The temporal variability of microphysical parameters of pyrolysis smoke, retrieved by inverting the characteristics of aerosol scattering and extinction, has been studied. The polarization scattering phase functions and spectral extinction coefficients were measured for 65 hours in smoke aerosols produced from thermal decomposition of pine wood during low-temperature pyrolysis in the Big Aerosol Chamber (BAC) of Institute of Atmospheric Optics, Siberian Branch, Russian Academy of Sciences. The microstructure parameters (volume concentration and mean radius of particles with division into fine and coarse fractions) and the complex refractive index of pyrolysis smoke are retrieved following the developed algorithm for inverting optical measurements. The real part of the refractive index is found to be in the vicinity of n = 1.55, and the imaginary part is in the range 0.007 < kappa < 0.009; the mean radius of fine particles varies in the narrow range 0.137-0.146 mu m. During smoke aging, the particle ensemble-mean radius monotonically increased from 0.19 to 0.6 mu m mainly due to a relative increase in the content of coarse aerosol. Results of this work are important for estimation of the radiative forcing of aerosol and improvement of climate models and algorithms of remote optical sounding.

Dust aerosol has an impact on both the regional radiation balance and the global radiative forcing estimation. The Taklimakan Desert is the focus of the present research on the optical and micro-physical characteristics of the dust aerosol characteristics in Central Asia. However, our knowledge is still limited regarding this typical arid region. The DAO-K (Dust Aerosol Observation-Kashgar) campaign in April 2019 presented a great opportunity to understand further the effects of local pollution and transported dust on the optical and physical characteristics of the background aerosol in Kashgar. In the present study, the consistency of the simultaneous observations is tested, based on the optical closure method. Three periods dominated by the regional background dust (RBD), local polluted dust (LPD), and Taklimakan transported dust (TTD), are identified through the backward trajectories, combined with the dust scores from AIRS (Atmospheric Infrared Sounder). The variations of the optical and micro-physical properties of dust aerosols are then studied, while a direct comparison of the total column and near surface is conducted. Generally, the mineral dust is supposed to be primarily composed of silicate minerals, which are mostly very weakly absorbing in the visible spectrum. Although there is very clean air (with PM2.5 of 21 mu g/m(3)), a strong absorption (with an SSA of 0.77, AAE of 1.62) is still observed during the period dominated by the regional background dust aerosol. The near-surface observations show that there is PM2.5 pollution of similar to 98 mu g/m(3), with strong absorption in the Kashgar site during the whole observation. Local pollution can obviously enhance the absorption (with an SSA of 0.72, AAE of 1.58) of dust aerosol at the visible spectrum. This is caused by the increase in submicron fine particles (such as soot) with effective radii of 0.14 mu m, 0.17 mu m, and 0.34 mu m. The transported Taklimakan dust aerosol has a relatively stable composition and strong scattering characteristics (with an SSA of 0.86, AAE of similar to 2.0). In comparison to the total column aerosol, the near-surface aerosol has the smaller size and the stronger absorption. Moreover, there is a very strong scattering of the total column aerosol. Even the local emission with the strong absorption has a fairly minor effect on the total column SSA. The comparison also shows that the peak radii of the total column PVSD is nearly twice as high as that of the near-surface PVSD. This work contributes to building a relationship between the remote sensing (total column) observations and the near-surface aerosol properties, and has the potential to improve the accuracy of the radiative forcing estimation in Kashgar.

The impact of Brown Carbon (BrC) to aerosol light absorption has been paid more attention recently and there are a large number of studies showing that the influence of BrC on radiative forcing should not be ignored. BrC also acts as an important component of haze pollution which is occurring frequently in Wuhan, China. Therefore, it is essential to estimate their optical properties, composition, and mass concentration. Considering most haze pollution happens during the coldest time, we retrieved BrC columnar content during winter in Wuhan for the first time. Our method bases on the fact that BrC showed the strong spectral dependence on UV-light absorption. Using this method, we found that BrC makes up the small proportions of total aerosol volume (less than 10%). In the winter of 2011, we retrieved the daily-averaged columnar- integrated mass concentration of BrC on clear day is 4.353 mg/m(2) while that of haze day is 12.750 mg/m(2). According to the sensitivity study, we found that the results highly relied on the assumed aerosol refractive index. To reduce the uncertainty of this approach, we need to gain a better understanding of the temporal variability of the radiation absorbing components of these aerosols in the future.