Black carbon (BC) mixed with non-BC components strongly absorbs visible light and leads to uncertainty in assessing the absorption enhancement (Eabs) and thus radiative forcing. Traditional Single-Particle Soot Photometer (SP2) combined with the leading-edge only fitting (the only-SP2 method) derives BC's mixing states through Mie scattering calculations. However, errors exist in retrieved optical diameter (Dopt) and MR due to the assumption of the ideal spherical core-shell structure and the selection of the calculation parameters like density and refractive index (RI) of the components. Here, we employed a custom-developed tandem CPMA-SP2 system, which classifies fixed-mass BC to characterize the mixing state, then compared with the only-SP2 method in quantifying the mixing state and Eabs. The field measurements show that the SP2 demonstrates variability in assessing the mixing state of BC in different aging states. The thickly-coated particles with small core approaching the internally mixed state are more sensitive to the change of calculated RI. The Dopt decreases with the RI increasing, indicating that this method accurately measures both Dopt and Eabs when a reasonable refractive index is selected for calculation. However, for thinly-coated particles with moderate or large core, this method results in significant deviations in the computed Eabs (errors up to 15 %). These deviations may be caused by the various shapes of BC and systematic errors. Our results provide valuable insights into the accuracy of the SP2-retrieved Dopt and MR based on Mie calculations and highlight the importance of employing advanced techniques for further assessment of BC's mixing state.
Permafrost soils contain approximately twice the amount of carbon as the atmosphere and this carbon could be released with Arctic warming, further impacting climate. Mosses are major component of Arctic tundra ecosystems, but the environmental drivers controlling heat penetration though the moss layer and into the soil and permafrost are still debated, especially at fine spatial scales where microtopography impacts both vegetation and soil moisture. This study measured soil temperature profiles (1-15 cm), summer thaw depth, water table depth, soil moisture, and moss thickness at a fine spatial scale (2 m) together with meteorological variables to identify the most important controls on the development of the thaw depth during two Arctic summers. We found a negative relationship between the green moss thickness (up to 3 cm) and the soil temperatures at 15 cm, suggesting that mosses insulated the soil even at high volumetric water contents (>70%) in the top 5 cm. A drier top (2-3 cm) green moss layer better insulated deep (15 cm) soil layers by reducing soil thermal conductivity, even if the moss layers immediately below the top layer were saturated. The thickness of the top green moss layer had the strongest relationships with deeper soil temperatures, suggesting that the top layer had the most relevant role in regulating heat transfer into deeper soils. Further drying of the top green moss layer could better insulate the soil and prevent permafrost thawing, representing a negative feedback on climate warming, but damage or loss of the moss layer due to drought or fire could reduce its insulating effects and release carbon stored in the permafrost, representing a positive feedback to climate warming.
The thermal stability of permafrost, a foundation for engineering infrastructure in cold regions, is increasingly threatened by the dual stressors of climate change and anthropogenic disturbance. This study investigates the dynamics of the crushed rock revetted embankment at the Kunlun Mountain Section of the Qinghai-Tibet Railway, systematically investigating the coupled impacts of climate warming and engineering activities on permafrost thermal stability using borehole temperature monitoring data (2008-2024) and climatic parameter analysis. Results show that under climate-driven effects, the study area experienced an air temperature increase of 0.2 degrees C per decade over the 2015-2024. Concurrently, the mean annual air thawing degree-days (TDD) rose by 13.8 degrees C center dot d/a, leading to active-layer thickening at a rate of 3.8 cm center dot a- 1at natural ground sites. From 2008 to 2024, the active layer had thickened by 0.7-0.8 m. At the embankment toe (BH 5), the active-layer thickening rate (3.3 cm center dot a- 1) was 25 % lower than that at the natural ground borehole (3.8 cm center dot a- 1); correspondingly, the underlying permafrost temperature increase rate at the toe (0.3 degrees C per decade) was lower than that at the natural borehole (0.5-0.6 degrees C per decade). Permafrost warming rates decreased with depth. Shallow layers (above -2 m) were significantly influenced by climate, with warming rates of 0.3-0.6 degrees C per decade. In contrast, deep layers (below -10 m) showed warming rates converging with the background atmospheric temperature trend (0.2 degrees C per decade). Thermal regime disturbance was most pronounced at horizontal distances of 3.0-5.0 m from the embankment. Nevertheless, the crushed-rock revetment maintained a permafrost table 0.6 m shallower than that of natural ground, confirming its thermal diode effect (facilitating convective cooling in winter), which partially offset climate warming impacts. This study provides critical empirical data and validates the cooling mechanism of crushed-rock revetment, which is essential for predicting the long-term thermal stability and informing adaptive maintenance strategies for railway infrastructure in warming permafrost regions.
