Permafrost is a crucial part of the Earth's cryosphere. These millennia-old frozen soils not only are significant carbon reservoirs but also store a variety of chemicals. Accelerated permafrost thaw due to global warming leads to profound consequences such as infrastructure damage, hydrological changes, and, notably, environmental concerns from the release of various chemicals. In this perspective, we metaphorically term long-preserved substances as dormant chemicals that experience an awakening during permafrost thaw. We begin by providing a comprehensive overview and categorization of these chemicals and their potential transformations, utilizing a combination of field observations, laboratory studies, and modeling approaches to assess their environmental impacts. Following this, we put forward several perspectives on how to enhance the scientific understanding of their ensuing environmental impacts in the context of climate change. Ultimately, we advocate for broader research engagement in permafrost exploration and emphasize the need for extensive environmental chemical studies. This will significantly enhance our understanding of the consequences of permafrost thaw and its broader impact on other ecosystems under rapid climate warming.

It is increasingly recognized that light-absorbing impurities (LAI) deposited on snow and ice affect their albedo and facilitate melting processes leading to various feedback loops, such as the ice albedo feedback mechanism. Black carbon (BC) is often considered the most important LAI, but some areas can be more impacted by high dust emissions. Iceland is one of the most important high latitude sources for the Arctic due to high emissions and the volcanic nature of the dust. We studied optical properties of volcanic dust from Iceland and Chile to understand how it interacts with the Sun's radiation and affects areas of deposition as LAI. Optical properties of dust samples were measured at the laboratory of the Finnish Geospatial Research Institute (FGI) using the latest setup of the FGI's goniospectrometer. We found that, depending on the particle size, the albedo of dry volcanic dust on the visible spectrum is as low as 0.03, similar to that of BC, and the albedo decreases with increasing particle size. Wet dust reduces its albedo by 66% compared to dry sample. This supports the comparability of their albedo reducing effects to BC as LAIs, and highlights their significant role in albedo reduction of snow and ice areas. The potential use of the results from our measurements is diverse, including their use as a ground truth reference for Earth Observation and remote sensing studies, estimating climate change over time, as well as measuring other ecological effects caused by changes in atmospheric composition or land cover.

High Mountain Asia (HMA) shows a remarkable warming tendency and divergent trend of regional precipitation with enhanced meteorological extremes. The rapid thawing of the HMA cryosphere may alter the magnitude and frequency of nature hazards. We reviewed the influence of climate change on various types of nature hazards in HMA region, including their phenomena, mechanisms and impacts. It reveals that: 1) the occurrences of extreme rainfall, heavy snowfall, and drifting snow hazards are escalating; accelerated ice and snow melting have advanced the onset and increased the magnitude of snowmelt floods; 2) due to elevating trigger factors, such as glacier debuttressing and the rapid shift of thermal and hydrological regime of bedrock/snow/ice interface or subsurface, the mass flow hazards including bedrock landslide, snow avalanche, ice-rock avalanches or glacier detachment, and debris flow will become more severe; 3) increased active-layer detachment and retrogressive thaw slumps slope failures, thaw settlement and thermokarst lake will damage many important engineering structures and infrastructure in permafrost region; 4) multi-hazards cascading hazard in HMA, such as the glacial lake outburst flood (GLOF) and avalanche-induced mass flow may greatly enlarge the destructive power of the primary hazard by amplifying its volume, mobility, and impact force; and 5) enhanced slope instability and sediment supply in the highland areas could impose remote catastrophic impacts upon lowland regions, and threat hydropower security and future water shortage. In future, ongoing thawing of HMA will profoundly weaken the multiple-phase material of bedrock, ice, water, and soil, and enhance activities of nature hazards. Compounding and cascading hazards of high magnitude will prevail in HMA. As the glacier runoff overpasses the peak water, low flow or droughts in lowland areas downstream of glacierized mountain regions will became more frequent and severe. Addressing escalating hazards in the HMA region requires tackling scientific challenges, including understanding multiscale evolution and formation mechanism of HMA hazard-prone systems, coupling thermo-hydro-mechanical processes in multi-phase flows, predicting catastrophes arising from extreme weather and climate events, and comprehending how highland hazards propagate to lowlands due to climate change.

