This paper presents a constitutive model for biotreated sand, developed within the framework of thermodynamic theory, to describe its mechanical behavior under undrained shear conditions. The model incorporates a reinforcement index and a hardening index to account for bonding effects. Undrained triaxial shear tests are conducted to validate the constitutive model. The results demonstrate the model's capacity to accurately predict the undrained shear behavior of biotreated sand under various reinforcement levels and initial confining pressures. It effectively captures the evolution of deviatoric stress, pore pressure, and stress paths. Furthermore, the model accounts for energy dissipation and the degradation of inter-grain bonding during undrained shearing, providing a theoretical foundation for the engineering application of biotreated sand.

PurposeThis study aims to investigate the effects of root exudates on the aggregate stability and permeability of loess and to further reveal the mechanisms of vegetation in preventing and controlling soil erosion beyond mechanical effects.Materials and methodsWetting tests were conducted to investigate how loess aggregate stability varies with curing time and root exudate concentration; and infiltration tests were carried out to examine the influence of root exudates on the infiltration characteristics of loess with varying degrees of compaction.Results and discussionThe results showed that the stability of loess aggregates significantly increased due to the application of root exudates. Curing could enhance the stabilizing effects of root exudates on loess aggregates; however, there existed a critical curing duration. The application of root exudates reduced the stable infiltration rate and hydraulic conductivity of loess. However, untreated specimens under lower degrees of compaction exhibited lower stable infiltration rate and hydraulic conductivity due to local structural damage. The stable infiltration rate of both treated and untreated specimens decreased with curing time.ConclusionsThe effects of root exudates can be attributed to their ability to function as stabilizing agents and promote aggregation, due to their high adsorption capacities and negatively charged groups on their surfaces. On the other hand, the presence of root exudates can significantly enhance the soil microbial activity, the microorganisms and their hyphae further strengthen the soil structure, fill pores and increase the soil hydrophobicity, thereby improving the aggregate stability while reducing the soil permeability.

The experimental studies were performed to examine the failure mechanism and the capacity of BFRP bolt-anchorage system under laboratory and field conditions in supporting clay slopes in Sichuan Basin, China. The results indicate that BFRP anchor bolts, designed based on the principle of equal strength replacement between bolt tensile strength and the bonding strength of the first interface, can meet the safety standards required for slope engineering. During the stable phase of the slope, the mechanical behavior and deformation characteristics of BFRP anchor bolts are comparable to those of steel anchor bolts, with the axial force of BFRP bolts being 1/3 to 1/4 lower than the designed value. When the slope enters the accelerated creep stage, the axial force of steel anchor bolts exceeds the designed value by 40 %, while the axial force of BFRP bolts remains at only 2/3 of that of steel bolts. The failure mechanisms of the BFRP bolt-anchorage system primarily involve shear failure at the bolt-mortar interface and pullout failure of the bolt body, which are attributed to the cumulative damage of the polymer material. Based on the experimental findings, it is recommended that the minimum tensile safety factor for BFRP bars used in temporary slope support should be set at 1.26. This study enhances the understanding of BFRP anchorage systems in clay soil environments and provides valuable insights for the design and construction of infrastructure projects in similar geological conditions.

In order to overcome the obstacles of poor wear resistance and complex preparation process of the traditional tillage soil-engaging parts, this study presents a powder laying-feeding multi-material additive manufacturing method based on selective laser melting (SLM), to fabricate the heterogeneous material tillage parts with 316 L stainless steel (316 L) as the part-body and high entropy alloys (HEAs)-diamond composites as the part-blade. The microstructures including SLM forming quality, interfacial bonding of heterogeneous material, graphitization of diamond and interfacial behavior of diamond/HEAs matrix are systematically investigated. The results indicate that, adopting medium laser energy density 79.4 J/mm(3) of the composites during same-layer deposition, the overlapping area of 316 L/composites exhibits metallurgical bonding with high relative density of the composites section. Only slight graphitization of diamond happens and similar to 2 mu m width diffusion zone forms between diamond and HEAs matrix, without harmful carbide formation. Moreover, compared with commercial 65Mn steel, the wear resistance (wear mass loss rate) and corrosion resistance (corrosion current density) of HEAs-diamond composites have been decreased by 28 times and 230 times, respectively. The hetero-material 316L-composites exhibits good interfacial bonding strength of 432.3 MPa with elongation of 11.2 %. This study not only results in a novel solution of tillage wear-resisting parts, but also provides a multi-material additive manufacturing technology for metallic heterogeneous components.

