The degradation of subarctic peatland ecosystems under climate change impacts surrounding landscapes, carbon balance, and biogeochemical cycles. To assess these ecosystems' responses to climate change, it is essential to consider not only the active-layer thickness but also its thermo-hydraulic conditions. Ground-penetrating radar is one of the leading methods for studying the active layer, and this paper proposes systematically investigating its potential to determine the thermal properties of the active layer. Collected experimental data confirm temperature hysteresis in peat linked to changes in water and ice content, which GPR may detect. Using palsa mires of the Kola Peninsula (NW Russia) as a case study, we analyze relationships between peat parameters in the active layer and search for thermal gradient responses in GPR signal attributes. The results reveal that frequency-dependent GPR attributes can delineate thermal intervals of +/- 1 degrees C through disperse waveguides. However, further verification is needed to clarify the conditions under which GPR can reliably detect temperature variations in peat, considering factors such as moisture content and peat structure. In conclusion, our study discusses the potential of GPR for remotely monitoring freeze-thaw processes and moisture distribution in frozen peatlands and its role as a valuable tool for studying peat thermal properties in terms of permafrost stability prediction.