This study investigates the stabilization of lateritic soil through partial replacement of cement with flue gas desulfurization (FGD) gypsum, aiming to enhance its engineering properties for pavement subgrade applications. Lateritic soils are known for their high plasticity and low strength, which limit their utility in infrastructure. To address these challenges, soil specimens were treated with varying cement contents (3%, 6%, 9%) and FGD gypsum additions (1%-6%). Laboratory tests were conducted to evaluate plasticity, compaction, permeability, unconfined compressive strength (UCS), California Bearing Ratio (CBR), and fatigue behaviour. The optimal mix 6% cement with 3% FGD gypsum demonstrated significant improvements: UCS increased by over 110% after 28 days, permeability reduced by 26%, and soaked CBR improved by 56% compared to untreated soil. Additionally, fatigue life showed remarkable enhancement under cyclic loading, indicating increased durability for high-traffic applications. To support predictive insights, machine learning models including Decision Tree, Random Forest, and Multi-Layer Perceptron (MLP) were trained on 168 data samples. The MLP and Random Forest models achieved high prediction accuracy (R2 approximate to 0.98), effectively capturing the non-linear interactions between mix proportions and UCS. SHAP (SHapley Additive exPlanations) analysis identified curing duration as the most influential factor affecting strength development. This integrated experimental-computational approach not only validates the feasibility of using FGD gypsum in sustainable soil stabilization but also demonstrates the effectiveness of machine learning in predicting key geotechnical parameters, reducing reliance on extensive laboratory testing and promoting data-driven pavement design.

Phosphogypsum (PG), an industrial solid waste produced from the wet phosphoric acid process, has seriously damaged the ecological environment. Its comprehensive utilization rate needs to be improved urgently. In this paper, the chemical enhancement effect of solid waste PG on expansive soil, known as engineering cancer, was investigated through systematic macroscopic and microscopic experiments. The positive and negative environmental impacts of the PG modifier were also comprehensively analyzed. Laboratory soil test results show that PG mixed with expansive soil can change the consistency limit of expansive soil, effectively increase the soil strength by 2-3 times and reduce the expansion of expansive soil to 62%. Therefore, it can be considered to be applied to the improvement of expansive soil roadbed. However, when the dosage is too high, it may be affected by the dissolution of PG, and the improvement effect is relatively decreased. The optimal dosage of PG is 15%. XRD, XRF, SEM and MIP microcosmic tests show that the mineral composition, element content and porosity of the expansive soil have changed after the addition of PG. Its microstructure is much tighter. Through TCLP test, the environmental effects of heavy metals caused by resource utilization of PG modified expansive soil were evaluated. In this study, only Cr element exceeded 2.6% slightly when the content of PG was 25%. The analysis found that the engineering properties of expansive soil were effectively improved, resulting in the effective solidification of heavy metals in PG.

The impact of delayed compaction on the geoengineering properties of pond ash (PA) treated with geopolymer, Portland cement, and hydrated lime is presented in this paper. The gradation, compacted dry density (CDD), unconfined compressive strength (UCS), California bearing ratio (CBR), hydraulic conductivity, and compressibility index of PA treated with 3%, 9%, and 15% additive contents were evaluated at 0, 3, 6, 12, 24, 48, and 72 h delay periods. The mineralogical and morphological changes in the stabilised material were assessed using X-ray diffraction and scanning electron microscope analysis. The results show an enhancement in the particle size of PA with delay time due to the development of cementitious products and agglomeration of particles. Delay in compaction causes a reduction in dry density and strength properties, whereas hydraulic conductivity and compressibility index increase with delay time. The formation of cementitious products and agglomeration during delay periods leads to improper compaction and deteriorates the mechanical performance. The formations of both sodium-based geopolymer compounds and calcium-based hydration products contribute to the superior geoengineering properties of geopolymer-stabilised PA compared to cement and lime-stabilised PA, which have Ca-based hydration products alone. The developed mathematical models predict the engineering properties of stabilised PA with higher R-square values (>0.90). Based on this study, it is concluded that the geopolymer is more effective as a stabiliser than lime and cement.

Urban construction has generated substantial amounts of waste soils, impeding urban ecological development. With the aim of promoting waste recycling, waste soils possess a high potential for sustainable utilization in subgrade construction. However, these waste materials exhibit inadequate engineering properties and necessitate stabilization for an investigation into their long-term performance as subgrade filling materials. Initially, a thorough assessment and comparison were conducted to examine the key mechanical properties of lime- and cement-stabilized soils with mixed ratios (total stabilizer contents ranging from 2% to 8%). The results indicated that these soils met the requirements of subgrade materials except for the 2% lime-treated soil. Subsequently, to reveal the improvement in water resistance of stabilized waste soil (e.g., under conditions of rainfall or elevated groundwater table), the effects of soil densities and stabilizer contents on the disintegration characteristics were investigated using a range of disintegration tests. An evolutionary model for the disintegration ratio of stabilized soils was then developed to predict the process of disintegration breakage. This model facilitates the quantification of the lower disintegration rates and elevated disintegration time attributed to higher levels of compactness and stabilizer contents during a three-stage disintegration process. This enhances the understanding and evaluation of sustainable applications in stabilized waste soils used as subgrade filling materials.

This paper reports the influence of delay time on the index and engineering properties of geopolymer-, cement-, and lime-treated expansive soil. Locally available expansive soil was treated with different doses of slag-based geopolymer, cement, and lime. The index and engineering properties like Atterberg's limits, free swell index, grain-size distribution, compaction properties, and unconfined compressive strength (UCS) were evaluated at delay periods of 0, 6, 12, 24, 48, 72, and 168 h. Further, the mineralogical characteristics and microstructure of the stabilized materials were examined using X-ray diffraction (XRD) and scanning electron microscopic (SEM) images. It was observed that with an increase in delay time, the plasticity and swelling characteristics of the treated soil reduced with improvement in the soil grain size along with the formation of hydration and geopolymeric compounds. The delay in compaction results in the decline of the compacted density and UCS. The formation of hydrated products and flocs during the delay period caused loose packing under dynamic loading and affects the mechanical properties. A significant improvement in plasticity and engineering properties of the expansive soil was observed with geopolymer stabilizers. Thus, it is noteworthy to consider geopolymers as a new generation eco-friendly stabilizer for treating expansive clays for geotechnical constructions.

With the invasion of heavy metal ions, the electric double layer (DDL) on the surface of cohesive soil particles changes under the influence of heavy metal ions, which leads to significant changes in its physical and mechanical properties. In order to study the variation law of engineering characteristics of heavy metal contaminated soil, three common heavy metal materials, zinc (Zn), lead (Pb) and cadmium (Cd), are selected as pollution additives in this paper. Taking typical silty clay and clay in Nanjing as the research object, through physical property test (boundary moisture content test, particle test) and mechanical property test (direct shear test), The variation law of physical and mechanical indexes of natural cohesive soil polluted by heavy metals is studied, and the influence mechanism of metal ions in heavy metal contaminated soil on engineering characteristics is clarified, which provides a basis for the evaluation method of engineering characteristics of heavy metal contaminated soil.