Climate change is transforming the ice-free areas of Antarctica, leading to rapid changes in terrestrial ecosystems. These areas represent <0.5% of the continent and coincide with the most anthropogenically pressured sites, where the human footprint is a source of contamination. Simultaneously, these are the locations where permafrost can be found, not being clear what might be the consequences following its degradation regarding trace element remobilisation. This raises the need for a better understanding of the natural geochemical values of Antarctic soils as well as the extent of human impact in the surroundings of scientific research stations. Permafrost thaw in the Western Antarctic Peninsula region and in the McMurdo Dry Valleys is the most likely to contribute to the remobilisation of toxic trace elements, whether as the result of anthropogenic contamination or due to the degradation of massive buried ice and ice-cemented permafrost. Site-specific locations across Antarctica, with abandoned infrastructure, also deserve attention by continuing to be a source of trace elements that later can be released, posing a threat to the environment. This comprehensive summary of trace element concentrations across the continent's soils enables the geographical systematisation of published results for a better comparison of the literature data. This review also includes the used analytical techniques and methods for trace element dissolution, important factors when reporting low concentrations. A new perspective in environmental monitoring is needed to investigate if trace element remobilisation upon permafrost thaw might be a tangible consequence of climate change.

This manuscript presents a comprehensive presentation of ground temperature data collected at 16 nodes of the 121 of the Crater Lake Circumpolar Active Layer Monitoring (CALM) site on Deception Island, Antarctica, from 2008 to early 2022. Each one of the 16 shallow boreholes has been equipped with miniature temperature loggers, providing valuable insights into the thermal regime of the ground at a depth of 50 cm, which corresponds to the mean depth of the top of the permafrost table as observed by annual mechanical probing in the CALM site. Despite a 9-month long gap in data collection during 2017 due to persistent snow cover, the time series remains largely intact, with annual measurements taken every 3 h. The manuscript details the methodologies employed for data collection, including the use of iButton loggers, and outlines the challenges faced in retrieving and processing the data in the harsh Antarctic environment. The cleaned dataset, which consolidates data from various nodes while removing erroneous records, is made freely accessible to the scientific community without any additional processing of the data such as offset corrections or gaps interpolation. This resource is expected to facilitate further research into the thermal dynamics of the active layer and permafrost and its implications for climate change since both are influenced by external factors such as snow cover, air temperature and others. Overall, the presented dataset contributes to the limited body of knowledge regarding Antarctic permafrost and provides a foundation for future investigations into the effects of climate change on frozen ground dynamics. The dataset serves as a vital tool for researchers aiming to model ground thermal behaviour and assess the impacts of environmental changes in polar regions.

Continuous permafrost is present across the McMurdo Dry Valleys of southern Victoria Land, Antarctica. While summer active-layer thaw is common in the low-elevation portions of the Dry Valleys, active layers have not significantly thickened over time. However, in some locations, coastal Antarctic permafrost has begun to warm. Here, based on soil and meteorological measurements from 1993 to 2023, we show that wintertime soil temperatures have increased across multiple sites in the Dry Valleys, at rates exceeding the pace of summer soil warming. Linear warming trends over time are significant (P < 0.05) at six of seven soil monitoring sites. Winter warming is strongly correlated with increased numbers of down-valley wind events (Foehn/katabatics), but it may also be driven by increased incident longwave radiation at some stations (although winter longwave increase is not significant over time). While down-valley wind events increase winter warming, when down-valley wind events are excluded from the record, winter soil warming remains persistent and significant, suggesting that Antarctic soils are experiencing less cold winters over time in response to regional warming. Together, these observations suggest that some Antarctic permafrost may be approaching a transition to discontinuous permafrost in some regions as winter freezing intensity is reduced over time.

