The discharge of fertilizers and untreated sewage from the Indian subcontinent was attributed to damage the coastal ecosystem and threat to the fishery resources. Based on the recent data collected along the Indian coasts, the issues were reanalyzed to identify potential mechanisms responsible. Carbon, nitrogen and oxygen isotopes revealed that the fertilizers used in the agricultural soil contaminate groundwaters, then fluxed to the coastal ocean. Similarly, the impact of municipal sewage is restricted close to the coast rather than spreading to the international waters. This reanalysis suggests that the occurrence of coastal eutrophication, hypoxia or shift in the ecosystem was mainly caused by natural processes such as coastal upwelling, stratification and reversing of coastal currents than hitherto hypothesized as the discharge of fertilizers and municipal sewage.

PurposeOver the past three decades, open-pit mining has been expanding in arid and semi-arid areas of China.Open-pit mining profoundly changes the soil environment and has a profound impact on the circulation of soil water in the aeration zone.Therefore, this research explores the impacts of open-pit coal mining on soil moisture processes in the semi-arid grasslands of Eastern Inner Mongolia Autonomous Region, China.Materials and methodsSoil samples were collected from depths of 0-500 cm at Shengli No. 1 open-pit mine's inner dump and a nearby natural grassland. These soil samples were analyzed for stable isotope characteristics (delta 2H,delta 18O\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$${\delta 2 H, \delta {18} O}$$\end{document}) and moisture content. Collection of underground water samples inside and outside the mining area for conductivity analysis.Results and discussionSoil evaporation loss in the mine's inner dump was significantly higher than in the grassland, with rates of 22.26% for delta 18O\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$${\delta {18} O}$$\end{document} and 6.61% for delta 2H\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$${\delta 2 H}$$\end{document}. The limiting depth of soil evaporation at the mine was found to be 260 cm, compared to 200 cm in the grassland. The increased underground water conductivity in the mine area was linked to heightened soil evaporation loss. Isotopic profiling of the soil indicated that the open-pit mining led to deeper preferential flow infiltration during heavy precipitation, reaching 280 cm in the mine area versus 220 cm in the grassland.ConclusionsThe surface soil moisture content (SMC) increased due to mining activities intensified water-heat exchanges with the atmosphere, leading to more frequent and severe wet-dry cycles. This study provides a comprehensive understanding of open-pit mining's impact on SMC, evaporation, and infiltration in semi-arid areas, offering critical insights for ecological reclamation and sustainable mine construction.

In arid regions, the stable hydrogen and oxygen isotopic composition in raindrops is often modified by sub-cloud secondary evaporation when they descend from cloud base to ground through the unsaturated air. As a result of kinetic fractionation, the slope and intercept of the delta H-2-delta O-18 correlation equation decrease. The variation of deuterium excess from cloud base to the ground is often used to quantitatively evaluate the influence of secondary evaporation effect on isotopes in precipitation. Based on the event-based precipitation samples collected at Urumqi Glacier No. 1, eastern Tianshan during four-year observation, the existence and impact of secondary evaporation effects were analyzed by the methods of isotope-evaporation model. Under high air temperature, small raindrop diameter and precipitation amount, and low relative humidity conditions, the remaining rate of raindrops is small and the change of deuterium excess is large relatively, and the slope and intercept of delta H-2-delta O-18 correlation equation are much lower than those of Global Meteoric Water Line, which mean that the influence secondary evaporation on precipitation enhanced. While on the conditions of low air temperature, high relative humidity, heavy rainfall, and large raindrop diameter, the change of deuterium excess is small relatively and the remaining rate of raindrops is large, and the slope and intercept of delta H-2-delta O-18 correlation equation increase, the secondary evaporation is weakened. The isotope-evaporation model described a good linear correlation between changes of deuterium excess and evaporation proportion with the slope of 0.90%/%, which indicated that an increase of 1% in evaporation may result in a decrease of deuterium excess about 0.90%.

Increased permafrost temperatures have been reported in the circum-Arctic, and widespread degradation of permafrost peatlands has occurred in recent decades. The timing of permafrost aggradation in these ecosystems could have implications for the soil carbon lability upon thawing, and an increased understanding of the permafrost history is therefore needed to better project future carbon feedbacks. In this study, we have conducted high-resolution plant macrofossil and geochemical analyses and accelerator mass spectrometry radiocarbon dating of active layer cores from four permafrost peatlands in northern Sweden and Norway. In the mid-Holocene, all four sites were wet fens, and at least three of them remained permafrost-free until a shift in vegetation toward bog species was recorded around 800 to 400 cal. BP, suggesting permafrost aggradation during the Little Ice Age. At one site, Karlebotn, the plant macrofossil record also indicated a period of dry bog conditions between 3300 and 2900 cal. BP, followed by a rapid shift toward species growing in waterlogged fens or open pools, suggesting that permafrost possibly was present around 3000 cal. BP but thawed and was replaced by thermokarst.

