Biomass residues from the agricultural industry, logging and wood processing activities have become a valuable fuel source. If processed under pyrolysis combustion, several products are generated. Bio-oil and gases are essential alternatives to fossil coal-based fuels for energy and electricity production, whose need is constantly growing. Biochar, the porous carbon-based lightweight product, often ends up as a soil fertilizer. However, it can be applied in other industrial sectors, e.g., in plastics production or in modifying cementitious materials intended for construction needs. This work dealt with the application of small amounts of softwood-based biochar up to 2.0 wt.% on hydration kinetics and a wide range of physical and mechanical properties, such as water transport characteristics and flexural and compressive strengths of modified cement pastes. In the comparison with reference specimens, the biochar incorporation into cement pastes brought benefits like the reduction of open porosity, improvement of strength properties, and decreased capillary water absorption of 7-day and 28-day-cured cement pastes. Moreover, biochar-dosed cement pastes showed an increase in heat evolution during the hydration process, accompanied by higher consumption of clinker minerals. Considering all examined characteristics, the optimal dosage of softwood-derived biochar of 1.0 wt.% of Portland cement can be recommended.

Although cemented soil as a subgrade fill material can meet certain performance requirements, it is susceptible to capillary erosion caused by groundwater. In order to eliminate the hazards caused by capillary water rise and to summarize the relevant laws of water transport properties, graphene oxide (GO) was used to improve cemented soil. This paper conducted capillary water absorption tests, unconfined compressive strength (UCS) tests, softening coefficient tests, and scanning electron microscope (SEM) tests on cemented soil using various contents of GO. The results showed that the capillary water absorption capacity and capillary water absorption rate exhibited a decreasing and then increasing trend with increasing GO content, while the UCS demonstrated an increasing and then decreasing trend. The improvement effect is most obvious when the content is 0.09%. At this content, the capillary absorption and capillary water absorption rate were reduced by 25.8% and 33.9%, respectively, and the UCS at 7d, 14d, and 28d was increased by 70.32%, 57.94%, and 61.97%, respectively. SEM testing results demonstrated that GO reduces the apparent void ratio of cemented soil by stimulating cement hydration and promoting ion exchange, thereby optimizing the microstructure and improving water resistance and mechanical properties. This research serves as a foundation for further investigating water migration and the appropriate treatment of GO-modified cemented soil subgrade.

Knowledge of the amount of unfrozen water and its migration in permafrost soils is important for understanding physico-chemical and biological processes. Here, we developed sub-routines in FREZCHEM and embedded them in the WATEREGO2 soil environmental model to: (a) estimate unfrozen water content under changing soil temperatures and water-ice phase changes; and (b) determine the effects of Van der Waals (VdW) and rheological forces driven by seasonal temperature variations on the transport of residual water and the long-term evolution of ground ice content over depths of 30 m. Together, the seasonal thermal regime and associated VdW and rheological forces on the transport of residual water lead to the evolution of distinct zones of ice-enrichment: near the surface of permafrost, at 3-5 m, 11-13 m and 17-19 m depth. The depths of ice enrichment are a function of soil thermal diffusivity, and the time needed to evolve the ground ice content is dependent on soil type, soil water chemistry and permafrost temperature. The model can explain observed variations with depth in ground ice content of icy permafrost soils and indicate that these conditions evolve over time. The findings can be used to assess the stability of permafrost to climate change under different temperature scenarios.

There is an obvious trend of climate warming and wetting on the Qinghai-Tibet Plateau during the past fifty years. Climate changes in air temperature or precipitation will inevitably influence the stability of permafrost. Previous studies mainly focus on the thermal influence of climate warming, but little is known about the induced rainfall infiltration and the hydrothermal response mechanism. Based on the meteorological data observed at Beiluhe observation station during 2013, the established water-vapor-heat transport model is used to predict the response under 1 degrees C and 2 degrees C increment of temperature, which considering the influences of rainfall. Climate change influences the thermal-moisture of permafrost mainly by changing the surface energy budget and soil hydrothermal transport components. The results show that climate warming greatly increased the surface net radiation, latent heat of evaporation and soil heat flux, decreased the sensible heat and rainfall infiltration. The rising air temperature reduces the soil moisture and soil hydraulic conductivity. Temperature gradient increases dramatically with temperature arising, further increases the moisture and energy components and reduces the components related to the water potential gradient. Climate warming increases the surface evaporation and thickness of active layer and accelerates the degradation of permafrost, which is contrary to the thermal effects of rainfall increasing.