In landslide studies, particle size is a key quantitative indicator, reflecting the formation and development of the sliding zone. It plays a crucial role in understanding the mechanisms and evolutionary processes that lead to landslide occurrences. Precise measurement of particle size is crucial. This study centered on soil samples from the Lanniqing landslide in Southwest China. To begin, seven distinct methods were used to preprocess the soil samples. Next, the particle size frequency distribution was measured using the Mastersizer 2000 laser particle size analyzer. Key parameters, including median particle size, mean particle size, sorting coefficient, skewness, and kurtosis, were then compared and analyzed to determine the most appropriate preprocessing method for evaluating the characteristics of the soil samples. The mechanism of landslide occurrence was subsequently analyzed by examining the particle size characteristics, mechanical properties, and mineral composition of the soil samples. The results suggested that method C provides the most reliable analysis of particle size characteristics in soil samples. The observed coarsening of coarse particles, along with a significant increase in clay content within the sliding zone, indicates that the sliding surface has undergone multiple shear and compression events. The interplay of the upper traffic load and slope cutting at the front edge set the stage for the Lanniqing landslide, prompting the initial development of potential sliding surfaces. Rainfall acts as a catalyst for slope instability. The high clay content, combined with the formation of a low-permeability layer rich in clay minerals on the sliding surface, leads to excessive pore water pressure and mineral lubrication. These factors inherently trigger and accelerate the occurrence of the landslide.
Large amounts of steel slag (SS) stockpiled and buried leads to land occupation, and is prone to cause soil and water contamination. Partially replacing natural minerals in pavement construction can contribute to the rapid consumption of stockpiled SS, but its poor volume stability limits its widespread adoption into engineering applications. Meanwhile, the potential leaching of hazardous substances (HS) should also be emphasized. This study prepared different pretreated SSs and asphalt mixtures. The differences and improvement mechanisms of the pretreatment on the SS properties were investigated through micro-morphology and chemical composition analyses. The physical properties of different SS and the long-term volume stability and moisture damage resistance of the steel slag asphalt mixture (SSAM) were tested. Moreover, a revised HS leaching test method for the SSAM was proposed, and the effectiveness of various pretreatment methods in reducing HS leaching was evaluated. The results revealed that the porous characteristics and free oxides contained in SS were the main obstacles to their large-scale application in pavement engineering. Natural aging, thermal immersion, and acid modification alter the composition of SS through chemical reactions and accelerate the consumption of free oxides. The polymer film formed by the silane coupling agent on the SS surface mitigated the environmental effects on the performance. The long-term performance of the SSAMs was improved, and the amount of HS precipitated was significantly reduced. Acetic acid modification and surface treatments are recommended because they are more effective in improving moisture damage resistance and reducing potential adverse environmental impacts. The findings are significant for reasonable pretreatment and application of converted SS as well as for contributing to the sustainable development of transportation infrastructure.
Amaranth (Amaranthus hypochondriacus L.) is a potential forage crop with a high yield and crude protein (CP) content; however, establishment methods need to improve for the crop to be less sensitive to typhoons. Optimal establishment, cultivation, and utilization in amaranth were examined in a variety of seasons and methods of establishment in 2021-2023. Four methods were examined: (1) direct seeding in rows, (2) direct seeding in spots, (3) soil seed balls, and (4) transplant pretreatment methods under a randomized blocked design (n = 3). Sowings every month from April to August were applied only in 2021, while establishments in April, May, and August with both pretreatment methods were applied in 2022 and 2023. The establishment in August successfully escaped damage from typhoons. The direct seeding of either rows or spots showed marginal success in establishment compared to stable establishment in pretreatment methods. In 2022 and 2023, the highest yield and CP content were achieved in soil seed balls plots in April and in both pretreated plots sown in August, respectively. The quality of silage fermentation showed a high pH, ranging from 4.52 to 6.39, due to the high CP content in 7.59-18.36% dry matter (DM). Sowing in April or August established with soil seed balls can avoid typhoon damage to have stable forage yields and can be processed with a favorable quality of amaranth silage in the region.
This study focuses on mitigating the socio-economic and environmental damage of the invasive macroalga Rugulopteryx okamurae and counteracting the pollution from petroleum-based plastics by using the alga as a feedstock for polyhydroxybutyrate (PHB) production. The enzymatic hydrolysis of R. okamurae, non-pretreated and hydrothermally acid-pretreated (0.2 N HCl, 15 min), was carried out, reaching reducing sugar (RS) concentrations of 10.7 g/L and 21.7 g/L, respectively. The hydrolysates obtained were used as a culture medium for PHB production with Cupriavidus necator, a Gram-negative soil bacterium, without supplementation with any external carbon and nitrogen sources. The highest yield (0.774 g PHB/g RS) and biopolymer accumulation percentage (89.8% cell dry weight, CDW) were achieved with hydrolysates from pretreated macroalga, reaching values comparable to the highest reported in the literature. Hence, it can be concluded that hydrolysates obtained from algal biomass hydrothermally pretreated with acid have a concentration of sugars and a C/N ratio that favour PHB production.
