Permafrost soils contain approximately twice the amount of carbon as the atmosphere and this carbon could be released with Arctic warming, further impacting climate. Mosses are major component of Arctic tundra ecosystems, but the environmental drivers controlling heat penetration though the moss layer and into the soil and permafrost are still debated, especially at fine spatial scales where microtopography impacts both vegetation and soil moisture. This study measured soil temperature profiles (1-15 cm), summer thaw depth, water table depth, soil moisture, and moss thickness at a fine spatial scale (2 m) together with meteorological variables to identify the most important controls on the development of the thaw depth during two Arctic summers. We found a negative relationship between the green moss thickness (up to 3 cm) and the soil temperatures at 15 cm, suggesting that mosses insulated the soil even at high volumetric water contents (>70%) in the top 5 cm. A drier top (2-3 cm) green moss layer better insulated deep (15 cm) soil layers by reducing soil thermal conductivity, even if the moss layers immediately below the top layer were saturated. The thickness of the top green moss layer had the strongest relationships with deeper soil temperatures, suggesting that the top layer had the most relevant role in regulating heat transfer into deeper soils. Further drying of the top green moss layer could better insulate the soil and prevent permafrost thawing, representing a negative feedback on climate warming, but damage or loss of the moss layer due to drought or fire could reduce its insulating effects and release carbon stored in the permafrost, representing a positive feedback to climate warming.

Large-scale wildfires are essential sources of black carbon (BC) and brown carbon (BrC), affecting aerosol-induced radiative forcing. This study investigated the impact of two wildfire plumes (Plume 1 and 2) transported to Moscow on the optical properties of BC and BrC during August 2022. During the wildfires, the total light absorption at 370 nm (b(abs_370nm)) increased 2.3-3.4 times relative to background (17.30 +/- 13.98 Mm(-)(1)), and the BrC contribution to total absorption increased from 14 % to 42-48 %. BrC was further partitioned into primary (BrCPri) and secondary (BrCSec) components. Biomass burning accounted for similar to 83-90 % of BrCPri during the wildfires. The b(abs_370nm) of BrCPri increased 5.6 times in Plume 1 and 11.5 times in Plume 2, due to the higher prevalence of peat combustion in Plume 2. b(abs_370nm) of BrCSec increased 8.3-9.6 times, driven by aqueous-phase processing, as evidenced by strong correlations between aerosol liquid water content and b(abs_370nm) of BrCSec. Daytime b(abs_370nm) of BrCSec increased 7.6 times in Plume 1 but only 3.6 times in Plume 2, due to more extensive photobleaching, as indicated by negative correlations with oxidant concentrations and longer transport times. The radiative forcing of BrCPri relative to BC increased 1.8 times in Plume 1 and Plume 2. In contrast, this increase for BrCSec was 3.4 times in Plume 1 but only 2.3 times in Plume 2, due to differences in chemical processes, which may result in higher uncertainty in its radiative forcing. Future work should prioritize elucidating both the emissions and atmospheric processes to better quantify wildfire-derived BrC and its radiative forcing.

Soil organic matter (SOM) stability in Arctic soils is a key factor influencing carbon sequestration and greenhouse gas emissions, particularly in the context of climate change. Despite numerous studies on carbon stocks in the Arctic, a significant knowledge gap remains regarding the mechanisms of SOM stabilization and their impact on the quantity and quality of SOM across different tundra vegetation types. The main aim of this study was to determine SOM characteristics in surface horizons of permafrost-affected soils covered with different tundra vegetation types (pioneer tundra, arctic meadow, moss tundra, and heath tundra) in the central part of Spitsbergen (Svalbard). Physical fractionation was used to separate SOM into POM (particulate organic matter) and MAOM (mineral-associated organic matter) fractions, while particle-size fractionation was applied to evaluate SOM distribution and composition in sand, silt, and clay fractions. The results indicate that in topsoils under heath tundra POM fractions dominate the carbon and nitrogen pools, whereas in pioneer tundra topsoils, the majority of the carbon and nitrogen are stored in MAOM fractions. Moreover, a substantial proportion of SOM is occluded within macro-and microaggregates. Furthermore, the results obtained from FTIR analysis revealed substantial differences in the chemical properties of individual soil fractions, both concerning the degree of occlusion in aggregates and across particle size fractions. This study provides clear evidence that tundra vegetation types significantly influence both the spatial distribution and chemical composition of SOM in the topsoils of central Spitsbergen.

