Objective In coal mining regions, extensive coal dust is generated during mining, transportation, and storage, coupled with substantial black carbon produced resulting from incomplete coal combustion in the industry chain. Over time, these materials form absorbable substances, evolving into core- shell aerosols with inorganic salt shells. These aerosols, including sulfate, nitrate, and water, exert significant climate impacts through direct and indirect radiation effects. The environmental and radiative forcing effects are substantial. Absorbing aerosol demonstrates strong solar radiation absorption across the ultraviolet to infrared spectrum. However, past studies primarily focus on their optical properties in visible and infrared bands, overlooking ultraviolet band absorption. Current research often assumes a lognormal particle size distribution for absorbing aerosols, neglecting variations in distribution and optical properties resulting from diverse emission scenarios. Therefore, a thorough analysis of absorbing aerosol optical properties at local scales is crucial. Quantitative assessments of particle size distribution, mixing state, and spatio-temporal variations are vital for elucidating the intricate interactions with boundary layer development, radiative forcing changes, and air pollution. Methods In our study conducted in the coal mining area of Changzhi City, Shanxi Province, various datasets are collected, including surface black carbon concentration, particle size distribution, and columnar aerosol optical depth (AOD). The investigation commenced with the utilization of the variance maximization method to categorize AOD data into distinct pollution events. Subsequent analysis involved evaluating the particle size distribution corresponding to different pollution degrees through probability density functions. The uncertainty of particle size for the desorption aerosol core and shell is then determined by integrating black carbon mass concentration data and particle size distribution information. These uncertainties are then used as input parameters to run the Mie scattering model based on the core- shell structure. This process results in the inversion of the multi- band optical characteristic parameters of absorbing aerosol in the coal mining area. The computations are carried out under both the assumption of a uniform distribution and a non- uniform distribution, representing different mixing degrees of aerosols. To complete the picture, the uncertainty interval for the single scattering albedo (SSA) of absorbing aerosol was constrained through the application of absorption & Aring;ngstr & ouml;m exponent (AAE) theory. This comprehensive approach provides a nuanced understanding of the complex dynamics of absorbing aerosol in the specific context of coal mining environments. Results and Discussions In the coal mining area, absorbing aerosols are influenced by emission sources, manifesting a particle size distribution divergent from the lognormal model. Under various pollution conditions, robust peaks are discernible in smaller particle size ranges (0.28 -0.3 mu m), with weaker peaks present around 0.58 -0.65 mu m. The relative proportion between the two peaks fluctuates in tandem with the pollution severity (Fig. 3). Using the Mie scattering model, the optical characteristics of absorbing aerosol are inverted based on AOD information, black carbon mass concentration, and particle number concentration. Results indicate that under the assumption of a uniform distribution (Fig. 4), the average size of the core particles at 0.28, 0.58, and 0.7 mu m is relatively low, leading to corresponding patterns in SSA with changes in core particle size. Additionally, the average core particle size shows no significant variation with changes in wavelength in different size ranges. SSA decreases with increasing wavelength, with greater fluctuations in the smaller particle size range (0.25-0.58 mu m) and more stable changes in the larger particle size range (0.58-1.6 mu m). Under this assumption, the AAE theory is found to be inapplicable. In the case of a non- uniform distribution (Fig. 5), SSA values exhibit a slow, followed by a gradual and then rapid increase in the shortwave region, while in the longwave region, SSA first rapidly increases and then gradually levels off. For shorter wavelengths (500 nm and above), AAE theory proves effective for absorbing aerosol with smaller particle sizes. For longer wavelengths (675 nm and above), AAE theory is applicable to absorbing aerosol with moderate particle sizes. However, for larger particles such as coal dust, AAE theory is not suitable. It is noteworthy that, under both assumptions, the inversion results of SSA values in the longwave spectrum (such as 870 and 936 nm) are relatively lower compared to the shortwave spectrum (such as 440 and 500 nm). This discrepancy will lead to an underestimation of emission quantities. Conclusions We conduct on- site observations in the coal mining area of Changzhi City, Shanxi Province, aiming to capture the variation characteristics of AOD, particle concentration, and black carbon mass concentration. Utilizing the Mie scattering model based on the core- shell hypothesis, we simulate the SSA of absorbing aerosol under two different mixing states. Additionally, we calculate the optical variations of absorbing aerosol constrained by the AAE. The research findings reveal the following: 1) The particle size distribution of absorbing aerosol in the coal mining area deviates from the assumptions made in previous studies, which typically assumed single or double- peaked distributions. Influenced by emission sources, the characteristics vary under different pollution conditions. Smaller particles predominantly originate from the incomplete combustion of coal in local power plants and coking factories, producing black carbon. Larger particles stem from the aging processes of black carbon in the atmospheric environment and coal dust generated during coal transportation. 2) Comparison of the SSA variations under different mixing states simulated by the two hypotheses indicates that particle size, mixing state, and spectral range significantly impact the SSA of absorbing. In contrast to previous studies using the infrared spectrum, the present investigation reveals higher SSA values in the ultraviolet and visible light spectrum, suggesting a potential underestimation of black carbon emissions. 3) The AAE theory is applicable only to certain particle size ranges in different spectral bands. For large- sized absorbing aerosol in the coal mining area, using the AAE theory to estimate SSA introduces uncertainty, and applying the AAE assumption across all particle size ranges leads to an underestimation of emissions. These findings underscore that the distribution characteristics of SSA in absorbing aerosol do not strictly adhere to the power- law relationship of the AAE index but are collectively determined by particle size distribution, mixing state, and spectral range.