The development of continuously degradable and recyclable polymeric composites with superb mechanical properties, which can extend the service life of materials and reduce the environmental impact, will make a significant contribution to global sustainability. In this study, poly(vinyl alcohol) (PVA)-based composites (DPVA-Fe-TA) with degradability, recyclability and excellent mechanical properties are prepared by complexation of 3,4-dihydroxybenzaldehyde-grafted PVA (D-PVA), tannin (TA) and Fe3+ ions in dimethyl sulfoxide (DMSO), and then dialysis in deionized water and glycerol (Gly). The two-step dialysis process, playing a crucial role in reducing the free water of D-PVA-Fe-TA composites, enhances the formation of reversible of hydrogen-bonding and the reinforcement of self-assembled Fe(3+)chelation between TA and D-PVA, and facilitates the fabrication of PVA-based composites with a breaking strength of approximate to 18.7 MPa, an elongation at break of similar to 812 % and a toughness of approximate to 86.81 MJ/m(3); Meanwhile, the resulting homogeneous and dense structure of D-PVA-Fe-TA composites hinders the penetration of Gly solution, thereby enhancing the bonding strength and environmental adaptability of D-PVA-TA-Fe composites within the temperature range of-20 degrees C to 60 degrees C. Furthermore, the as- prepared D-PVA-TA-Fe composites exhibit recyclability for multiple cycles. When placed under soil culture medium, the resulting composites can be degraded without the need for manual interference. This study presents a novel strategy for the fabrication of materials possessing excellent mechanical strength, environmental adaptability, recyclability and degradation, which have great potential for taking the place of conversional composites in specific conditions.

The evolution of loess microstructure exerts a direct impact on its collapse evolution during dry and wet (DW) cycles. In this study, a hydro-mechanical coupling numerical model considering DW cycles and mechanical loading was established by extending the Barcelona Basic model, meanwhile combining with the test results to reveal the effect of DW cycling on the collapse deformation and strength response of loess. Additionally, the microscopic mechanism of loess collapse evolution was revealed through microscopic tests. Results indicated DW cycles caused the net compaction of loess, with the first DW cycle exerting the most significant effect on its deformation, consequently deteriorating the loess. Wetting under constant loading leads to a collapse of macrostructures formed by aggregates. Moreover, DW cycles transformed the structural units from line and surface contact to point. The basic structural units exhibited obvious grade properties, in which DW cycles trigger the collapse of compound aggregates, with the number of relatively stable mononuclear aggregates and intergranular pores increasing. DW cycles in an open environment induced the loss of cementing materials such as soluble salts and reduced the bonding strength among basic structural units. This subsequently tended to weaken the structural properties of loess and decreased the mechanical properties.

Three soft rock facies of the Middle Globigerina Limestone (MGL) from Malta, of mineralogical composition and index properties similar to some medium -high density Chalk facies, are disaggregated through prolonged agitation in water to create reconstituted samples. The significant activity of their clay-sized calcite grains can impart a medium -high plasticity. Scanning electron microscopy analyses of natural and reconstituted samples show the natural bonding as interlock, possibly induced by cohesive clay-sized calcite grains during the sediment compaction. Micro-analyses and compression test data also show that local calcite crystal overgrowth under burial has reduced further the soft rock porosity, making it lower than that of the reconstituted material one-dimensionally compressed to the geological preconsolidation pressure. Nonetheless, the low stress sensitivity of natural MGL suggests that this interlock bonding does not strengthen much the material with respect to the highly compressed reconstituted soil. The natural MGL is of very low permeability, which reduces further with compression. Concurrently, the soft rock creep coefficient increases, reaching values far above those typical for clays. The microstructural features and the mechanical properties of the different MGL facies are shown to be sensitive to clay mineral content.

