The present paper sets out a comparative analysis of carbon emission and economic benefit of different performance gradients solid waste based solidification material (SSM). The macro properties of SSM were the focus of systematic study, with the aim of gaining deeper insight into the response of the SSM to conditions such as freeze-thaw cycles, seawater erosion, dry-wet cycles and dry shrinkage. In order to facilitate this study, a range of analytical techniques were employed, including scanning electron microscopy (SEM), X-ray diffraction (XRD) and mercury intrusion porosimetry (MIP). The findings indicate that, in comparison with cement, the carbon emissions of SSM (A1) are diminished by 77.7 %, amounting to 190 kg/t, the carbon-performance ratio (24.4 kg/ MPa), the cost-performance ratio (32.1RMB/MPa) and the carbon-cost ratio (0.76kg/RMB) are reduced by 86 %, 56 % and 68 % respectively. SSM demonstrated better performance in terms of freeze-thaw resistance, seawater erosion resistance and dry-wet resistance when compared to cement. The dry shrinkage value of SSM solidified soil was reduced by approximately 35 % at 40 days compared to cement solidified soil, due to compensatory shrinkage and a reduction in pores. In contrast to the relatively minor impact of seawater erosion and the moderate effects of the wet-dry cycle, freeze-thaw cycles have been shown to cause the most severe structural damage to the micro-structure of solidified soil. The conduction of durability tests resulted in increased porosity and the most probable aperture. The increase in pores and micro-structure leads to the attenuation of macroscopic mechanical properties of SSM solidified soil. The engineering application verified that with the content of SSM of 50 kg/m, 4.5 % and 3 %, the strength, bearing capacity and bending value of SSM modified soil were 1.9 MPa, 180 kPa and 158, respectively in deep mixing piles, shallow in-situ solidification, and roadbed modified soil field.

Structures constructed on collapsible soil are prone to failure under flooding. Agro-waste like rice husk ash (RHA) and its geopolymer (LGR), consisting of lime (L), RHA, water glass (Na2SiO3), and caustic soda (NaOH), present a potential solution to address this issue. RHA and LGR were mixed up to 16% to improve the collapsible soil. Samples were remolded at optimal water content and maximum dry density for strength and collapsible potential tests. Unconfined compressive strength, deformation modulus, and soaked California bearing ratio exhibit exponential improvement with the inclusion of LGR. Additionally, for comparison of microstructural characteristics, analyses involving energy-dispersive X-ray spectroscopy (EDAX) and scanning electron microscope (SEM) were conducted on both virgin and treated specimens. LGR resulted in the emergence of new peaks of sodium silicates and calcium silicates, as indicated by EDAX. The formation of H-C-A-S gel and H-N-A-S gel observed in SEM suggests the development of bonds among soil particles attributed to geopolymerization. SEM reveals the transformation of the inherent collapsible soil from a dispersed and silt-dominated structure to a reticulated structure devoid of micro-pores following the incorporation of LGR. A numerical model was constructed to forecast the performance of both virgin and stabilized collapsible soils under pre- and post-flooding conditions. The outcomes indicate an enhancement in the soil's bearing capacity upon stabilization with 12% LGR. The implementation of 12% LGR significantly resulted in a lower embodied energy-tostrength ratio, emissions-to-strength ratio, and relatively lower cost-to-strength ratio compared to the soil treated with 16% cement kiln dust (CKD). (c) 2025 Institute of Rock and Soil Mechanics, Chinese Academy of Sciences. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/