This study shows the impact of black carbon (BC) aerosol atmospheric rivers (AAR) on the Antarctic Sea ice retreat. We detect that a higher number of BC AARs arrived in the Antarctic region due to increased anthropogenic wildfire activities in 2019 in the Amazon compared to 2018. Our analyses suggest that the BC AARs led to a reduction in the sea ice albedo, increased the amount of sunlight absorbed at the surface, and a significant reduction of sea ice over the Weddell, Ross Sea (Ross), and Indian Ocean (IO) regions in 2019. The Weddell region experienced the largest amount of sea ice retreat (similar to 33,000 km(2)) during the presence of BC AARs as compared to similar to 13,000 km(2) during non-BC days. We used a suite of data science techniques, including random forest, elastic net regression, matrix profile, canonical correlations, and causal discovery analyses, to discover the effects and validate them. Random forest, elastic net regression, and causal discovery analyses show that the shortwave upward radiative flux or the reflected sunlight, temperature, and longwave upward energy from the earth are the most important features that affect sea ice extent. Canonical correlation analysis confirms that aerosol optical depth is negatively correlated with albedo, positively correlated with shortwave energy absorbed at the surface, and negatively correlated with Sea Ice Extent. The relationship is stronger in 2019 than in 2018. This study also employs the matrix profile and convolution operation of the Convolution Neural Network (CNN) to detect anomalous events in sea ice loss. These methods show that a higher amount of anomalous melting events were detected over the Weddell and Ross regions. Impact Statement Sea ice protects ice sheets, which are melting at a very high rate to raise the sea level. In addition to global warming, this study is indicative that black carbon aerosols transported from anthropogenic wildfire events, such as from the Amazon, darken the snow, reduce their reflectance, increase the absorption of solar energy incident on the surface, and exacerbate the sea ice retreat. Thus, this study points out that anthropogenic wildfire impacts far away from a region can have a severe impact on sea ice and ice sheets over the Antarctic which has a sea level rise potential of 60 m. Our study shows that only over the Weddell region, sea ice retreat was 20,000 km(2) higher during the presence of BC transport events than other days in 2019.

Maritime Antarctica has a milder climate than the Antarctic continent and is naturally more sensitive to rising global temperature. Therefore, it is necessary to understand the soils, including those with permafrost, as well as the relief and the occurrence of organic carbon at Byers Peninsula. This study aims therefore to investigate soil physical and chemical properties at Byers Peninsula, Maritime Antarctica, in particular, the distribution of organic carbon. Thirteen soil profiles were described, collected, and subjected to a physical, chemical, and spatial analysis. Colonization by avifauna and vegetation is important for inputing soil organic carbon at Byers Peninsula. Cryoturbation and permafrost are crucialforthe redistribution of the C pool. Distribution of organic carbon on the Byers Peninsula have shown that its concentrations are higher and more punctual at the surface, but also that carbon has been redistributed to deeper layers. Gelisols (Cryosols) are important C pools. They are extremely useful from the environmental monitoring perspective as they represent areas sensitive to temperature increases on the Antarctic Peninsula caused by global climate changes. Using geomorphological groups is one way to improve the understanding of these relief forms, soil and rocktypes, vegetation patterns, and the presence of permafrost.

To better understand the changes in the hydrologic cycle caused by global warming in Antarctica, it is crucial to improve our understanding of the groundwater flow system, which has received less attention despite its significance. Both hydraulic and thermal properties of the active layer, through which groundwater can flow during thawing seasons, are essential to quantify the groundwater flow system. However, there has been insufficient information on the Antarctic active layer. The goal of this study was to estimate the hydraulic and thermal properties of Antarctic soils through laboratory column experiments and inverse modeling. The column experiments were conducted with sediments collected from two lakes in the Barton Peninsula, Antarctica. A sand column was also operated for comparison. Inverse modeling using HydroGeoSphere (HGS) combined with Parameter ESTimation (PEST) was performed with data collected from the column experiments, including permeameter tests, saturation -drain tests, and freeze -thaw tests. Hydraulic parameters (i.e., K s , theta s , S wr , alpha , beta, and S s ) and thermal diffusivity ( D ) of the soils were derived from water retention curves and temperature curves with depth, respectively. The hydraulic properties of the Antarctic soil samples, estimated through inverse modeling, were 1.6 x 10 - 5 -3.4 x 10 -4 cm s -1 for K s , 0.37 -0.42 for theta s , 6.62 x 10 - 3 -1.05 x 10 -2 for S wr , 0.53 -0.58 cm - 1 for alpha, 5.75 -7.96 for beta, and 5.11 x 10 - 5 -9.02 x 10 -5 cm - 1 for S s . The thermal diffusivities for the soils were estimated to be 0.65-4.64 cm 2 min -1 . The soil hydraulic and thermal properties reflected the physical and ecological characteristics of their lake environments. The results of this study can provide a basis for groundwater -surface water interaction in polar regions, which is governed by variably -saturated flow and freezethaw processes.