Slope failures resulting from thaw slumps in permafrost regions, have developed widely under the influence of climate change and engineering activities. The shear strength at the interface between the active layer and permafrost (IBALP) at maximum thawing depth is a critical factor to evaluate stability of permafrost slopes. Traditional direct shear, triaxial shear, and large-scale in-situ shear experiments are unsuitable for measuring the shear strength parameter of the IBALP. Based on the characteristics of thaw slumps in permafrost regions, this study proposes a novel test method of self-weight direct shear instrument (SWDSI), and its principle, structure, measurement system and test steps are described in detail. The shear strength of the IBALP under maximum thaw depth conditions is measured using this method. The results show that under the condition that the permafrost layer is thick underground ice and the active layer consists of silty clay with 20% water content, the test results are in good agreement with the results of field large-scale direct shear tests and are in accordance with previous understandings and natural laws. The above analysis indicates that the method of the SWDSI has a reliable theoretical basis and reasonable experimental procedures, and meets the needs of stability assessment of thaw slumps in permafrost regions. The experimental data obtained provide important parameter support for the evaluation of related geological hazards.
Here, we present the result of different models for active layer thickness (ALT) in an area of the Italian Central Alps where a few information about the ALT is present. Looking at a particular warm year (2018), we improved PERMACLIM, a model used to calculate the Ground Surface Temperature (GST) and applied two different versions of Stefan's equation to model the ALT. PERMACLIM was updated refining the temporal basis (daily respect the monthly means) of the air temperature and the snow cover. PERMACLIM was updated also to minimize the bias of the snow cover in summer months using the PlanetScope images. Moreover, the contribution of the solar radiation was added to the air temperature to improve the summer GST. The modelled GST showed a good calibration and, among the two versions of Stefan's equation, the first (ALT1) indicates a maximum active layer thickness of 7.5 m and showed a better accuracy with R2 of 0.93 and RMSE of 0.32 m. The model underlined also the importance of better definition of the thermal conductivity of the ground that can strongly influence the ALT.
On December 18, 2023, a magnitude MS6.2 earthquake struck Jishishan County, Gansu Province, triggering over 40 seismic subsidence sites within a seismic intensity VI zone, 32 km from the epicenter.The earthquake caused tens of millions in economic losses to mountain photovoltaic power stations. Extensive geological surveys and comparisons with similar landslides (such as soil loosening, widespread cracks, and stepped displacements) triggered by the 1920 Haiyuan MS8.5 earthquake and the 1995 Yongdeng MS5.8 earthquake, this study preliminarily identifies one subsidence sites as a seismic-collapsed loess landslide. To investigate its disaster-causing mechanism: the dynamic triaxial test was conducted to assess the seismic subsidence potential of the loess at the site, and the maximum subsidence amount under different seismic loads were calculated by combining actual data from nearby bedrock stations with site amplification data from the active source; simulation of the destabilization evolution of seismic-collapsed loess landslides by large-scale shaking table tests; and a three-dimensional slope model was developed using finite element method to study the complex seismic conditions responsible for site damage. The research findings provide a theoretical foundation for further investigations into the disaster mechanisms of seismic-collapsed loess landslides.
Permafrost is undergoing widespread degradation affected by climate change and anthropogenic factors, leading to seasonal freezing and thawing exhibiting interannual, and fluctuating differences, thereby impacting the stability of local hydrological processes, ecosystems, and infrastructure. To capture this seasonal deformation, scholars have proposed various InSAR permafrost deformation models. However, due to spatial-temporal filtering smoothing high-frequency deformation and the presence of approximate assumptions in permafrost models, such differences are often difficult to accurately capture. Therefore, this paper applies an InSAR permafrost monitoring method based on moving average models and annual variations to detect freezing and thawing deformation in the Russian Novaya Zemlya region from 2017 to 2021 using Sentinel-1 data. Most of the study area's deformation rates remained between 10 and 10 mm/yr, while in key oil extraction areas, they reached -20 mm/yr. Seasonal deformation amplitudes were relatively stable in urban areas, but reached 90 mm in regions with extensive development of thermokarst lakes, showing a significant increasing trend. To validate the accuracy of the new method in capturing seasonal deformations, we used seasonal deformations obtained from different methods to retrieval the Active Layer Thickness (ALT), and compared them with field ALT measurement data. The results showed that the new method had a smaller RMSE and improved accuracy by 5% and 30% in two different ALT observation areas, respectively, compared to previous methods. Additionally, by combining the spatial characteristics of seasonal deformation amplitudes and ALT, we analyzed the impact of impermeable surfaces, confirming that human-induced surface hardening alters the feedback mechanism of perennial frozen soil to climate.
