The release of greenhouse gases from the large organic carbon stock in permafrost deposits in the circumarctic regions may accelerate global warming upon thaw. The extent of this positive climate feedback is thought to be largely controlled by the microbial degradability of the organic matter preserved in these sediments. In addition, weathering and oxidation processes may release inorganic carbon preserved in permafrost sediments as CO2, which is generally not accounted for. We used C-13 and C-14 analysis and isotopic mass balances to differentiate and quantify organic and inorganic carbon released as CO2 in the field from an active retrogressive thaw slump of Pleistocene-age Yedoma and during a 1.5-years incubation experiment. The results reveal that the dominant source of the CO2 released from freshly thawed Yedoma exposed as thaw mound is Pleistocene-age organic matter (48-80%) and to a lesser extent modern organic substrate (3-34%). A significant portion of the CO2 originated from inorganic carbon in the Yedoma (17-26%). The mixing of young, active layer material with Yedoma at a site on the slump floor led to the preferential mineralization of this young organic carbon source. Admixtures of younger organic substrates in the Yedoma thaw mound were small and thus rapidly consumed as shown by lower contributions to the CO2 produced during few weeks of aerobic incubation at 4 degrees C corresponding to approximately one thaw season. Future CO2 fluxes from the freshly thawed Yedoma will contain higher proportions of ancient inorganic (22%) and organic carbon (61-78%) as suggested by the results at the end, after 1.5 years of incubation. The increasing contribution of inorganic carbon during the incubation is favored by the accumulation of organic acids from microbial organic matter degradation resulting in lower pH values and, in consequence, in inorganic carbon dissolution. Because part of the inorganic carbon pool is assumed to be of pedogenic origin, these emissions would ultimately not alter carbon budgets. The results of this study highlight the preferential degradation of younger organic substrates in freshly thawed Yedoma, if available, and a substantial release of CO2 from inorganic sources.

We present a review of the changing state of European permafrost within a spatial zone that includes the continuous high latitude arctic permafrost of Svalbard and the discontinuous high altitude mountain permafrost of Iceland, Fennoscandia and the Alps. The paper focuses on methodological developments and data collection over the last decade or so, including research associated with the continent-scale network of instrumented permafrost boreholes established between 1998 and 2001 under the European Union PACE project. Data indicate recent warming trends, with greatest warming at higher latitudes. Equally important are the impacts of shorter-term extreme climatic events, most immediately reflected in changes in active layer thickness. A large number of complex variables, including altitude, topography, insolation and snow distribution, determine permafrost temperatures. The development of regionally calibrated empirical-statistical models, and physically based process-oriented models, is described, and it is shown that, though more complex and data dependent, process-oriented approaches are better suited to estimating transient effects of climate change in complex mountain topography. Mapping and characterisation of permafrost depth and distribution requires integrated multiple geophysical approaches and recent advances are discussed. We report on recent research into ground ice formation, including ice segregation within bedrock and vein ice formation within ice wedge systems. The potential impacts of climate change on rock weathering, permafrost creep, landslides. rock falls, debris flows and slow mass movements are also discussed. Recent engineering responses to the potentially damaging effects of climate warming are outlined, and risk assessment strategies to minimise geological hazards are described. We conclude that forecasting changes in hazard occurrence, magnitude and frequency is likely to depend on process-based modelling, demanding improved understanding of geomorphological process-response systems and their impacts on human activity. (C) 2008 Published by Elsevier B.V.