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This study investigates salt weathering in the indoor, humid environment of China's Jinsha earthen site. Methods such as digital microscope, scanning electron microscopy (SEM), ion chromatography (IC), energy dispersive spectroscopy (EDS), and laser particle size analysis were employed to collect and analyze samples from four heavily weathered walls. The sampling approach took into account differences in depth and height and prioritized the extraction from various weathering layers to unveil the attributes, causes, and mechanisms of salt weathering. The findings indicate that the Jinsha site's eastern segment suffered salt-induced damage, such as powdering, salt crusts, and blistering, due to the presence of gypsum and magnesium sulfate. These salts were primarily sourced from groundwater. Groundwater ions ascended to the site's surface via capillary action, instigating various forms of salt damage. Salt damage severity has a direct link to salt and moisture content. The degradation patterns can be categorized into powder and multi-layered composite deterioration, both seems related to soil particle composition. Powder deterioration tends to occur when the sand content exceeds 40%. This research proposes preservation strategies that focus on managing groundwater and conducting environmental surveillance. These measures are designed to effectively address and mitigate the risks associated with salt damage.

期刊论文 2025-07-03 DOI: 10.1080/15583058.2024.2330954 ISSN: 1558-3058

The deterioration of soft rocks caused by freeze-thaw (F-T) climatic cycles results in huge structural and financial loss for foundation systems placed on soft rocks prone to F-T actions. In this study, cementtreated sand (CTS) and natural soft shale were subjected to unconfined compression and splitting tensile strength tests for evaluation of unconfined compressive strength (UCS, qu), initial small-strain Young's modulus (Eo) using linear displacement transducers (LDT) up to a small strain of 0.001%, and secant elastic modulus (E50) using linear variable differential transducers (LVDTs) up to a large strain of 6% before and after reproduced laboratory weathering (RLW) cycles (-20 degrees C-110 degrees C). The results showed that eight F-T cycles caused a reduction in qu, E50 and Eo, which was 8.6, 15.1, and 14.5 times for the CTS, and 2.2, 3.5, and 5.3 times for the natural shale, respectively. The tensile strength of the CTS and natural rock samples exhibited a degradation of 5.4 times (after the 8th RLW cycle) and 2.7 times (after the 15th RLW cycle), respectively. Novel correlations have been developed to predict Eo (response) from the parameters quand E50 (predictors) using MATLAB software's curve fitter. The findings of this study will assist in the design of foundations in soft rocks subjected to freezing and thawing. The analysis of variance (ANOVA) indicated 95% confidence in data health for the design of retaining walls, building foundations, excavation in soft rock, large-diameter borehole stability, and transportation tunnels in rocks for an operational strain range of 0.1%-0.01% (using LVDT) and a reference strain of less than 0.001% (using LDT). (c) 2025 Institute of Rock and Soil Mechanics, Chinese Academy of Sciences. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/ 4.0/).

期刊论文 2025-06-01 DOI: 10.1016/j.jrmge.2024.09.060 ISSN: 1674-7755

Debris flows pose significant threats due to their high velocity and fluid-like consistency. This research evaluates the intricate failure mechanisms of the rainfall-induced debris-flow event in Nenmara, Palakkad district, Kerala, India, on August 16, 2018, through detailed investigations. A geophysical (Multi-channel Analysis of Surface Waves (MASW)) test was carried out to obtain the shear wave velocity (Vs) of substrata. The dewpoint potentiometer and ring shear test were used to assess unsaturated soil strength and residual shear parameters to analyse the progressive failure mechanism of the landslide using the numerical model LS-RAPID. The mineralogical studies in the Nenmara region reveal that the soil originated from charnockite rocks containing quartz and clay minerals. The low Vs of 197 m/s at 2 m depth indicates the loose and unconsolidated soil layer at the site. The debris flow initiates when the pore water pressure ratio (ru) rises to 0.40 with a peak velocity of 11.9 m/s and 13.9 m/s in the X and Y directions, which led to the demolition of 3 buildings and the loss of 8 lives. The deterministic analysis reveals that ru above 0.30 can trigger a landslide near the Nenmara location. The rainfall threshold analysis suggests that 148 mm of daily or 210 mm of continuous rainfall over five days can trigger landslides around the Nenmara region. This research combines geophysical, geotechnical, and numerical simulations to make a substantial contribution to disaster management in comprehending the mechanism of debris flow by identifying triggering factors, and it will help to find the appropriate mitigation measures for future hill area development.