The Hola basin in the northern Da Xing'anling Mountains in Northeast China has been extensively developed for coal mining since the 1980s, resulting in a significantly degrading permafrost environment. However, the changing thermal state of permafrost under the boreal forest remains unclear. Based on ground temperature records from nine monitoring boreholes at three areas (disturbed, backfilled, and undisturbed areas) from 2015 to 2020, the thermal state of permafrost under the dual influences of climate change and human activities were evaluated. It is found that the temperatures at the depth of zero annual amplitude (T-ZAA) in the disturbed area increased by 0.2-0.5 degrees C during the past 6 years, turning the cold permafrost (T-ZAA <= -1.0 degrees C) into a warm one (-1 <= T-ZAA <= 0 degrees C). Additionally, the permafrost table was lowered by 0.8-7.0 m. As a result, subaerial supra-permafrost talik occurred. However, T-ZAA in the undisturbed areas lowered by 0.03-0.11 degrees C, possibly due to the lagged response of the local climate cooling during 2001-2010. In the meantime, T-ZAA rose sharply in the disturbed areas, indicating more significant influences of intense human activities on permafrost in comparison with that of climate change. As the permafrost degrades, the boreal permafrost eco-environment has changed dramatically, as revealed by the draining and drying up of the Yueya'hu Lake in the southern Hola basin. These results help reveal the physical mechanisms, evaluate the rates and amplitudes of environmental changes, and manage the boreal forest environment and resources in a sustainable manner.

The tropospheric NO2 concentration from OMI AURA always shows high concentrations of NO2 at a few locations in India, one of the high concentrations of NO2 hotspots is associated with the locations of seven coal-fired Thermal Power plants (TPPs) in Singrauli. Emissions from TPPs are among the major sources of black carbon (BC) soot in the atmosphere. Knowledge of BC emissions from TPPs is important in characterizing regional carbonaceous particulate emissions, understanding the fog/haze/smog formation, evaluating regional climate forcing, modeling aerosol optical parameters and concentrations of black carbon, and evaluating human health. Furthermore, elevated BC concentrations, over the Indo-Gangetic Plain (IGP) and the Himalayan foothills, have emerged as an important subject to estimate the effects of deposition and atmospheric warming of BC on the accelerated melting of snow and glaciers in the Himalaya. For the first time, this study reports BC concentrations and aerosol optical parameters near dense coal-fired power plants and open cast coal mining adjacent to the east IGP. In-situ measurements were carried out in Singrauli (located in south-east IGP) at a fixed site about 10 km from power plants and in transit measurements in close proximity to the plants, for few days in the month of January and March 2013. At the fixed site, BC concentration up to the 95 mu gm(-3) is observed with strong diurnal variations. BC concentration shows two maxima peaks during early morning and evening hours. High BC concentrations are observed in close proximity to the coal-fired TPPs (>200 mu gm(-3)), compared to the outside domain of our study region. Co-located ground-based sunphotometer measurements of aerosol optical depth (AOD) show strong spatial variability at the fixed site, with AOD in the range 0.38-0.58, and the highest AOD in the range 0.7-0.95 near the TPPs in transit measurements (similar to the peak of BC concentrations). Additionally, the Angstrom exponent was found to be in the range 0.4-1.0 (maximum in the morning time) and highest in the proximity of TPPs (similar to 1.0), suggesting abundance of fine particulates, whereas there was low Angstrom exponent over the surrounding coal mining areas. Low Angstrom exponent is characterized by dust from the unpaved roads and nearby coal mining areas. MODIS derived daily AOD shows a good match with the MICROTOPS AOD. The CALIPSO derived subtypes of the aerosol plot shows that the aerosols over Singrauli region are mainly dust, polluted dust, and elevated smoke. The preliminary study for few days provides information about the BC concentrations and aerosol optical properties from Singrauli (one of the NO2 hotspot locations in India). This preliminary study suggests that long-term continuous monitoring of BC is needed to understand the BC concentrations and aerosol optical properties for better quantification and the estimation of the emission to evaluate radiative forcing in the region.