The critical role of light-absorbing aerosol black carbon (BC) in modifying the Earth's atmosphere and climate system warrants detailed characterization of its microphysical properties. The present study examines the BC microphysical properties (size distributions and mixing state) and their impact on the light-absorption characteristics over a semi-urban tropical coastal location in Southern Peninsular India. The measurements of refractory BC (rBC) properties, carried out using the single particle soot photometer during 2018-2021, covering four distinct air mass conditions (Marine, Continental, Mixed-1, and Mixed-2), were used for this purpose. These were supported by measurements of non-refractory submicron particulate matter (NR-PM1) mass loadings and the core-shell Mie theory model for BC-containing particles. The results suggested that the BC particles exhibited varying sizes (mass median diameters from 0.181 +/- 0.079 mu m to 0.202 +/- 0.064 mu m) and relative coating thicknesses (RCT) (1.3-1.6) under distinct air mass conditions. These characteristics reflected varying source/sink strengths, aging processes of BC, and potential condensable coating material. The aerosol system during the Marine air mass period has lower BC (similar to 0.67 +/- 0.57 mu g m(-3)) and NR-PM1 (12.06 +/- 10.81 mu g m(-3)) mass concentrations, and the lowest RCT on BC (similar to 1.34 +/- 0.14). However, the other periods with continental influence depicted significant coatings on BC (mean RCT >1.5). The coatings on BC particles exhibited daytime enhancement, driven by photochemically produced condensable material, a contrasting diurnal pattern to that of other BC properties. Interestingly, the RCT on BC increased and/or remained invariant with increasing relative humidity (RH) until RH 85 %), indicating the potential role of secondary organics as coatings. The changes in the BC mixing state resulted in a significant alteration to its light-absorption properties. The mean light-absorption enhancement of BC (compared to uncoated BC) ranged from 1.36 +/- 0.14 for the Marine air mass periods to 1.58 +/- 0.15 for the Continental air mass periods, whereas the overall mass absorption cross-sections of BC varied between 7.91 +/- 0.91 to 9.03 +/- 0.84 m(2)/g at 550 nm. The key implication of this study is that changes to the BC mixing state, caused by multiple underlying processes unique to tropical atmospheric conditions, can lead to a significant enhancement in its light-absorption characteristics, which can lead to a notable increase in the positive radiative forcing of BC.

Understanding long-term interactions between climate, permafrost, and vegetation provides an essential context for interpreting current Arctic greening. Using 65 fossil pollen records from northern Siberia and a Random Forest model trained on a dataset of 835 modern pollen-climate assemblages, we quantitatively reconstructed mean temperature of the warmest month (Mtwa: mean July temperature) anomalies over the past 40 thousand years (ka) and assessed associated vegetation changes. During the Last Glacial Period, herbaceous taxa overwhelmingly dominated, and warming of similar to 1 degrees C during similar to 40-35 cal ka BP was insufficient to deepen the active layer beyond the threshold required for tree establishment, leaving woody cover minimal. In the early Holocene, sustained warming of nearly 2 degrees C triggered permafrost degradation and active-layer thickening, enabling forest expansion, although tree taxa lagged shrubs by several millennia. These results reveal a clear threshold effect in vegetation-permafrost interactions and show that only sustained warming can overcome permafrost constraints. By providing quantitative temperature estimates, our reconstruction offers critical benchmarks for predicting how ongoing Arctic warming may transform vegetation patterns and permafrost stability.

Accurate soil thermal conductivity (STC) data and their spatiotemporal variability are critical for the accurate simulation of future changes in Arctic permafrost. However, in-situ measured STC data remain scarce in the Arctic permafrost region, and the STC parameterization schemes commonly used in current land surface process models (LSMs) fail to meet the actual needs of accurate simulation of hydrothermal processes in permafrost, leading to considerable errors in the simulation results of Arctic permafrost. This study used the XGBoost method to simulate the spatial-temporal variability of the STC in the upper 5 cm active layer of Arctic permafrost during thawing and freezing periods from 1980 to 2020. The findings indicated STC variations between the thawing and freezing periods across different years, with values ranging from-0.4 to 0.28 W & sdot;m-1 & sdot;K-1. The mean STC during the freezing period was higher than that during the thawing period. Tundra, forest, and barren land exhibited the greatest sensitivity of STC to freeze-thaw transitions. This is the first study to explore the long-term spatiotemporal variations of STC in Arctic permafrost, and these findings and datasets can provide useful support for future research on Arctic permafrost evolution simulations.

Both freeze-thaw cycles and vegetation cover changes significantly influence slope runoff and sediment yield in permafrost regions. Nevertheless, their synergistic mechanisms remain inadequately quantified and poorly understood. Through simulated rainfall experiments conducted on slopes in the source region of the Yangtze River, this study investigated the impacts of vegetation cover variation combined with soil freeze-thaw processes on runoff and sediment yield from typical alpine meadows and alpine steppes. The results indicate that: (1) The three factors of vegetation type and coverage, as well as rainfall intensity, jointly shape the relationship between precipitation runoff and sediment. Alpine meadows showed stronger erosion resistance than alpine steppes. (2) The freeze-thaw process of soil dominated the runoff and sediment generation: Runoff volume across varying vegetation coverage followed the order: autumn freezing period > spring thawing period > summer thawed period. However, sediment yield was highest during the spring thawing period, followed by the autumn freezing period and summer thawed period. (3) For higher vegetation coverage, freeze-thaw effects had a greater impact on runoff than on sediment yield; on the contrary, under low-coverage vegetation, the freeze-thaw process influenced sediment yield more than runoff; These findings provide theoretical guidance for achieving integrated soil erosion regulation goals in alpine grassland ecosystems within the Qinghai-Tibet Plateau under climate change.