The SCATSAT-1 (Scatterometer Satellite) was launched by ISRO (Indian Space Research Organisation) on September 26, 2016 from the Satish Dhawan Space Centre, Sriharikota, India. With nearly five years of its journey, the Ku-band (13.5 GHz) based SCATSAT-1 made a profound impact on many scientific domains such as ocean-atmosphere dynamics, soil moisture and vegetation dynamics, climate change, hydrology and polar sea-ice and snowmelt studies. As a successor of the Oceansat-2 Scatterometer (OSCAT), the SCATSAT-1 supports the long-term analysis in climate studies, crop yield prediction, and forecasting analysis. In addition, the SCATSAT-1 provides the four different levels of data products at an enhanced resolution to improve the scope of the scatterometer in different applications. Recently the SCATSAT-1 has been explored in many emerging applications apart from oceanography e.g., crop growth, snow cover analysis, jute crop detection and river level estimation with advanced algorithms i.e., machine learning-based classification, information fusion, and super-resolution mapping. Therefore, it is desired to summarise all operational SCATSAT-1 products, applications, and their emerging trends at the global level in the various scientific domains. This paper has summarized the progress made by SCATSAT-1 in different scientific domains since its launch. A meta-analysis has also been conducted in this paper (using the SCOPUS database) to analyse the current research status of SCATSAT-1 in terms of study area targets. This study highlights the features, challenges, and future directions for the scatterometer improvements.

Pigments are an essential part of everyday life on Earth with rapidly growing industrial and biomedical applications. Synthetic pigments account for a major portion of these pigments that in turn have deleterious effects on public health and environment. Such drawbacks of synthetic pigments have shifted the trend to use natural pigments that are considered as the best alternative to synthetic pigments due to their significant properties. Natural pigments from microorganisms are of great interest due to their broader applications in the pharmaceutical, food, and textile industry with increasing demand among the consumers opting for natural pigments. To fulfill the market demand of natural pigments new sources should be explored. Cold-adapted bacteria and fungi in the cryosphere produce a variety of pigments as a protective strategy against ecological stresses such as low temperature, oxidative stresses, and ultraviolet radiation making them a potential source for natural pigment production. This review highlights the protective strategies and pigment production by cold-adapted bacteria and fungi, their industrial and biomedical applications, condition optimization for maximum pigment extraction as well as the challenges facing in the exploitation of cryospheric microorganisms for pigment extraction that hopefully will provide valuable information, direction, and progress in forthcoming studies.

The seasonal movement of the zero-degree isotherm across the Southern Ocean and Antarctic Peninsula drives major changes in the physical and biological processes around maritime Antarctica. These include spatial and temporal shifts in precipitation phase, snow accumulation and melt, thawing and freezing of the active layer of the permafrost, glacier mass balance variations, sea ice mass balance and changes in physiological processes of biodiversity. Here, we characterize the historical seasonal southward movement of the monthly near-surface zero-degree isotherm latitude (ZIL), and quantify the velocity of migration in the context of climate change using climate reanalyses and projections. From 1957 to 2020, the ZIL exhibited a significant southward shift of 16.8 km decade(-1) around Antarctica and of 23.8 km decade(-1) in the Antarctic Peninsula, substantially faster than the global mean velocity of temperature change of 4.2 km decade(-1), with only a small fraction being attributed to the Southern Annular Mode (SAM). CMIP6 models reproduce the trends observed from 1957 to 2014 and predict a further southward migration around Antarctica of 24 +/- 12 km decade(-1) and 50 +/- 19 km decade(-1) under the SSP2-4.5 and SSP5-8.5 scenarios, respectively. The southward migration of the ZIL is expected to have major impacts on the cryosphere, especially on the precipitation phase, snow accumulation and in peripheral glaciers of the Antarctic Peninsula, with more uncertain changes on permafrost, ice sheets and shelves, and sea ice. Longer periods of temperatures above 0 degrees C threshold will extend active biological periods in terrestrial ecosystems and will reduce the extent of oceanic ice cover, changing phenologies as well as areas of productivity in marine ecosystems, especially those located on the sea ice edge.

The arid northwestern China is the most vulnerable region to climate change, where the variability of seasonally extreme temperature events has profound implications for both its hydrological, ecological, and human systems. In this study, we applied 15 indicators of extreme temperature to analyze the spatial and temporal variation of its occurrence in arid northwestern China for a recent 40-year period (1979 to 2018). These extreme temperature event dynamics were then combined with atmospheric and oceanic circulation to explore their response mechanisms. Our results revealed the following: (1) Over the 40-year period, the annual average temperature in this arid zone increased at a rate of 0.4 degrees C/decade (p = 0.09), exceeding the national average rate (0.28 degrees C/decade). Apart from a few indicators, extreme temperature events (TXx, TNx, TXn and TNn) generally increased at least twice as fast as average temperature during the four seasons, especially in spring, when TNn (0.98 degrees C/decade) rose five times faster than did the average temperature (0.2 degrees C/decade). (2) Spatially, except for the Kunlun Mountains and Tarim Basin, seasonal warming occurred in most parts of the studied arid zone, being most prominent in the summer. In this season, the average number of warm nights increased (3.23 days/decade), while the average number of cold nights decreased (2.69 days/decade). (3) After the 1990s, extreme temperature events accelerated significantly. The Cold Spell Duration Indicator decreased 42% in spring and the Warm Spell Duration Indicator increased 300% in summer, from 1979 -1998 to 1999-2018, which may hasten the formation of snow and glacier melt flooding events in the spring and summer. Spatiotemporal variability in seasonally extreme temperature events was closely related to atmospheric and oceanic circulation, particularly for the AMO (r = 0.8). Altogether, these findings enhance our understanding of how to better assess shifts in extreme temperature events in response to a changing climate in arid zones.