期刊论文 2025-02-01 DOI: 10.1007/s10064-025-04093-6 ISSN: 1435-9529

For rock structures exposed in the natural condition, water-induced weakening (including water softening and chemical weathering) is thought to be the main reason for its' stiffness and strength degradation, thus it is of great significance to study the mechanical properties of rocks under the influence of water. In this study, a hexagonal close-packed particle assembly (2D) composed of bonded circular particles with same diameter is considered to approximate a typical soft rock, where the composite contact model for rock materials considering the water-induced wakening is adopted to define the microscopic mechanical reactions between particles. Based on homogenisation theory and lattice model, the stress-strain relationship and strength criteria for rock considering water-induced weakening, as well as the quantitative correlation between macroscopic elastic and strength parameters with microscopic parameters are obtained. The effects of water softening and chemical weathering respectively characterised by saturation and mass loss ratio on macroscopic mechanical behaviours of rock are analysed in detail. The long-term ageing effects of water-induced weakening are also analysed. All results are in good agreement with the laboratory test results, verifying the applicability of the theoretical solution for analysing the effect of water-induced weakening on mechanical behaviours of rock.

期刊论文 2025-01-02 DOI: 10.1080/19648189.2024.2370855 ISSN: 1964-8189

Asbestos is a silicate mineral that occurs naturally and is made up of flexible fibres that are resistant to heat, fire, and chemicals and do not conduct electricity. Both anthropogenic disturbance and natural weathering of asbestos-containing waste materials (ACWMs) can result in the emission of asbestos fibre dust, which when breathed, can cause asbestosis, a chronic lung illness that happens due to prolonged exposure of such fibre dust, and can cause 'mesothelioma' cancer. Although asbestos mining and its utilisation had been banned in many countries, there is still a significant issue of ACWMs disposal in the built environment and abandoned sites. It is neither practical nor economical to safely eliminate ACWMs from the built environment, and it is estimated that globally, 4 billion metric tonnes of ACWMs require safe management strategies. The toxicity of inhaled asbestos fibre relies on its surface properties, and in particular the distribution of iron, which serves a critical role in pathogenicity by forming reactive free radicals that damage DNA, thereby trigging cancer. Examining the usefulness of higher plants and microbes in the bioremediation of soil contaminated with ACWMs is the prime aim of the review. Higher plants and microorganisms such as lichens, fungi, and bacteria often play a major role in the remediation of soil contaminated with ACWMs by facilitating the bioweathering of asbestos and the removal of iron to mitigate the toxicity of asbestos.

期刊论文 2025-01-01 DOI: 10.1071/SR25013 ISSN: 1838-675X

Terrestrial enhanced rock weathering (ERW) is a promising carbon dioxide removal technology that consists in applying ground silicate rock such as basalt on agricultural soils. On top of carbon sequestration, ERW has the potential to raise the soil pH and release nutrients, thereby improving soil fertility. Despite these possible co-benefits, concerns such as heavy metal pollution or soil structure damage have also been raised. To our knowledge, these contrasted potential effects of ERW on soil fertility have not yet been simultaneously investigated. This field trial aimed at assessing the impact of ERW on biological, physical, and chemical soil properties in a temperate agricultural context. To do so, three vineyard fields in Switzerland were selected for their distinct geochemical properties and were amended with basaltic rock powder at a dose of 20 tons per hectare (2 kg.m(-2)). On each field, basaltic rock powder was either applied one year before the sampling campaign, one month before the sampling campaign, or not applied (control) for a total of 27 plots with 9 repetitions of each level. Overall, basaltic rock powder addition had a predominantly positive to neutral effect on soil fertility. Most soil properties showed no significant change either 1 month or 1 year post application. Nevertheless, our study highlighted a significant increase in earthworm abundance (+71 % on average), soil respiration (+50 %) and extractable sodium concentration (+23 %) as early as 1 month post application. The higher soil respiration raises the question of CO2 losses from organic matter mineralization that could limit ERW's efficiency. The increase in sodium raises concerns about a sodification risk potentially damaging soil fertility. These elements now require further investigation before enhanced rock weathering can be considered a viable and secure carbon dioxide removal technology.

期刊论文 2024-12-01 DOI: 10.1016/j.scitotenv.2024.176297 ISSN: 0048-9697

Studying the effects of weathering on the mechanical properties and microscopic evolution of weathered granite soil (WGS) is essential for connecting microstructure with macroscopic behavior. This study conducts systematic monotonic and cyclic triaxial tests, along with a series of microscopic tests on WGS samples, to explore the influence of weathering on WGS mechanical properties and the mechanism of granite weathering. Results indicate that both effective internal friction angle and effective cohesion decrease progressively with increased weathering. Completely weathered granite (CWG) exhibits greater dynamic strength compared to granite residual soil (GRS). Additionally, as weathering progresses, quartz fragments are lost, while feldspar and biotite weather to form secondary minerals such as kaolinite and illite, leading to an overall enrichment in aluminum and iron in the granite. Weathering causes structural deterioration of WGS. Finally, the mechanical parameters of WGS and their chemical weathering indices show a coefficient of determination ranging from 60 to 99%. This study helps elucidate the fundamental causes of performance changes in WGS, thereby optimizing engineering design and enhancing disaster prediction accuracy, while providing new research perspectives and experimental evidence for WGS.

