Under environment with various water contents, the variations in the mixing state and particle size of coated black carbon (BC) aerosols cause changes in optical and radiative effects. In this study, fractal models for thinly, partially, and thickly coated BC under six relative humidities (RHs 1/4 0-95%) are constructed and optically simulated at 1064 and 532 nm. Differential scattering cross-sections are selected to retrieve the mixing state (Dp/Dc) of BC to investigate the possible retrieval errors caused by the nonspherical morphology when using the single-particle soot photometer (SP2). Furthermore, the radiative forcing of BC aerosols at different RHs are analyzed. Results showed that the retrieval errors (REs) of Dp/Dc are negative for coated particles with BC volume fraction smaller than 0.10, indicating that the mixing states of coated fractal BC are underestimated during the hygroscopic growth. The partiallycoated BC has the best retrieval accuracy of the mixing state, followed by the closed-cell and coatedaggregate model, judging from averaged REs. Radiative forcing enhancements for partially-coated aerosols with different BC volume fractions exponentially increase to opposite values, resulting in a warming or cooling effect. This study helps understand the uncertainties in Dp/Dcof BC aerosols retrieved by SP2 and their radiative forcing at different RHs. (c) 2025 Chinese Society of Particuology and Institute of Process Engineering, Chinese Academy of Sciences. Published by Elsevier B.V. All rights are reserved, including those for text and data mining, AI training, and similar technologies.

In this research, we studied the effects of black carbon (BC) aerosol radiative forcing on seasonal variation in the Northern Hemisphere (NH) using numerical simulations with the NASA finite-volume General Circulation Model (fvGCM) forced with monthly varying three-dimensional aerosol distributions from the Goddard Ozone Chemistry Aerosol Radiation and Transport Model (GOCART). The results show that atmospheric warming due to black carbon aerosols subsequently warm the atmosphere and land surfaces, especially those over Eurasia. As a result, the snow depth in Eurasia was greatly reduced in late winter and spring, and the reduction in snow cover decreased the surface albedo. Our surface energy balance analysis shows that the surface warming due to aerosol absorption causes early snow melting and further increases surface-atmosphere warming through snow/ice albedo feedback. Therefore, BC aerosol forcing may be an important factor affecting the snow/ice albedo in the NH.

The effects of black carbon (BC) aerosol radiative forcing on spring rainfall in Southeast Asia are studied using numerical simulations with the NASA finite-volume General Circulation Model (fvGCM) forced with monthly varying three-dimensional aerosol distributions from the Goddard Ozone Chemistry Aerosol Radiation and Transport model (GOCART). During the boreal spring, March-April-May (MAM), BC from local emissions accumulates over Southeast Asia. The BC aerosol layer, which extends from the surface to higher elevation above planetary boundary layer (PBL), absorbs solar radiation and heats the mid-troposphere through a semi-direct effect over regions of large aerosol optical thickness (AOT) and thereby significantly perturbs large-scale and meridional circulations. Results show that anomalous precipitation patterns and associated large-scale circulations induced by radiative forcing by BC aerosol can explain observed precipitation reductions, especially over Southeast Asia. Therefore, BC aerosol forcing may be one of the important factors affecting the spring rainfall trend over Southeast Asia. (C) 2010 Elsevier Ltd. All rights reserved.