Glacier melting represents an important flux of carbon and nitrogen (N) and affects the hydrological cycle. In this study, we presented the features of dissolved organic carbon (DOC) and N concentrations, their potential sources and export from the Muz Taw glacier in Central Asia. The average DOC and total dissolved nitrogen concentrations were 1.12 +/- 1.66 and 0.62 +/- 0.59 mg L-1 in surface snow and 0.21 +/- 0.04 and 0.31 +/- 0.10 mg L-1 in snowpit samples, respectively. The values from snowpit of the Muz Taw glacier were comparable to data reported from glaciers in the Tibetan Plateau but were considerably higher than those from polar regions. The C/N ratios in snow ranged from 0.7 to 11.7, indicating the high bioavailability of DOC. Mass absorption cross of DOC at 365 nm in snow indicated that during the snow melting process, light-absorbing DOC was prone to be attached to particles, especially in the ablation zone of the Muz Tawglacier. Radiative forcing caused by DOC contributed approximately 38 +/- 26% and 18 +/- 9.8% of that caused by black carbon for surface snow and snowpit samples, respectively. DOC and N deposition on the glacier surface were influenced by the combined sources from anthropogenic input, wild biomass burning emission, and dust input from local regions and long range transport. Export of DOC and N from the Muz Taw glacier was estimated to be 3.47-18.5 t C yr(-1) and 5.11-10.23 t N yr(-1) respectively, based on their concentrations and current glacier mass balance. These results enhanced our understanding of the sources and cycle of DOC and N released from glaciers in Central Asia, where glacier meltwater can protect the population from drought stress. (C) 2020 Elsevier B.V. All rights reserved.

Permafrost (perennially frozen) soils store vast amounts of organic carbon (C) and nitrogen (N) that are vulnerable to mobilization as dissolved organic carbon (DOC) and dissolved organic and inorganic nitrogen (DON, DIN) upon thaw. Such releases will affect the biogeochemistry of permafrost regions, yet little is known about the chemical composition and source variability of active-layer (seasonally frozen) and permafrost soil DOC, DON and DIN. We quantified DOC, total dissolved N (TDN), DON, and DIN leachate yields from deep active-layer and near-surface boreal Holocene permafrost soils in interior Alaska varying in soil C and N content and radiocarbon age to determine potential release upon thaw. Soil cores were collected at three sites distributed across the Alaska boreal region in late winter, cut in 15 cm thick sections, and deep active-layer and shallow permafrost sections were thawed and leached. Leachates were analyzed for DOC, TDN, nitrate (NO3-), and ammonium (NH4+) concentrations, dissolved organic matter optical properties, and DOC biodegradability. Soils were analyzed for C, N, and radiocarbon (C-14) content. Soil DOC, TDN, DON, and DIN yields increased linearly with soil C and N content, and decreased with increasing radiocarbon age. These relationships were significantly different for active-layer and permafrost soils such that for a given soil C or N content, or radiocarbon age, permafrost soils releasedmore DOC and TDN (mostly as DON) per gram soil than active-layer soils. Permafrost soil DOC biodegradability was significantly correlated with soil Delta C-14 and DOM optical properties. Our results demonstrate that near-surface Holocene permafrost soils preserve greater relative potential DOC and TDN yields than overlying seasonally frozen soils that are exposed to annual leaching and decomposition. While many factors control the fate of DOC and TDN, the greater relative yields from newly thawed Holocene permafrost soils will have the largest potential impact in areas dominated by organic-rich soils.

This study investigates the impacts of active layer detachments (ALDs) on nitrogen in seasonal runoff from High Arctic hillslope catchments. We examined dissolved nitrogen in runoff from an undisturbed catchment (Goose (GS)) and one that was disturbed (Ptarmigan (PT)) by ALDs, prior to disturbance (2007) and 5 years after disturbance (2012). The seasonal dynamics of nitrogen species concentrations and fluxes were similar in both catchments in 2007, but the mean seasonal nitrate concentration and mass flux from the disturbed catchment were on the order of 30 times higher relative to the undisturbed catchment in 2012. Stormflow yielded 45% and 60% of the 2012 total dissolved nitrogen flux in GS and PT, respectively, although rainfall runoff provided less than 25% of seasonal discharge. Results support that through the combined effects of increased disturbance and rainfall, climate change stands to significantly enhance the export of nitrate from High Arctic watersheds. This study highlights that the increase in the delivery of nitrate from disturbance is especially pronounced late in the season when downstream productivity and the biological demand for this often limiting nutrient are high. Our results also demonstrate that the impact of ALDs on nitrate export can persist more than 5 years following disturbance.