Indian monsoon circulation is the primary driver of the long-range transboundary mercury (Hg) pollution from South Asia to the Himalayas and Tibet Plateau region, yet the northward extent of this transport remains unknown. In this study, a strong delta Hg-202 signature overlapping was found between Lake Gokyo and Indian anthropogenic sources, which is an indicative of the Hg source regions from South Asia. Most of the sediment samples were characterized with relatively large positive Delta Hg-199 values (mean = 0.07 parts per thousand-0.44 parts per thousand) and small positive Delta Hg-200 values (mean = 0.03 parts per thousand-0.08 parts per thousand). Notably, the Delta Hg-199 values in the lake sediments progressively increased from southwest to northeast. Moreover, the Delta Hg-199 values peaked at Lake Tanglha (mean = 0.44 parts per thousand +/- 0.04 parts per thousand) before decreased at Lake Qinghai that is under the influence of the westerlies. Our results suggest that transboundary atmospheric transport could transport Hg from South Asia northwards to at least the Tanglha Mountains in the northern Himalaya-Tibet.
Nitrate (NO3-) is a prominent atmospheric pollutant and a key chemical constituent of snow and ice, which plays a crucial role in the atmosphere and significantly impacts regional climate and environment conditions through a series of complex chemical processes. By summarizing the recent research progress on the nitrate chemical process (particularly on the isotopic measurements of NO3- (delta 15N, Delta 17O and delta 18O)) in atmosphere and glacier snow, this study mainly investigated the chemical compositions and chemical processes, formation pathways, and photochemical reactions of nitrate in snow and atmosphere. Our results identified that the main ways of atmospheric nitrate formation are the hydrolysis of N2O5 and the reaction of center dot OH with NO2; the spatial distribution of Delta 17O and delta 18O values of atmospheric nitrate have a significant latitudinal trend between 30 degrees N-60 degrees N; the study of stable isotopes (delta 15N and delta 18O) and the oxygen isotope anomaly (Delta 17O) of nitrate have mainly been carried out over the densely populated and coastal mega cities; there exist significant gaps in the study of chemistry processes of nitrate in snow and ice and the air-snow interfaces across glaciated regions. This study provides a basic reference for more robust observations and research of nitrate in glacier areas in the future.