Decline in snow mass threatens the regional economy that critically depends on meltwater. However, the economic scale of snow mass loss is hardly understood, and its role in the vulnerability of future economic development is unclear. We investigate the current reserves of snow cover and the value of its loss. The result showed that the total annual snow mass in western China declines at a rate of 3.3 x 10(9) Pg per decade (p < 0.05), which accounts for approximately 0.46% of the mean of annual snow mass (7.2 x 10(11) Pg). Snow mass loss over the past 40 years in western China turns into an average loss value of CN0.1 billion (in the present value) every year ($1 = CN7). If the trend continues at the current rate, the accumulated loss value would rise to CN63 billion by 2040. Furthermore, subject to the combinations of RCPs and SSPs scenario, the future economic value of snow mass loss in western China appears to accelerate driven by both declining snowmelt resources and socioeconomic development demand. RCP26-SSP1 is the pathway among all to have the least economic cost in replacing the snowmelt loss, and the cost would be quadrupled in RCP80-SSP3 scenario by 2100. At a basin scale, the declining snow mass would turn the regional economy to be more vulnerable except Junggar and Ili endorheic basin. The Ertis river and Qaidam endorheic basins display to be most vulnerable. It highlights that the snowvalue can be economically important in the regions ofwest China and should be considered more properly in water resources management. (C) 2020 The Author(s). Published by Elsevier B.V.

Perfluoroalkyl acid analogs (PFAAs) are a class of chemically stable environmentally persistent organic pollutants (POPs) that are difficult to degrade and have a strong capacity to accumulate in the human body. PFAAs have been found to be biotoxic to humans and have been detected in various environmental media, especially in the cryosphere at trace concentrations. The cryosphere, sensitively responds to climate change, plays a crucial role in the global water, carbon and energy cycles. However, researches on cryosphere PFAAs especially in Tibetan Plateau (TP) is limited. Therefore, we summarize the physicochemical properties, physiological toxicity, spatiotemporal distribution, sources, diffusion and migration pathways, as well as analysis and removal methods of PFAAs in the cryosphere regions. The results show that PFAAs pollutants are mainly produced and distributed in the more economically developed countries in Europe and the United States, as well as in East Asia, and PFAAs can be transported by atmospheric circulation and water cycle to remote regions including cryosphere regions. The current detection methods for PFAAs in cryosphere need to be further refined for increased accuracy and convenience. There is also a need to develop more effective removal methods that will reduce the environmental and human threats posed by these PFAAs. Finally, we propose key scientific questions for future research in cryosphere including PFAAs redistribution influenced by cryosphere changes, human activities, and the interaction of other spheres.

Permafrost degradation alters the flow rate, direction, and storage capacity of soil moisture, affecting ecohydrological effects and climate systems, and posing a potential threat to natural and human systems. The most widely distributed permafrost regions are coastal, high-latitudes and high-altitudes (mainly by the Qinghai-Tibet Plateau). Past studies have demonstrated that permafrost degradation in these regions lacks sorting out regional driving factors, assessing cascading effects on the hydrological environment and monitoring methods. To address this, we reviewed the historical research situation and major topics of permafrost degradation from 1990 to 2022. We analyzed the spatio-temporal dynamics and driving mechanism of permafrost degradation. Then, we comprehensively discussed the effects of permafrost degradation on the soil physical structure and hydraulic properties, soil microorganisms and local vegetation, soil evapotranspiration and stream runoff, and integrated ecohydrological effects. Permafrost field site data were then collected from existing findings and methods for direct or indirect monitoring of permafrost changes at different scales. These results revealed that the research on the hydrological effects of permafrost change was mainly centered on the soil. In addition, regional environmental factors driving permafrost degradation were inconsistent mainly in coastal regions influenced by sea level, high-latitude regions influenced by lightning and wildfire, and high-altitude regions influenced by topography. Permafrost degradation promoted horizontal and/or vertical hydrological connectivity, threatening the succession of high latitude vegetation communities and the transition from high altitude grassland to desert ecosystems, causing regional water imbalances would mitigate or amplify the ability of integrated ecohydrological benefits to cope with climate warming. The never-monitored permafrost area was 1.55x106 km2, but the limitations of using data for the same period remained a challenging task for soil moisture monitoring. Finally, future research should enhance the observation of driving factors at the monitoring site and combine remote sensing data, model simulations or numerical simulations, and isotope tracers to predict the future degradation state of deep permafrost effectively. It is expected that this review will guide further quantifying the driving mechanisms of permafrost degradation and the resulting cascading effects.