Precipitation comes in various phases, including rainfall, snowfall, sleet, and hail. Shifts of precipitation phases, as well as changes in precipitation amount, intensity, and frequency, have significant impacts on regional climate, hydrology, ecology, and the energy balance of the land-atmosphere system. Over the past century, certain progress has been achieved in aspects such as the observation, discrimination, transformation, and impact of precipitation phases. Mainly including: since the 1980s, studies on the observation, formation mechanism, and prediction of precipitation phases have gradually received greater attention and reached a certain scale. The estimation of different precipitation phases using new detection theories and methods has become a research focus. A variety of discrimination methods or schemes, such as the potential thickness threshold method of the air layer, the temperature threshold method of the characteristic layer, and the near-surface air temperature threshold method, have emerged one after another. Meanwhile, comparative studies on the discrimination accuracy and applicability assessment of multiple methods or schemes have also been carried out simultaneously. In recent years, the shift of precipitation from solid to liquid (SPSL) in the mid-to-high latitudes of the Northern Hemisphere has become more pronounced due to global warming and human activities. It leads to an increase in rain-on-snow (ROS) events and avalanche disasters, affecting the speed, intensity, and duration of spring snow-melting, accelerating sea ice and glacier melting, releasing carbon from permafrost, altering soil moisture, productivity, and phenological characteristics of ecosystems, and thereby affecting their structures, processes, qualities, and service functions. Although some progress has been made in the study of precipitation phases, there remains considerable research potential in terms of completeness of basic data, reliability of discrimination schemes, and the mechanistic understanding of the interaction between SPSL and other elements or systems. The study on shifts of precipitation phases and their impacts will play an increasingly important role in assessing the impacts of global climate change, water cycle processes, water resources management, snow and ice processes, snow and ice-related disasters, carbon emissions from permafrost, and ecosystem safety.

The Qinghai-Tibet Plateau (QTP) has an extensive frozen soil distribution and intense geological tectonic activity. Our surveys reveal that Qinghai-Tibet Plateau earthquakes can not only damage infrastructure but also significantly impact carbon dioxide emissions. Fissures created by earthquakes expose deep, frozen soils to the air and, in turn, accelerate soil carbon emissions. We measured average soil carbon emission rates of 968.53 g CO2 m(-2).a(-1) on the fissure sidewall and 514.79 g CO2 m(-2).a(-1) at the fissure bottom. We estimated that the total soil carbon emission flux from fissures caused by M >= 6.9 earthquakes on the Qinghai-Tibet Plateau from 326 B.C. to 2022 is 1.83 x 10(12) g CO2 a(-1); this value is equivalent to 0.51% similar to 1.48% and 2.34% similar to 5.14% of the increased annual average carbon sink resulting from the national ecological restoration projects targeting forest protection and grassland conservation in China, respectively. These earthquake fissures thus increased the soil carbon emission rate by 0.71 g CO2 m(-2).a(-1) and significantly increased the total carbon emissions. This finding shows that repairing earthquake fissures could play a very important role in coping with global climate change.

Reducing agricultural carbon emissions (ACEs) is critical to achieving green agriculture in China. Chinese agriculture has long faced the dilemma of large numbers of people and small landholdings, well as low-quality arable land. As a result, agricultural production relies heavily on inputs of agricultural chemicals to boost yields, damaging the rural environment. In this study, we use provincial panel data from China and a spatial difference-in-differences model to explore the influence of rural land consolidation policy (RLCP) on ACEs and their spatial spillover effects. The results show that the global Moran's of ACEs reflected a downward trend, the spatial correlation gradually weakened, and ACEs developed from a state of polarization to one of balance. RLCP has had a significant reduction and a negative spatial spillover effect on ACEs. Our analysis of the mechanism shows that rural land consolidation promoted the reduction of ACEs by improving the quality of farmland soil and the utilization rate of water resources. Under different geographical conditions, the construction of rural land consolidation has had a significant ACE reduction effect on both the south and the north, although RLCP in southern China has had a negative spatial spillover effect.