This study reports day-night and seasonal variations of aqueous brown carbon (BrCaq) and constituent humic-like substances (HULIS) (neutral and acidic HULIS: HULIS-n and HULIS-a) from the eastern Indo-Gangetic Plain (IGP) of India during 2019-2020. This is followed by the application of the receptor model positive matrix factorization (PMF) for optical source apportionment of BrCaq and the use of stable isotopic ratios (813C and 815N) to understand atmospheric processing. Nighttime BrCaq absorption and mass absorption efficiencies (MAE) were enhanced by 40-150 % and 50-190 %, respectively, compared to the daytime across seasons, possibly as a combined effect from daytime photobleaching, dark-phase secondary formation, and increased nighttime emissions. MAE250 nm/MAE365 nm (i.e., E2/E3) ratios and Angstrom Exponents revealed that BrCaq and HULIS-n were relatively more aromatic and conjugated during the biomass burning-dominated periods while BrCaq and HULIS-a were comprised mostly of nonconjugated aliphatic structures from secondary processes during the photochemistry-dominated summer. The relative radiative forcing of BrCaq with respect to elemental carbon (EC) was 10-12 % in the post-monsoon and winter in the 300-400 nm range. Optical source apportionment using PMF revealed that BrCaq absorption at 300, 365 and 420 nm wavelengths in the eastern IGP is mostly from biomass burning (60-75 %), followed by combined marine and fossil fuel-derived sources (24-31 %), and secondary processes (up to 10 %). Source-specific MAEs at 365 nm were estimated to be the highest for the combined marine and fossil fuel source (1.34 m2 g-1) followed by biomass burning (0.78 m2 g-1) and secondary processing (0.13 m2 g-1). Finally, 813C and 815N isotopic analysis confirmed the importance of summertime photochemistry and wintertime NO3--dominated chemistry in constraining BrC characteristics. Overall, the quantitative apportionment of BrCaq sources and processing reported here can be expected to lead to targeted source-specific measurements and a better understanding of BrC climate forcing in the future.

A total of 256 water samples were collected from the river, precipitation, and permafrost active layer in a typical small alpine catchment during the ablation periods in 2020 and 2021. The results indicated that every water body was alkaline, and the TDS and EC concentrations were in the following order: precipitation Ca2+ & AP; Mg2+ and Na+ + K+ > Mg2+ > Ca2+, respectively; the anion concentration showed the order of SO42 � > Cl- > NO3 . The results revealed that permafrost and river water had similar geochemical compositions. Similar & delta;2H and & delta;18O values were also observed between river and permafrost water. Additionally, the water chemistry of rivers and permafrost revealed that the chemical weathering of carbonate and silicate rocks is an important source of riverine solutes; however, silicate weathering played a more crucial role. Both hydrochemistry and stable isotopes collectively indicated that there was a close hydraulic connectivity between the water content in river and permafrost active layer in the small alpine catchment. Based on the end-member mixing analysis model, the water in permafrost active layer and precipitation accounted for 62% and 38% of the runoff, respectively, indicating that it was dominated by permafrost during the ablation period. The warming and hu-midification of climate tend to facilitate permafrost degradation. Thus, studying the transformation of different water bodies in alpine regions is imperative to provide water resource security and sustainable development in alpine regions.

The Arctic soil communities play a vital role in stabilizing and decomposing soil carbon, which affects the global carbon cycling. Studying the food web structure is critical for understanding biotic interactions and the functioning of these ecosystems. Here, we studied the trophic relationships of (microscopic) soil biota of two different Arctic spots in Ny-angstrom lesund, Svalbard, within a natural soil moisture gradient by combining DNA analysis with stable isotopes as trophic tracers. The results of our study suggested that the soil moisture strongly influenced the diversity of soil biota, with the wetter soil, having a higher organic matter content, hosting a more diverse community. Based on a Bayesian mixing model, the community of wet soil formed a more complex food web, in which bacterivorous and detritivorous pathways were important in supplying carbon and energy to the upper trophic levels. In contrast, the drier soil showed a less diverse community, lower trophic complexity, with the green food web (via unicellular green algae and gatherer organisms) playing a more important role in channelling energy to higher trophic levels. These findings are important to better understand the soil communities inhabiting the Arctic, and for predicting how the ecosystem will respond to the forthcoming changes in precipitation regimes. Wetter soils, with a higher organic matter content, host more diverse soil biota and support more complex food webs, in which bacterivorous and detritivorous pathways are relevant in supplying energy.