The thermal coupling between the atmosphere and the subsurface on the Qinghai-Tibetan Plateau (QTP) governs permafrost stability, surface energy balance, and ecosystem processes, yet its spatiotemporal dynamics under accelerated warming are poorly understood. This study quantifies soil-atmosphere thermal coupling ((3) at the critical 0.1 m root-zone depth using in-situ data from 99 sites (1980-2020) and a machine learning framework. Results show significantly weaker coupling in permafrost (PF) zones (mean (3 = 0.42) than in seasonal frost (SF) zones (mean (3 = 0.50), confirming the powerful thermal buffering of permafrost. Critically, we find a widespread trend of weakening coupling (decreasing (3) at 66.7 % of sites, a phenomenon most pronounced in SF zones. Our driver analysis reveals that the spatial patterns of (3 are primarily controlled by surface insulation from summer rainfall and soil moisture. The temporal trends, however, are driven by a complex and counter-intuitive interplay. Paradoxically, rapid atmospheric warming is the strongest driver of a strengthening of coupling, likely due to the loss of insulative snow cover, while trends toward wetter conditions drive a weakening of coupling by enhancing surface insulation. Spatially explicit maps derived from our models pinpoint hotspots of accelerated decoupling in the eastern and southern QTP, while also identifying high-elevation PF regions where coupling is strengthening, signaling a loss of protective insulation and increased vulnerability to degradation. These findings highlight a dynamic and non-uniform response of land-atmosphere interactions to climate change, with profound implications for the QTP's cryosphere, hydrology, and ecosystems.

Amid global climate change, freeze-thaw cycles in cold regions have intensified, reducing the stability of infrastructures and significantly increasing the demand for grouting reinforcement. However, the deterioration in the durability of existing grouting materials under the combined effects of freeze-thaw cycles and low temperatures has become a major technical bottleneck restricting their application in cold regions. This paper focuses on polyurethane (PU) grouting materials with foaming and lifting characteristics, systematically reviewing the research progress and technical challenges associated with their engineering applications in cold regions. First, in terms of material composition and preparation, the core components and modified additives are detailed to establish a theoretical foundation for performance regulation. Second, addressing the application requirements in cold regions, standardized testing methods and comprehensive evaluation systems are summarized based on key indicators such as heat release temperature, impermeability, diffusion properties, mechanical strength, and expansion properties. Combined with microstructural characteristics, the deformation behavior and failure mechanisms of PU grouting materials under freeze-thaw cycles and salt-freezing environments are revealed. At the engineering application level, the challenges faced by PU grouting materials in cold regions-such as inhibited low-temperature reactivity and insufficient long-term durability-are highlighted. Finally, considering current research gaps, including the unclear mechanisms of microscopic dynamic evolution and the lack of studies on the combined effects of complex environments, future research directions are proposed. This paper aims to provide theoretical support for the development and application of PU grouting materials in cold-region geotechnical engineering.

Ecosystem carbon use efficiency (CUE) is a key indicator of an ecosystem's capacity to function as a carbon sink. While previous studies have predominantly focused on how climate and resource availability affect CUE through physiological processes during the growing season, the role of canopy structure in regulating carbon and energy exchange, especially its interactions with winter climate processes and nitrogen use efficiency (NUE) in shaping ecosystem CUE in semi-arid grasslands, remains insufficiently understood. Here, we conducted a 5-year snow manipulation experiment in a temperate grassland to investigate the effects of deepened snow on ecosystem CUE. We measured ecosystem carbon fluxes, soil nitrogen concentration, species biomass, plants' nitrogen concentration, canopy height and cover and species composition. We found that deepened snow increased soil nitrogen availability, while the concurrent rise in soil moisture facilitated nutrient acquisition and utilization. Together, these changes supported greater biomass accumulation per unit of nitrogen uptake, thereby enhancing NUE. In addition, deepened snow favoured the dominance of C3 grasses, which generally exhibit higher NUE and greater height than C3 forbs, providing a second pathway that further elevated community-level NUE. The enhanced NUE, through both physiological efficiency and compositional shifts, promoted biomass production and facilitated the development of larger canopy volumes. Larger canopy volumes under deepened snow increased gross primary production through improved light interception, while the associated increase in autotrophic maintenance respiration was moderated by higher NUE. Besides, denser canopies reduced understorey temperatures throughout the day, particularly at night, thereby suppressing heterotrophic respiration. Ultimately, deepened snow increased ecosystem CUE by enhancing carbon uptake while limiting respiratory carbon losses. Synthesis. These findings demonstrated the crucial role of biophysical processes associated with canopy structure and NUE in regulating ecosystem CUE, which has been largely overlooked in previous studies. We also highlight the importance of winter processes in shaping carbon sequestration dynamics and their potential to modulate future grassland responses to climate change.