Copper smelting slag (CSS) are waste slag obtained from smelters after reusing sulphur smelting slag. This study explores the potential of CSS to serve as a resource in cement mortar construction. Specifically, the study investigates the use of mechanical and chemical methods to enhance the volcanic ash activity of CSS, enabling them to replace up to 30 % of the cement content in cement mortar. The modified CSS was analyzed in terms of particle size and (Toxicity Characteristic Leaching Procedure) TCLP testing, while cement mortar specimens were subjected to a battery of tests including compressive strength, Freeze-thaw experiment, TCLP testing and cement stability testing. The results showed that compared with the unmodified CSS material, the copper smelting slag cement material with CaCO3 3 meets the requirements of GB/T 1596-2017 on the standard compressive strength of OPC 42.5 grade, with a compressive strength of 38.88 MPa at 10 % CaCO3 3 admixture, among which the CSS cement material with 10 % CaCO3 3 is the best and meets the leaching toxicity standard. Moreover, the modified CSS reduced energy consumption by 7.15 %, CO2 2 emissions by 27.41 %, and cost by 19.84 %. XRD, FTIR and SEM analysis showed that the mechanical activation of CaCO3 3 doping more drastically damaged the crystal structure of CSS, and local lattice distortion occurred, which induced the transformation of CSS from crystalline phase to amorphous phase and destroyed the ordered structure of minerals, resulting in the volcanic ash activity increased. Overall, this study demonstrates that CSS can serve as a viable raw material in cement mortar samples, reducing environmental impact and achieving resourceful use of slag.

Recycled concrete aggregate (RCA) is a voluminous solid waste material derived from the construction sector and is typically stockpiled in landfills. In recent years, the ground improvement industry has grappled with challenges stemming from the depletion of natural quarry materials, resulting in a skyrocketing of their prices and increased project costs. This research investigated the feasibility of using RCA stabilized by one-part geopolymers to produce an innovative semi-rigid inclusion column system for ground improvement of soft soils. Na2SiO3anhydrous was used as a sole solid activator for the activation of fly ash (FA), slag (S) or a binary precursor (FA+S) in the stabilization of RCA. The unconfined compressive strength (UCS) and microstructure of the stabilized mixtures have been examined with respect to different binder formulations and curing conditions. The permanent deformation characteristics of mixtures under cyclic loading were evaluated through repeated load triaxial (RLT) tests to replicate the moving wheel loads imposed on the semi-rigid inclusion columns. In addition, the cost and environmental impacts of the optimum mixtures suggested in this research were studied. The test results indicated that stabilizing RCA with as low as 5% one-part alkali-activated FA, S or (FA+S) met the minimum strength requirement (1.034 MPa) for ground improvement work. Compared with standalone FA and S geopolymer stabilized RCA mixtures, (FA+S) geopolymer stabilized RCA mixtures were identified as preferred industrial formulations due to their prolonged setting time for ease of mixing and handling when used in stone column applications. It was found that curing temperature and duration played a pivotal role in the strength gain of the mixtures. The RLT test results demonstrated that implementing the optimum RCA + 5%(FA+S) mixture as identified in this study for semi-rigid inclusion columns, led to a reduction in permanent strain values by approximately 90% compared to conventional unbound stone columns. The comparison between the optimum mixture highlighted in this study with other stabilization methods showed that the semi-rigid inclusion columns had great potential to enable large-scale production, cost and emission reduction in future ground improvement projects.

Quantitatively evaluating the ecological environment impacts of vegetation destruction due to open-pit mining activities is vital for enhancing the green mining standard and cost management capabilities of mining enter-prises. Based on the Landsat time series, this study proposes an ecological environment impact assessment and quantitative characterization method for vegetation destruction in mining areas resulting from open-pit mining activities. First, the modified normalized difference water index and the normalized difference vegetation index time series data were calculated. The water body thresholds and the fraction of vegetation coverage were ascertained using the K-means clustering algorithm and the dimidiate pixel model, respectively, to determine the area of direct vegetation destruction in mining areas. Second, utilizing the Theil-Sen Median trend analysis and the Mann-Kendall test, the indirect impact area of vegetation in the mining region was identified. Lastly, by integrating vegetation's net primary productivity with the Chinese Emission Allowance price index, the total carbon emission cost of vegetation destruction due to mining activities over 20 years was calculated to be about 2.122 million yuan. The findings indicated that the ecological environmental impact of open-pit mining activities on vegetation destruction cannot be ignored. From 2000 to 2020, open-pit mining at the Wulishan limestone mine in Anhui Province, China, increased the area of direct vegetation destruction by 9.072 x 105 m2, and the indirect impact area on vegetation was 7.371 x 105 m2. The carbon emission cost of vegetation destruction in the direct destruction area was about 104,000 yuan per year, and the carbon emission cost of vegetation damage in the indirect impact area was approximately 2,082.53 yuan per year. This research provides a scientific foun-dation for ecological environmental protection, regulations, green mining, and cost management for mining enterprises, promoting the harmonious progress of both the economy and environmental protection.