期刊论文 2024-10-17 DOI: 10.1038/s41598-024-75092-y ISSN: 2045-2322

Ny-& Aring;lesund, located in Arctic Svalbard, is one of the most sensitive areas on Earth to global warming. In recent years, accelerated glacier ablation has become remarkable in Ny-& Aring;lesund. Glacial meltwaters discharge a substantial quantity of materials to the ocean, affecting downstream ecosystems and adjacent oceans. In August 2015, various water samples were taken near Ny-& Aring;lesund, including ice marginal meltwater, proglacial meltwater, supraglacial meltwater, englacial meltwater, and groundwater. Trace metals (Al, Cr, Mn, Fe, Co, Cu, Zn, Cd, and Pb), major ions, alkalinity, pH, dissolved oxygen, water temperature and electric conductivity were also measured. Major ions were mainly controlled by chemical weathering intensity and reaction types, while trace metals were influenced by both chemical weathering and physicochemical control upon their mobility. Indeed, we found that Br & oslash;ggerbreen was dominated by carbonate weathering via carbonation of carbonate, while Austre Lov & eacute;nbreen and Pedersenbreen were dominated by sulfide oxidation coupled with carbonate dissolution with a doubled silicate weathering. The higher enrichment of trace metals in supraglacial meltwater compared to ice marginal and proglacial meltwater suggested anthropogenic pollution from atmospheric deposition. In ice marginal and proglacial meltwater, principal component analysis indicated that trace metals like Cr, Al, Co, Mn and Cd were correlated to chemical weathering. This implies that under accelerated glacier retreat, glacier-derived chemical components are subjected to future changes in weathering types and intensity.

期刊论文 2024-10-01 DOI: 10.1007/s13131-024-2385-9 ISSN: 0253-505X

Rock permeability, an important factor in subsurface fluid migration, can be influenced by microcracks and chemical weathering due to water-rock interactions. Understanding the relationship between permeability, chemical weathering, and microcracks is crucial for assessing fluid flow in rocks. This study focuses on the hydrogeological characteristics of granite and gneiss, potential host rocks for high-level radioactive waste disposal in South Korea. Samples were analyzed for permeability, porosity, P-wave velocity, and chemical weathering indices. Regression analysis revealed a weak correlation between permeability and both porosity and rock density, while an inverse correlation was observed between permeability and chemical weathering indices. Interestingly, some samples showed low permeability (10-21 to 10-22 m2) despite high weathering, while others showed high permeability (10-18 to 10-19 m2) despite low weathering. SEM-EDS analysis indicated the presence of microcracks within the rocks or the filling of these cracks with secondary minerals. The findings suggest that chemical weathering generally increases pore size and porosity, but actual permeability can vary depending on the presence and connectivity of microcracks and the extent to which they are filled with secondary minerals. Therefore, both chemical weathering and microcrack connectivity must be considered when evaluating the hydrogeological characteristics of crystalline rocks.

期刊论文 2024-10-01 DOI: 10.3390/w16203007

The study is concerned with the rate of evaporation from porous rock, including the second stage of evaporation characterised by the existence of a dry surface layer separated from the wet capillary zone by a sharp evaporation front. The main objective is to investigate the relationship between the depth of evaporation front and the rate of evaporation as the drying process progresses, and to compare measured evaporation rate with the corresponding calculated values. Sandstone core samples saturated with water were allowed to dry naturally under room conditions, while the changes in the evaporation rate and the depth of evaporation front, among other quantities, were measured. We demonstrate that the evaporation rate can be very accurately determined from the depth of the evaporation front and the ambient air temperature and relative humidity using Fick's law for water-vapor diffusion. During the second stage of evaporation, the diffusion flux through the dry surface layer is computed using the water-vapor diffusion coefficient of the rock, determined from a separate wet cup experiment. In order to cover the first stage of evaporation, an additional parameter characterising the diffusion layer of air above the surface is required, either determined by the best fit to the measured evaporation rates, or adopted from previous studies. The calculated evaporation rate was in good agreement with measurements, with Pearson correlation coefficient 0.98 and relative error of the calculations averaging 15% over the evaporation front depths ranging from 0 to 29 mm. A workflow for determining the evaporation rate from sandstone outcrops is suggested, along with possible applications in sandstone weathering research.

期刊论文 2024-09-01 DOI: 10.3390/hydrology11090133
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