Flash floods are often responsible for deaths and damage to infrastructure. The objective of this work is to create a data-driven model to understand how predisposing factors influence the spatial variation of the triggering factor (rainfall intensity) in the case of flash floods in the continental area of Portugal. Flash floods occurrences were extracted from the DISASTER database. We extracted the accumulated precipitation from the Copernicus database by considering two days of duration. The analysed predisposing factors for flooding were extracted considering the whole basin where each occurrence is located. These factors include the basin area, the predominant lithology, drainage density, and the mean or median values of elevation, slope, stream power index (SPI), topographic wetness index (TWI), roughness, and four soil properties. The Random Forest algorithm was used to build the models and obtained mean absolute percentage error (MAPE) around 19%, an acceptable value for the objectives of the work. The median of SPI, mean elevation and the area of the basin are the top three most relevant predisposing factors interpreted by the model for defining the rainfall input for flash flooding in mainland Portugal.

There has been a growing interest in controlled low strength material CLSM due to its engineering features, such as self-leveling and early strength development, as well as it potential for utilizing industrial waste. Still, the dynamic properties on CLSM are rarely studied. This study evaluates the feasibility of red mud as a partial aggregate replacement in foamed-lightweight CLSM, incorporating high-carbon fly ash and preformed foam. We varied both the red mud contents RMc and foam volume ratio FVR within the mixtures and examined their impact on unconfined compressive strength and dynamic properties including shear modulus G and damping ratio D. The results reveal that the red mud enhances foam stability, leading to more uniform pore structures and increased porosity, which reduces bulk densities. Despite higher porosity, red mud serves as a strong alkaline activator, enhancing geopolymer reactions of high-carbon fly ash and thereby increasing both compressive strength and initial shear modulus G0. Interestingly, increasing FVR had minimal impact on the D, while higher RMcnotably increased D, highlighting its distinct role in energy dissipation. The red mud-incorporated foamed CLSM exhibits strain-dependent normalized shear modulus G/G0 comparable to that of gravel, while its D is 40-100 % higher than gravel or gravelly soil at shear strain of 1.10-5, which corresponds to typical traffic-induced vibration levels. Moreover, theoretical volumetric-gravimetric relationships are introduced to account for the combined effects of FVR and RMcon CLSM behavior. These findings demonstrate that the red mud included foamed CLSM can be utilized as advanced structural backfill material capable of effectively mitigating the vibrations induced by traffic, low-amplitude seismic events, and mechanical sources.

Soil chemical washing has the disadvantages of long reaction time, slow reaction rate and unstable effect. Thus, there is an urgent need to find a cost-effective and widely applicable alternative power to facilitate the migration of washing solutions in the soil, so as to achieve efficient removal of heavy metals, reduce the risk of soil compaction, and mitigate the damage of soil structure. Therefore, the study used a combination of freeze-thaw cycle (FTC) and chemical washing to obtain three-dimensional images of soil pore structure using micro-X-ray microtomography, and applied image analysis techniques to study the effects of freeze-thaw washing on the characteristics of different pore structures of the soil, and then revealed the effects of pore structure on the removal of heavy metals. The results showed that the soil pore structure of the freeze-thaw washing treatment (FT) became more porous and complex, which increased the soil imaged porosity (TIP), pore number (TNP), porosity of macropores and irregular pores, permeability, and heavy metal removal rate. Macroporosity, fractal dimension, and TNP were the main factors contributing to the increase in TIP between treatments. The porous structure resulted in larger effective pore diameters, which contain a greater number of branching pathways and pore networks, allowing the chemical washing solutions to fully contact the soil, increasing the roughness of the soil particle surface, mitigating the risk of soil compaction, and decreasing the contamination of heavy metals. The results of this study contribute to provide new insights into the management of heavy metal pollution in agricultural soils.

Rock phosphate is a non-renewable primary source for mineral phosphorus (P) fertilizers that intensive agriculture is highly dependent on. To avoid P fertilizer shortages and limit negative environmental impacts, circular economy approaches are needed with recycling-derived fertilizer (RDF) applications. Here, a grassland field trial was established with two struvites (potato wastewater, municipal wastewater) and two ashes (poultry-litter ash, sewage-sludge ash) at a P application rate of 40 kg P ha(-1) (replicates n = 5). The impact of these RDFs on the soil microbial P cycling community was compared to conventional mineral P-fertilizer and a P-free control. Topsoil samples were taken directly after Lolium perenne grass cuts at months 3, 5 and 15. Cultivable phosphonate and phytate utilizing bacteria, potential acid and alkaline phosphomonoesterase activity, and phoC and phoD copy numbers responded stronger to seasonal effects than treatment effects. No significant overall effect of the fertilizer application was detected in the beta-diversity of the bacterial and fungal communities after 15 months, but individual phylogenetic taxa were affected by the treatments. The ash treatments resulted in significantly higher relative abundance of Bacillota and Rokubacteria and lower relative abundance of Actinomycetota. Sewage-sludge ash had significantly lowest abundances of genera Bacillus and Bradyrhizobium that are well known for their P cycling abilities. The struvite RDFs either positively influenced the P cycling microbial community as demonstrated through higher tri-calcium phosphate solubilizing capabilities (month 3), or were similar to the superphosphate and P-free treatment. From a soil-microbial health perspective, the presented findings indicate that struvites are a suitable substitute for superphosphate fertilizers.