Thawing-triggered slope failures and landslides are becoming an increasing concern in cold regions due to the ongoing climate change. Predicting and understanding the behaviour of frozen soils under these changing conditions is therefore critical and has led to a growing interest in the research community. To address this challenge, we present the first mesh-free smoothed particle hydrodynamics (SPH) computational framework designed to handle the multi-phase and multi-physic coupled thermo-hydro-mechanical (THM) process in frozen soils, namely the THM-SPH computational framework. The frozen soil is considered a tri-phase mixture (i.e., soil, water and ice), whose governing equations are then established based on u-p-T formulations. A critical-state elasto-plastic Clay and Sand Model for Frozen soils (CASM-F), formulated in terms of solid-phase stress, is then introduced to describe the transition response and large deformation behaviour of frozen soils due to thawing action for the first time. Several numerical verifications and demonstrations highlight the usefulness of this advanced THM-SPH computational framework in addressing challenging problems involving thawing-induced large deformation and failures of slopes. The results indicate that our proposed single-layer, fully coupled THM-SPH model can predict the entire failure process of thawing-induced landslides, from the initiation to post-failure responses, capturing the complex interaction among multiple coupled phases. This represents a significant advancement in the numerical modelling of frozen soils and their thawing-induced failure mechanisms in cold regions.
The direct radiative impact of atmospheric aerosols remains more uncertain than that of greenhouse gases, largely due to the complex transformations' aerosols undergo during atmospheric aging. Sulfate aerosols have been the subject of considerable research, with a robust body of literature characterising their cooling effect. In contrast, the light-absorbing properties and warming potential of black carbon and related products remain less well understood, with limited research available to date. The present study examines the iron-catalyzed reaction of catechol in levitated microdroplets, tracked in situ using elastic light scattering spectroscopy. The reaction forms water-insoluble polycatechol aggregates, which drive a transition from homogeneous spheres to heterogeneous droplets with internal inclusions. To interpret the evolving optical behaviour, the Multiple Sphere T-Matrix (MSTM) model is employed, a method which overcomes the limitations of Mie theory by accounting for internal morphological complexity. The model provides realistic complex refractive indices and fractal parameters, though it should be noted that its solutions are not unique due to sensitivity to input assumptions and droplet variability. This underscores the necessity for supplementary measurements and more comprehensive models incorporating evaporation, chemical dynamics, and phase transitions. These findings emphasise the potential of elastic scattering spectroscopy for real-time monitoring of multiphase chemistry and offer new constraints for improving aerosol aging schemes in climate models, thereby contributing to reduced uncertainties in aerosol radiative forcing.
When developing Arctic territories, studying and forecasting the state of cryogenic landscapes in the context of climate change plays an important role. General conclusions about permafrost degradation do not fully capture changes at regional and local levels, as the direction and pace of landscape transformation depend on many factors, including the specific characteristics of the terrain. Permafrost degradation and changes in the depth of the active layer thickness (ALT) can be accompanied by alterations in ground vegetation cover (GVC) and surface moisture, which can be recorded through remote sensing (RS) data. However, there is a knowledge gap regarding the use of RS data to identify long-term trends in the phytocenotic properties of GVC and soil moisture at different geomorphological levels, as well as to determine the relationship between these trends and changes in ALT. In this study, based on Landsat data from 1985 to 2024, changes in GVC and soil moisture across various geomorphological levels were identified in a local area of the Yamal Peninsula. The analysis used the NDVI vegetation index, the NDWI moisture index, and the WI (Wetness Index) temperature-vegetation index, which reflects the moisture content of GVC and soil. The general trend observed is an increase in the growth rates of these indices as the geomorphological levels rise from the floodplain to Terrace IV. A comparison of these observed trends in the NDVI, NDWI, and WI indices with in situ geocryological observations shows the potential of using these indices as indicators of ALT change.