Variations in the chemical composition of geofluids and of gas fluxes are significant parameters for understandingmud volcanismand correctly estimate their emissions in carbon species, particularly greenhouse gas, methane. In this study, muddy water and gas samples were collected from the Anjihai, Dushanzi, Aiqigou, and Baiyanggou mud volcanoes in the southern Junggar Basin during the four seasons, around a year. This region hosts the most active mud volcanism throughout China. Gas and water were analyzed for major molecular compositions, carbon and hydrogen isotopes of the gas phase, as well as cations and anions, hydrogen and oxygen isotopes of water. The emitted gases are dominated by CH4 with some C2H6, CO2, and N-2. The seasonal changes in the chemical composition and carbon isotopes of emitted gases are not significant, whereas clear variations in the amounts of cations and anions dissolved in the water are reported. These are higher in spring and summer than autumn and winter. The CH4, CO2, and C2H6 fluxes are 157.3-1108 kg/a, 1.8-390.1 kg/a, and 10.2-118.7 kg/a, respectively, and a clear seasonal trend of the gas seepage flux has been observed. In January, the macro-seepage flux of open vents is >= 65% higher than in April, whereas the micro-seepage flux significantly decreased, probably due to the frozen shallow ground and blockage of soil fractures around the vents by heavy snow and ice during January. This probably causes an extra gas pressure transferred to the major vents, resulting in higher flux of the macro-seepage in the cold season. However, the total flux of the whole mud volcano system is generally consistent around a year.

Climate warming leads to widespread permafrost thaw with a fraction of the thawed permafrost carbon (C) being released as carbon dioxide (CO2), thus triggering a positive permafrost C-climate feedback. However, large uncertainty exists in the size of this model-projected feedback, partly owing to the limited understanding of permafrost CO2 release through the priming effect (i.e., the stimulation of soil organic matter decomposition by external C inputs) upon thaw. By combining permafrost sampling from 24 sites on the Tibetan Plateau and laboratory incubation, we detected an overall positive priming effect (an increase in soil C decomposition by up to 31%) upon permafrost thaw, which increased with permafrost C density (C storage per area). We then assessed the magnitude of thawed permafrost C under future climate scenarios by coupling increases in active layer thickness over half a century with spatial and vertical distributions of soil C density. The thawed C stocks in the top 3 m of soils from the present (2000-2015) to the future period (2061-2080) were estimated at 1.0 (95% confidence interval (CI): 0.8-1.2) and 1.3 (95% CI: 1.0-1.7) Pg (1 Pg = 10(15) g) C under moderate and high Representative Concentration Pathway (RCP) scenarios 4.5 and 8.5, respectively. We further predicted permafrost priming effect potential (priming intensity under optimal conditions) based on the thawed C and the empirical relationship between the priming effect and permafrost C density. By the period 2061-2080, the regional priming potentials could be 8.8 (95% CI: 7.4-10.2) and 10.0 (95% CI: 8.3-11.6) Tg (1 Tg = 10(12) g) C year(-1) under the RCP 4.5 and RCP 8.5 scenarios, respectively. This large CO2 emission potential induced by the priming effect highlights the complex permafrost C dynamics upon thaw, potentially reinforcing permafrost C-climate feedback.