The present world faces a new threat of ancient microbes and resistomes that are locked in the cryosphere and now releasing upon thawing due to climate change and anthropogenic activities. The cryosphere act as the best preserving place for these microbes and resistomes that stay alive for millions of years. Current reviews extensively discussed whether the resurrection of microbes and resistomes existing in these pristine environments is true or just a hype. Release of these ancient microorganisms and naked DNA is of great concern for society as these microbes can either cause infections directly or they can interact with contemporary microorganisms and affect their fitness, survival, and mutation rate. Moreover, the contemporary microorganisms may uptake the unlocked naked DNA, which might transform non-pathogenic microorganisms into deadly antibiotic-resistant microbes. Additionally, the resurrection of glacial microorganisms can cause adverse effects on ecosystems downstream. The release of glacial pathogens and naked DNA is real and can lead to fatal outbreaks; therefore, we must prepare ourselves for the possible reemergence of diseases caused by these microbes. This study provides a scientific base for the adoption of actions by international cooperation to develop preventive measures.

Cryoconite holes are structures characteristic of the glacierised ablation areas, formed from dark sediment deposition which melt the glacier ice leading to their cylindrical structure formation. The present study focuses on an unstudied blue ice area of East Antarctica over the Hells Gate Ice Shelf in Northern Victoria Land. Taking advantage of neural network methodology applied on drone acquisitions, an automatic detection of cryoconite holes was carried out (88% of accuracy), mapping similar to 3500 m(2) (0.4% fractional cover) of cryoconite holes over an area of 900 000 m(2). The surveyed area showed heterogeneity in cryoconite hole distribution, with some regions showing an area fraction of holes (regions exhibiting frozen ponds and ice bands) as high as 8%. Thanks to this detection, the spatially integrated radiative forcing of cryoconite holes over blue ice surface was estimated to be almost 1 Wm(-2). This estimation was based on the measured albedo difference between the two surfaces, which averages 0.31. However, the radiative forcing is strongly increased if calculated at a single cryoconite hole scale, showing an average of similar to 200 Wm(-2). In conclusion, the present research represents a first attempt of analysing cryoconite holes as factors impacting the blue ice in Northern Victoria Land, deepening our understanding of their glaciological role at the margins of the East Antarctic Ice Sheet.

The seasonal movement of the zero-degree isotherm across the Southern Ocean and Antarctic Peninsula drives major changes in the physical and biological processes around maritime Antarctica. These include spatial and temporal shifts in precipitation phase, snow accumulation and melt, thawing and freezing of the active layer of the permafrost, glacier mass balance variations, sea ice mass balance and changes in physiological processes of biodiversity. Here, we characterize the historical seasonal southward movement of the monthly near-surface zero-degree isotherm latitude (ZIL), and quantify the velocity of migration in the context of climate change using climate reanalyses and projections. From 1957 to 2020, the ZIL exhibited a significant southward shift of 16.8 km decade(-1) around Antarctica and of 23.8 km decade(-1) in the Antarctic Peninsula, substantially faster than the global mean velocity of temperature change of 4.2 km decade(-1), with only a small fraction being attributed to the Southern Annular Mode (SAM). CMIP6 models reproduce the trends observed from 1957 to 2014 and predict a further southward migration around Antarctica of 24 +/- 12 km decade(-1) and 50 +/- 19 km decade(-1) under the SSP2-4.5 and SSP5-8.5 scenarios, respectively. The southward migration of the ZIL is expected to have major impacts on the cryosphere, especially on the precipitation phase, snow accumulation and in peripheral glaciers of the Antarctic Peninsula, with more uncertain changes on permafrost, ice sheets and shelves, and sea ice. Longer periods of temperatures above 0 degrees C threshold will extend active biological periods in terrestrial ecosystems and will reduce the extent of oceanic ice cover, changing phenologies as well as areas of productivity in marine ecosystems, especially those located on the sea ice edge.

The absence of vegetation in most ice-free areas of Antarctica makes the soil surface very sensitive to atmosphere dynamics, especially in the western sector of the Antarctic Peninsula, an area within the limits of the permafrost zone. To evaluate the possible effects of regional warming on frozen soils, we conducted an analysis of ground surface temperatures (GSTs) from 2007 to 2021 from different monitoring sites in Livingston and Deception islands (South Shetlands archipelago, Antarctica). The analysis of the interannual evolution of the GST and their daily regimes and the freezing and thawing indexes reveals that climate change is showing impacts on seasonal and perennially frozen soils. Freezing Degree Days (FDD) have decreased while Thawing Degree Day (TDD) have increased during the study period, resulting in a balance that is already positive at the sites at lower elevations. Daily freeze-thaw cycles have been rare and absent since 2014. Meanwhile, the most common thermal regimes are purely frozen - F1 (daily temperatures = +0.5 degrees C). A decrease in F1 days has been observed, while the IS and T1 days increased by about 60 days between 2007 and 2021. The annual number of days with snow cover increased between 2009 and 2014 and decreased since then. The GST and the daily thermal regimes evolution point to general heating, which may be indicative of the degradation of the frozen soils in the study area.