To achieve environmental and economic goals in ground improvement, a one-part geopolymer (OPG), synthesized from binary precursors (fly ash [FA] and granulated blast furnace slag [GGBFS]) and a solid activator (solid sodium silicate [NS]), was used to replace ordinary Portland cement (OPC) for stabilizing high-water-content soft clay. The effects of different initial water content (50%, 80%, 100%, and 120%) and various OPG binder content (10%, 20%, 30%, and 40%) on the strength development of the OPG-stabilized soft clay were investigated through unconfined compressive strength (UCS) and unconsolidated undrained (UU) triaxial tests. Additionally, the microstructure evolution and the distribution of pores in the OPG-stabilized soft clay were examined by the utilization of mercury intrusion porosimetry (MIP) and scanning electron microscopy-energy-dispersive spectroscopy (SEM-EDS) techniques, respectively. The life cycle assessment (LCA) methodology was then used to analyze the environmental and economic advantages of employing an OPG binder for soil stabilization. It was revealed that the optimal content of OPG binder was contingent upon the water content of soft clay, with variations in requirements for strength development. Specifically, for soft clay not demanding early strength, a maximum binder content of 20% is proposed. Conversely, for soft clay that necessitated rapid strength gain, the OPG binder content escalated with increasing water content of the soft clay, in which soft clays with different water contents had corresponding required amounts of OPG binder. For soil with water content ranging from 50% to 80%, the recommended OPG binder content is 20%. While for soil with 100% and 120% water content, the designed OPG binder content is suggested to be 30% and 40%, respectively. The environmental assessment demonstrated that the utilization of OPG as a binder for the stabilization of soft clay reduces costs and carbon emissions in comparison to OPC. The present study provides substantial theoretical validation for the utilization of OPG as a novel binder to stabilize soft clay with elevated water content, which holds promise as an eco-friendly and cost-effective solution in ground improvement.
Generally, high-water-content of dredged sediment (DS) tends to suffer from inferior mechanical properties and obvious shrinkage after solidification, so finding solutions to this issue is helpful for promoting the recovery and recycling of DS. In this paper, in reference to natural gypsum (NG), phosphogypsum (PG) was incorporated into DS solidified with alkali-activated slag (AAS) system. The effect of PG (0 %-20 %) on the hydration process (0-168 h), mechanical properties (3 d, 7 d and 28 d) and autogenous shrinkage (0-7 d) of DS solidified with AAS was investigated. It is found that the addition of PG not only induces the generation of ettringite to compensate for shrinkage, but also accelerates the formation of C-A-S-H by providing active calcium to promote stiffness to resist shrinkage. This results in a reduction of autogenous shrinkage by 74.3 % and an increase of compressive strength by 28.5% when PG dosage is 15%. Compared with NG, the difference in 28d-compressive strength of PG group is not more than 7.34 % under equivalent dosages. The dissolved SO4 2-from PG could be adsorbed on CA-S-H and preserved in pore solution in the form of Na2SO4. The decrease in S/Si from 0.31 to 0.09 indicates stored SO42- could be released back into system to promote the further generation of ettringite. To obtain superior mechanical properties and volume stability, appropriate PG dosage is 10 %-15 %. Compared with the control group, it increases the content of ettringite and amorphous phase by 2.4 %-4.6 % and 3.3 %-3.7 %, respectively. This research not only provides theoretical support for DS solidified with AAS to realize efficient utilization of solid waste resources (i.e., DS, PG and slag), but also gives a new insight into solidification of other high-watercontent system, such as backfill mining, grouting materials and treatment of soft soil foundations.