Water-induced disintegration is a critical issue in soil stabilization. In this study, soda residue (SR) and fly ash (FA) were mixed to improve the properties of high liquid limit clay (HLC), forming soda residue-fly ash stabilized clay (SRFSC), with cement and/or lime for further stabilization. The mix proportions of the SRFSC were optimized by the orthogonal method, using the compaction, unconfined compressive strength, shear, and disintegration tests. Meanwhile, microscopic tests were performed to reveal the possible mechanical mechanisms. The results showed that the SR and FA content are the primary determinants influencing the mechanical properties of SRFSC. When the base proportion is 70 % SR + 20 % FA + 10 % HLC, the strength is highest (2.45 MPa). At this proportion, the specimen with no cementitious material exhibits the best water disintegration resistance (WDR), reaching 107 min. Adding cement and lime can significantly enhance the WDR of the SRFSC, from complete disintegration at 0.28 min to remaining intact after soaking for 28 days. During field application, the cementitious materials content can be adjusted according to the actual conditions. The superior mechanical properties and WDR of SRFSC are mainly due to the good gradation and dense microstructure. The soda residue can provide abundant Ca2+ to enhance both the mechanical properties and WDR of SRFSC.

With the increasing utilization of underground space, engineering muck has become a potential urban risk. This study employed a waste-to-waste strategy to promote its low-carbon recycling by using rice husk ash (RHA) as a stabilizer, with a focus on elucidating the stabilization mechanisms through multi-scale analysis. The results showed that RHA synergized with cement, enhancing unconfined compressive strength and water stability, while reducing the specific surface area and swelling potential of the engineering muck. The optimal RHA dosage was found to be between 4 % and 6 %, with cement content ranging from 3 % to 9 %. The multi-scale analysis demonstrated that the stabilization mechanisms of RHA-cement stabilized soil were governed by two main factors: structural enhancement and surface modification, both of which were driven by the promotion of novel hydration products through the incorporation of RHA. Specifically, the needle-like and columnar minerals effectively filled soil pores, forming a dense, robust skeletal structure that enhanced the mechanical properties of the stabilized soil. Meanwhile, the honeycomb-like C-S-H gel adhered to soil particle surfaces, repairing cracks and reinforcing interparticle bonding, thus improving the overall structural integrity. AFM analysis further revealed that the honeycomb-like C-S-H gel consisted of rod-like nanoparticles that were regularly arranged on the soil surface. This feature increased surface roughness, reduced fractal dimensions, and created a multi-scale structure of micro-papillae and nano-hairs with a lotus leaf effect, significantly enhancing the hydrophobic properties of the soil.

Red mud is a kind of solid waste, which can be used as engineering roadbed filler after proper treatment. Due to the special physical and chemical properties of red mud, such as high liquid limit and high plasticity index, it may affect the stability of soil. Therefore, red mud can be improved by adding traditional inorganic binders such as lime and fly ash to improve its road performance as roadbed filler. Red mud-based modified silty sand subgrade filler will be affected by dry-wet alternation caused by various factors in practical application, thus affecting the durability of the material. In order to study the strength degradation characteristics and microstructure changes of red mud, lime and fly ash modified silty sand subgrade filler after dry-wet cycle, the samples of different curing ages were subjected to 0 similar to 10 dry-wet cycles, and their compressive strength, microstructure and environmental control indexes were tested and analyzed. The results show that the sample cured for 90 days has the strongest toughness and the best ability to resist dry and wet deformation. With the increase of the number of dry-wet cycles, the mass loss rate of the sample is in the range of 6 similar to 7 %, and the unconfined compressive properties and tensile properties decrease first and then increase. There are continuous hydration reactions and pozzolanic reactions in the soil, but the degree of physical damage in the early stage of the dry-wet cycle is large, and the later cementitious products have a certain offsetting effect on the structural damage. The internal cracks of the sample without dry-wet cycle are less and the structure is dense. After the dry-wet cycle, the microstructure of the sample changed greatly, and the cracks increased and showed different forms. Through SEM image analysis, it was found that the pore structure of the sample changed during the dry-wet cycle, which corresponded to the change law of mechanical properties. After wetting-drying cycles, the leaching concentration of heavy metals in the modified soil increased slightly, but the overall concentration value was low, which was not a toxic substance and could be used as a roadbed material. The study reveals the influence of dry-wet cycle on the strength characteristics and microstructure of red mud, lime and fly ash synergistically improved silty sand, which provides a technical reference for the engineering application of red mud-based materials.