We present a novel multiscale framework that integrates the single -point multiphase material point method (MPM) and the discrete element method (DEM) to model the complex freeze -thaw behavior of ice -bonded granular media. The proposed numerical framework is featured by (a) employing the continuum -based MPM to solve the macroscopic governing equations for granular systems involving thermo-hydro-mechanical (THM) coupling and phase transitions, and (b) using the grain -scale discontinuum-based DEM to capture the thermodynamically sensitive mechanical behaviors of ice -bonded granular media. The multiscale framework is constructed by attaching a DEM-based representative volume element (RVE) at each material point in MPM. This RVE serves as a live sample of each material point to track the state -dependent effective stress with respect to the local deformation and thermodynamic conditions like ice saturation, bridging the macroscopic phenomena and the underlying microstructural evolution. In particular, we implement a semiimplicit staggered integration scheme for the macroscale THM-coupled MPM to boost computational efficiency and enhance numerical stability. We also propose an innovative ice saturation -dependent bond contact to effectively reproduce the thermodynamically sensitive mechanical behaviors. The new multiscale framework is first benchmarked against analytical solutions for 1D non -isothermal consolidation problems. We then demonstrate its exceptional capability in simulating intricate freeze -thaw behavior of granular media through a boundary value problem involving cyclic freeze -thaw actions. Further cross -scale analyses reveal its potential in capturing key loading- and state -dependent THM responses with explainable microstructural mechanisms during complex freezing and thawing loading conditions.

The effect of several prevalent cations (including Na+, K+, Mg2+, Ca2+, Al3+, and Fe3+) on the adsorption of monochlorobenzene (MCB) onto bentonite was investigated at the coexistence of nonionic surfactant Tween 80 (T80) in surfactant-enhanced remediation (SER). They are all favorable for MCB and T80 adsorption, especially Mg2+ and Ca2+. Adsorption of MCB is strongly depended on T80 micelles. When its concentration exceeds the solubility, MCB is easier to bind with T80 micelles and be adsorbed by bentonite. Acidic environment can facilitate MCB and T80 adsorption, but the effect of cations on the adsorption is most significant under alkaline conditions. Adsorption capacity of MCB increases first followed by a slight decrease with increasing cations concentrations. The maximum adsorption rate of MCB determined is about 68.4% in a solution containing Mg2+ in the isothermal adsorption of MCB, while it is only 6.8% in a cation -free solution. Various characterizations showed that cations mainly changed the repulsion between bentonite particles and T80 micelles and the agglomeration and structure of bentonite, thus affecting the adsorption of MCB and T80 micelles. Our research demonstrated the nonnegligible promotion of MCB adsorption on bentonite by cations and acidic environment, which will adversely affect SER efficiency.

In this paper, pectin-based plastic films were developed by grafting vanillin to pectin chains and introducing Fe3+ ions. The mechanical properties, thermal stability, moisture resistance, UV-light barrier property, biodegrad-ability, and practical application of fabricated plastic film were evaluated. Results confirmed the successful grafting of vanillin and the presence of hydrogen bonds and metal-ligand bonds, giving the plastic film highest fracture stress of 41.68 +/- 4.10 MPa, which was nearly 481.31% enhancement than that of neat pectin film. Additionally, the thermal stability, moisture resistance, and UV-blocking property (200-400 nm) of fabricated plastic film were significantly improved. Moreover, the plastic film exhibited satisfying processability, which can be processed to bag and appearing excellent food preservation ability. After use, the plastic film can be completely biodegradable in soil (degradation time approximate to 7 weeks) and seawater without manual interference. Thus, our proposed pectin-based plastic film can be recommended as a non-polluting and sustainable food packaging substitute.