neutralization fraction [NH4+]/(2[SO42-] + [NO3-]) of 0.5 mol mol(-1) below 2 km and 0.7 mol mol(-1) above. We find that East Asian and European aerosol transported to the Arctic is mostly neutralized, whereas West Asian and North American aerosol is highly acidic. Growth of sulfur emissions in West Asia may be responsible for the observed increase in aerosol acidity at Barrow over the past decade. As global sulfur emissions decline over the next decades, increasing aerosol neutralization in the Arctic is expected, potentially accelerating Arctic warming through indirect radiative forcing and feedbacks. (C) 2011 Elsevier Ltd. All rights reserved.