This study investigates the influence of wood pellet fly ash blended binder (WABB) on the mechanical properties of typical weathered granite soils (WS) under a field and laboratory tests. WABB, composed of 50 % wood pellet fly ash (WA), 30 % ground granulated blast furnace slag (GGBS), and 20% cement by dry mass, was applied at dosages of 200-400 kg/m3 to four soil columns were constructed at a field site deposited with WS. After 28 days, field tests, including coring, standard penetration tests (SPT), and permeability tests, revealed enhanced soil cementation and reduced permeability, indicating a denser soil matrix. Unconfined compressive tests (UCT) and free-free resonant column (FFRC) tests on field cores at 28 and 56 days, compared with laboratory specimens and previously published data, demonstrated strength gains 1.2-2.1 times higher due to field-induced stress. The presence of clay minerals influenced the WABB's interaction and microstructure development. Correlations between seismic waves, small-strain moduli, and strength were developed to monitor in-situ static and dynamic stiffness gain of WABB-stabilized weathered granite soils.

Geopolymers are recently recognized as superior sustainable alkali-activated materials (AAMs) for soil stabilization because of their strong bonding capabilities. However, the influence of freeze-thaw cycles (FTCs) on the performance of geopolymer-stabilized soils reinforced with fibers remains largely unexplored. In the current study, for the first time, the durability of polypropylene fiber (PPF) reinforced clayey soil stabilized with fly ash (FA) based geopolymer is investigated under FTCs, evaluating its performance during prolonged seasonal freezing. The effects of repeated FTCs (0, 1, 3, 6, and 12 cycles), different contents of alkali-activated FA (5 %, 10 %, and 15 %), varying PPF percentages (0 %, 0.4 %, 0.8 %, and 1.2 % with a length of 6 mm), and curing time (7 and 28 days) on the properties of stabilized samples have been determined through tests including standard Proctor compaction, unconfined compressive strength (UCS), mass loss, scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), and Fourier transform infrared spectroscopy (FTIR). The results revealed that a 0.4 % PPF concentration maximized strength in FA-based geopolymer samples by restricting crack propagation, irrespective of FA content, number of FTCs, or curing time. However, higher PPF contents lowered UCS values and Young's modulus due to fiber clustering and increased failure strain, respectively. Generally, an initial increase in UCS, Young's modulus, and resilience modulus (MR) of stabilized samples occurred with more FTCs because of their dense structure, delayed pore formation, and continued geopolymerization process and followed by a constant or decreasing trend in strength after 6 (or 3 in some cases) FTCs due to ice expansion in created air voids. Longer curing time resulted in denser samples with improved resistance to FTCs, especially under 12 FTCs. Moreover, samples with 10 % alkali-activated FA demonstrated the least susceptibility to FTCs. While initial FTCs caused no mass loss, subsequent cycles led to increased mass loss and remained below 2 % for all samples. Microstructural analysis results corroborated UCS test results. Although the primary chemical composition remained unchanged after 12 FTCs, these cycles induced morphological changes such as critical void formation and cracking within the gel structure. The stabilization approach proposed in this study demonstrated sustained UCS after 12 FTCs, promising reduced maintenance costs and extended service life in regions with prevalent freeze-thaw damage.

This paper aims to enhance the effective utilization of construction solid waste renewable brick powder (RBP) and circulating fluidized bed fly ash (CFBFA), addressing the issues of resource consumption and environmental pollution associated with these two types of solid waste. It employs CFBFA to synergistically activate RBP for the preparation of solid waste-based earthwork subgrade backfill. This research examines the impact of RBP and CFBFA content on the performance of earthwork subgrade backfill (ESB), while the microstructure of the paste test block was investigated using XRD, SEM, FTIR, and TG-dTG techniques. The synergistic mechanism of multisolid waste was examined at the micro level, and the appropriate ratio of solid waste-derived lowcarbon ESB was thoroughly assessed. The findings indicate that an increase in the CFBFA content generally enhances the mechanical strength of the paste. At the experimental ratio of RBP: CFBFA: coarse-grained soil = 8: 32: 60, the 28-day unconfined compressive strength (UCS), California Bearing Ratio (CBR) value, rebound modulus value, shear strength value, and compression modulus value of the sample attain their maximums, measuring 5.3 MPa, 41.9 %, 71.9 MPa, 10.5 KPa, and 15.76 MPa, respectively, all exceeding the standard values. The hydration products of cementitious materials based on RBP and CFBFA mostly consist of C-S-H gel, ettringite (AFt), and calcite. The robust honeycomb gel structure, created by the staggered interconnection of C-S-H gel and ettringite, is the primary contributor to mechanical strength. The modified cementitious material, composed of RBP-CFBFA, exhibits effective cementation and solidification properties for heavy metals, achieving leaching concentrations that comply with Class III water standards as outlined in the Chinese standard GB/T 14848-2017.