In many soil processes, including solute and gas dynamics, the architecture of intra-aggregate pores is a crucial component. Soil management practices and wetting-drying (W-D) cycles, the latter having a significant impact on pore aggregation, are two key factors that shape pore structure. This study examines the effects of W-D cycles on the architecture of intra-aggregate pores under three different soil management systems: no-tillage (NT), minimum tillage (MT), and conventional tillage (CT). The soil samples were subjected to 0 and 12 W-D cycles, and the resulting pore structures were scanned using X-ray micro-computed tomography, generating reconstructed 3D volumetric data. The data analyses were conducted in terms of multifractal spectra, normalized Shannon entropy, lacunarity, porosity, anisotropy, connectivity, and tortuosity. The multifractal parameters of capacity, correlation, and information dimensions showed mean values of approximately 2.77, 2.75, and 2.75 when considering the different management practices and W-D cycles; 3D lacunarity decreased mainly for the smallest boxes between 0 and 12 W-D cycles for CT and NT, with the opposite behavior for MT. The normalized 3D Shannon entropy showed differences of less than 2% before and after the W-D cycles for MT and NT, with differences of 5% for CT. The imaged porosity showed reductions of approximately 50% after 12 W-D cycles for CT and NT. Generally, the largest pores (>0.1 mm3) contributed the most to porosity for all management practices before and after W-D cycles. Anisotropy increased by 9% and 2% for MT and CT after the cycles and decreased by 23% for NT. Pore connectivity showed a downward trend after 12 W-D cycles for CT and NT. Regarding the pore shape, the greatest contribution to porosity and number of pores was due to triaxial-shaped pores for both 0 and 12 W-D cycles for all management practices. The results demonstrate that, within the resolution limits of the microtomography analysis, pore architecture remained resilient to changes, despite some observable trends in specific parameters.

This study proposes a new approach for analyzing images of the internal structure of soil (microtomograms) and modeling key hydrophysical functions based on the tomographic characteristics of the pore space. The approach is based on constructing a series of closed shells (alpha-shapes) around the studied three-dimensional of the tomogram. These shells are capable of penetrating into the pores of the object with a diameter greater than a specified value. The dependence of the internal volume of the shells on the minimum pore size is analyzed. The algorithm of alpha-shapes construction simulates the process of drying pores connected to the surface and allows for analyzing the anisotropy of pore connectivity by limiting the permeability of a part of the object's surface. The constructed alpha-shapes model the surface of the liquid phase, and the maximum curvature of the surface corresponds to the capillary pressure. The approach is applied to analyze samples of the soil microprofile of a crusty solonetz with a contrasting pore space structure. The microhorizons of the solonetz demonstrate pronounced closed porosity and anisotropy of pore connectivity. The approach allows for the assessment of connectivity and anisotropy of pores, the water retention curve (WRC) without considering soil shrinkage. The results were compared with typical known WRCs of solonetzic soil horizons in soils of Russia. A comparison of WRC models obtained based on 2D and 3D images was conducted. The method was also tested on tomograms of samples of aeolian laminated sandstone, for which both tomograms and direct WRC measurements were simultaneously available.

The traditional view of Na+ as harmful and Ca2+ as beneficial doesn't always apply in multi-cationic soil solutions. Initially, adding Ca2+ promotes Na+ leaching, reducing salinity, but excess Ca2+ becomes counterproductive. As Na+ leaches, the soil's Ca2+-Na+-Mg2+ mix shifts to Ca2+-K2+-Mg2+, Ca2+'s function changes, even causing the opposite effect. To investigate the complex mechanism of Ca2+ to Na+-Mg2+ and K+-Mg2+, we conducted an indoor soil column experiment using saline water (4 dS m(-1)) with different cation compositions [Na+-Ca2+-Mg2+ (NCM), Na+-Mg2+ (NM), K+-Ca2+-Mg2+ (KCM), K+-Mg2+ (KM)] and deionized water as the control (CK). The results showed that NM exhibited the highest crack volume, while KM had the greatest macropore volume, with NM having approximately 15 % more crack volume than KM. Notably, only NM displayed a more pronounced inclination towards pore anisotropy value of 0 when compared to CK. NCM and KCM had higher pore anisotropy values than NM and KM. KM and KCM had more cracks angled ranging from 45-90 degrees than NM and NCM. KCM notably decreased transitional macropores 0.05) observed in widths < 2.5 mm between KCM and KM. NM displayed the shallowest macropore distribution and the highest variability in macropore length among all treatments. Only NCM showed significantly reduced variability in both macropore length and width compared to CK. In summary, Ca2+ exhibited distinct action patterns on K+-Mg2+ and Na+-Mg2+. For specific soil types and cationic compositions, Ca2+ may not fully exert its amendment effects. However, Ca2+'s effect is soil-specific, necessitating comprehensive studies across varied soil types.

Climate change in Arctic landscapes may increase freeze-thaw frequency within the active layer as well as newly thawed permafrost. Freeze-thaw is a highly disruptive process that can deform soil pores and alter the architecture of the soil pore network with varied impacts to water transport and retention, redox conditions, and microbial activity. Our objective was to investigate how freeze-thaw cycles impacted the pore network of newly thawed permafrost aggregates to improve understanding of what type of transformations can be expected from warming Arctic landscapes. We measured the impact of freeze-thaw on pore morphology, pore throat diameter distribution, and pore connectivity with X-ray computed tomography (XCT) using six permafrost aggregates with sizes of 2.5 cm3 from a mineral soil horizon (Bw; 28-50 cm depths) in Toolik, Alaska. Freeze-thaw cycles were performed using a laboratory incubation consisting of five freeze-thaw cycles (-10 C to 20 C) over five weeks. Our findings indicated decreasing spatial connectivity of the pore network across all aggregates with higher frequencies of singly connected pores following freeze-thaw. Water-filled pores that were connected to the pore network decreased in volume while the overall connected pore volumetric fraction was not affected. Shifts in the pore throat diameter distribution were mostly observed in pore throats ranges of 100 mu m or less with no corresponding changes to the pore shape factor of pore throats. Responses of the pore network to freeze-thaw varied by aggregate, suggesting that initial pore morphology may play a role in driving freeze-thaw response. Our research suggests that freeze-thaw alters the microenvironment of permafrost aggregates during the incipient stage of deformation following permafrost thaw, impacting soil properties and function in Arctic landscapes undergoing transition.