Permafrost degradation due to climate warming is currently observed in the northeastern part of European Russia. Peat plateaus underlain by permafrost cover only about 20% of the Russian European cryolithozone but contain almost 50% of soil organic carbon stocks (SOC), which are considered to be vulnerable to microbial mineralization after permafrost thaw. The current study was performed at three key sites of peat plateaus located along the southern permafrost limit. SOC decomposition was studied by aerobic and anaerobic incubation experiments, conducted at 4 degrees C over a period of 1301 days. The CO2 production was measured in peat samples at three key sites from the active layer (AL), transitional layer (TL), permafrost layer (PL), and at one site from the deep permafrost layer (DPL), which is in contact with mineral soil at 3.7 m depth. During the experiment, the initial CO2 respiration rates significantly differed in the samples AL, TL and PL in all key sites. However, at each site in the majority of samples the CO2 respiration rates were 2-5 times aerobically higher than anaerobically. In anaerobic conditions, in all sites, the CO2 respiration rate in PL was the lowest, higher in TL and the highest in AL in all 3 sites. Projections of CO2 aerobically production for 80 years represent 1.44 +/- 0.11, 6.31 +/- 0.47, 30.64 +/- 17.98% of initial permafrost carbon from the samples of Inta 1, Inth 11 and Kolva respectively. But under anaerobical conditions estimates are close and indicate insignificant amounts 0.30... 1.90% of carbon release over a period of 80 years. We suggest that even under ideal conditions of the incubation experiment, without considering ecological inertia under natural conditions, while also permafrost temperature is close to zero, greenhouse gas release from initial SOC is significantly less than estimated.

The chemical and isotopic signatures of moderately volatile elements are useful for understanding processes of volatile depletion in planetary formation and differentiation. However, the fractionation factors between gas and melt phases during evaporation that are required to model these planetary volatile depletion processes are still sparse. In this study, twenty heating experiments were conducted in 1 atm gas-mixing furnaces to constrain the behavior of K, Cu, and Zn evaporation and isotopic fractionation from basaltic melts at high temperatures. The temperatures range from 1300 degrees C to 1400 degrees C, and durations are from 2 to 8 days. Oxygen fugacities (fO(2)) range from one log unit below to ten log units above that of the ironwu.stite buffer (IW-1 to IW + 10, corresponding to logfO(2) of -10.7 to -0.68 at 1400 degrees C). The conditions were selected to achieve an evaporation-dominated regime (where timescales of diffusion << evaporation for trace elements) in order to avoid diffusion-limited evaporation. Our results show during evaporation Zn behaved as the most volatile, followed by Cu and then K, regardless of temperature and oxygen fugacity. Partitioning of Zn into spinel layers within experimental capsules, however, has been observed, which has substantial effects on the Zn isotope fractionation factor. Therefore, Zn results are presented but further discussion is excluded. Element loss depends on both temperature and oxygen fugacity, where higher temperatures and lower oxygen fugacities promote evaporation. However, with varying temperature and oxygen fugacity, the kinetic isotopic fractionation factors, a (where, R/R-0 = f(alpha-) (1)), for K and Cu remain constant, thus these factors can be applied to a wider range of conditions than those in this study. The experimentally determined fractionation factors for K, and Cu during evaporation from basaltic melts are 0.9944, and 0.9961, respectively. The fractionation factors for these elements with varying volatilities are significantly larger than the apparent observed fractionation factors, which approach one and are inferred from lunar basalts relative to the Bulk Silicate Earth. This observation suggests near-equilibrium conditions during volatile-element loss from the Moon as the apparent observed fractionation factors of lunar basalts are similar for all three elements. (C) 2021 Elsevier Ltd. All rights reserved.

Rocks from the lunar interior are depleted in moderately volatile elements (MVEs) compared to terrestrial rocks. Most MVEs are also enriched in their heavier isotopes compared to those in terrestrial rocks. Such elemental depletion and heavy isotope enrichments have been attributed to liquid-vapor exchange and vapor loss from the protolunar disk, incomplete accretion of MVEs during condensation of the Moon, and degassing of MVEs during lunar magma ocean crystallization. New Monte Carlo simulation results suggest that the lunar MVE depletion is consistent with evaporative loss at 1,670 +/- 129 K and an oxygen fugacity +2.3 +/- 2.1 log units above the fayalite-magnetite-quartz buffer. Here, we propose that these chemical and isotopic features could have resulted from the formation of the putative Procellarum basin early in the Moon's history, during which nearside magma ocean melts would have been exposed at the surface, allowing equilibration with any primitive atmosphere together with MVE loss and isotopic fractionation.