The landfill is one of the most important sources of microplastics (MPs). The pretreatment method is a precondition of microplastics study for the presence of complex substances in landfills. Therefore, it is essential to examine the impact of different pretreatment methods on the microplastics detection. A literature review and a comparison experiment on digestion solutions were performed to establish a comprehensive identification method for MPs in landfills. When exposed to of 30 % H2O2, minimal mass reduction of PE, PP and PET were 4.00 %, 3.00 % and 3.00 % respectively, and the least surface damage was observed in MPs, while exhibiting the most optimal peak value for infrared spectral characteristics. It is demonstrated that the effect of 30 % H2O2 dissolution was superior compared to 10 % KOH and 65 % HNO3. The method was subsequently utilized to investigate the distribution of MPs in a landfill. The dominant MPs were polyethylene (PE, 18.56-23.91 %), polyethylene terephthalate (PET, 8.80-18.66 %), polystyrene (PS, 10.31-18.09 %), and polypropylene (PP, 11.60-14.91 %). The comprehensive identification method of NaCl density separation + 30 % H2O2 digestion + NaI density separation + sampling microscope + Mirco-FTIR is suitable for the detection of MPs in landfills.
Recent research has focused on reinforcing sand consolidated through microbial -induced carbonate precipitation (MICP) with alkali -treated fibers to enhance its mechanical properties and mitigate brittleness. This research investigated how modified fiber affected the microstructure and properties of MICP solid sand. The fiber content (0, 0.5, 1, 3, and 5%), pretreatment concentration (0, 1, 5, 10, and 20%), pretreatment time (0, 0.5, 1, 2, and 4 h), and pretreatment temperature (25, 35, 45, and 55 degrees C) required for the experiment were determined by MICP testing. The interactions between fiber, sand, and calcium carbonate(CaCO3) were analyzed by calcium carbonate content(CaCO3(%)), unconfined compressive strength (UCS), environmental scanning electron microscopy (ESEM), and X-ray diffraction (XRD). The specimen without added fiber had a UCS of 2.13 MPa, the UCS of the added fiber sample was 2.8 MPa, which was 31.46% more than that of the specimen without added fiber, and the UCS of the specimen with added alkali -treated fiber was 3.62 MPa, which was 70% more than that of the specimen without added fiber and 28.57% more than that of the added untreated fiber. The optimum content of jute fibers was 0.5%, and the optimum concentration of alkali treatment of jute fibers was 10% for one hour.
In conventional microplastic (MP) analysis, acid or alkaline digestion is a necessary pretreatment step to remove residual organic matter from environmental samples. However, such a digestion process is not only cumbersome and time-consuming, but also possibly cause severe chemical damage to the MP itself, often making accurate MP characterization difficult. This study demonstrates that broadband coherent anti-Stokes Raman scattering (CARS) microspectroscopy is useful for rapidly detecting and identifying MPs in natural soil without any digestion process. A feasibility test is performed with soil samples, which are known to require the most complicated chemical pretreatment for MP analysis, deliberately mixed with various MP particles. The C-H bond-specific CARS imaging and spectral analysis allow rapid MP particle search and chemical identification even in the presence of other residual particles and strongly fluorescent substances from the soil. It is anticipated that this nondestructive, chemical pretreatment-free CARS approach will be a beneficial tool for studying the ecological impacts of MPs absorbed by terrestrial life, such as plants and soil organisms, as well as for complementary analysis of MPs subject to chemical degradation by digestion in investigating the environmental contamination of the MPs.
Microplastic pollution in the environment has become a source of concern in recent years. The transport and deposition of suspended atmospheric microplastics play an important role in the global linkage of microplastic sources and sinks. In this review, we summarized recent research progress on sampling devices, pretreatments, and identification methods for atmospheric microplastics. The total suspended particles and atmospheric deposition, including dust, rainfall, and snow samples, arc the environmental carriers for atmospheric microplastic studies. There arc active and passive sampling methods. Pretreatment depends on sample types and identification methods and includes sieving, digestion, density separation, filtration, and drying. The measured features for atmospheric microplastics include particle size distributions, shapes, colors, surface morphology, and polymer compositions, using stereomicroscopes, Fourier transform infrared spectroscopy, scanning electron microscopy, Raman spectroscopy, and liquid chromatography-tandem mass spectrometry. laser direct infrared spectroscopy and thermochemical methods coupled with mass spectrometry arc potential methods for identifying atmospheric microplastics. Currently, models for estimating the fluxes of atmospheric microplastic emission, transport, and deposition arc in the initial stages of development; their implementation will enhance our understanding of the microplastic cycle globally based on simulated and observed data.