New soils formed after glacier retreat can provide insights into the rates of soil formation in the context of accelerated warming due to climate change. Recently deglacierized terrains (since the Little Ice Age) are subject to weathering and pedogenesis, and freshly exposed sediments are prone to react readily with the environment. This study aims to determine the impact of parent material and time on soil physical and chemical properties of nine proglacial landscapes distributed in the Tropical Andes and Alps. A total of 188 soil samples were collected along chronosequences of deglacierization and from sites that differed in terms of parent material and classified following three parent material groups: (1) Granodiorite-Tonalite (GT), (2) Gneiss-Shales-Schists (GSS), and (3) Mont-Blanc Granite (MBG). We determined physical and chemical soil properties such as contents of clay, silt, sand, organic carbon, bulk density (BD), pH, extractable cation (exCa, exMg, exK), elemental composition by Xray fluorescence (Al, Si, P, S, K, Ca, Mn, Fe, Cu, Zn, As, Mo, Hg, Pb) and ICP-MS (Al, Ca, Cu, Fe, K, Mg, Mn, Mo, Na, P, S, Zn), and mineral phase (XRD diffraction analysis). Parent material-controlled particle-size distribution, SOC, pH, available P, exCa, and exMg, whereas time since deglacierization only affected SOC and P, and exMg globally. Most of the significant differences in soil properties between parent material groups occurred within the first 17 years after deglacierization, and then we observed a homogenization between sites. While the higher SOC and P contents observed within the GT Andean sites might be due to the parent material composition leading to faster initial soil formation, we identified potential As, Cu, Mo, and Mn toxicity within those soils. Our study highlights the need to investigate further proglacial soil's buffering capacity and carbon sequestration to globally inform the conservation and management of novel proglacial ecosystems.

Black Carbon (BC), as a driver of environmental change, could significantly impact the snow by accelerating melting and decreasing albedo. Systematic documentation of BC studies is crucial for a better understanding of its spatial and temporal trends. This study reviewed the BC studies in the ice core and remote lake sediments and their sources in the northern hemisphere. The literature surveyed points to around 2.9 to 3.7 times increase of BC in the European Alps and up to a three-fold increase of BC in the Himalayan-Tibetan Plateau (HTP) after the onset of industrialization in Europe and Asia, respectively. BC concentration from Greenland ice core showed seven times increase with an interrupted trend after 1950's. South Asian emissions were dominant in the HTP along with a contribution from the Middle East, whereas Western European and local emissions were responsible for the change in BC concentration in the European Alps. In the Arctic, contributions from North America, Europe and Asia persisted. Similarly, a historical reconstruction of lake sediments records demonstrates the effects of emissions from long-range transport, sediment focusing, local anthropogenic activities, precipitation and total input of flux on the BC concentration.

BackgroundGlobal warming is affecting all cold environments, including the European Alps and Arctic regions. Here, permafrost may be considered a unique ecosystem harboring a distinct microbiome. The frequent freeze-thaw cycles occurring in permafrost-affected soils, and mainly in the seasonally active top layers, modify microbial communities and consequently ecosystem processes. Although taxonomic responses of the microbiomes in permafrost-affected soils have been widely documented, studies about how the microbial genetic potential, especially pathways involved in C and N cycling, changes between active-layer soils and permafrost soils are rare. Here, we used shotgun metagenomics to analyze the microbial and functional diversity and the metabolic potential of permafrost-affected soil collected from an alpine site (Val Lavirun, Engadin area, Switzerland) and a High Arctic site (Station Nord, Villum Research Station, Greenland). The main goal was to discover the key genes abundant in the active-layer and permafrost soils, with the purpose to highlight the potential role of the functional genes found.ResultsWe observed differences between the alpine and High Arctic sites in alpha- and beta-diversity, and in EggNOG, CAZy, and NCyc datasets. In the High Arctic site, the metagenome in permafrost soil had an overrepresentation (relative to that in active-layer soil) of genes involved in lipid transport by fatty acid desaturate and ABC transporters, i.e. genes that are useful in preventing microorganisms from freezing by increasing membrane fluidity, and genes involved in cell defense mechanisms. The majority of CAZy and NCyc genes were overrepresented in permafrost soils relative to active-layer soils in both localities, with genes involved in the degradation of carbon substrates and in the degradation of N compounds indicating high microbial activity in permafrost in response to climate warming.ConclusionsOur study on the functional characteristics of permafrost microbiomes underlines the remarkably high functional gene diversity of the High Arctic and temperate mountain permafrost, including a broad range of C- and N-cycling genes, and multiple survival and energetic metabolisms. Their metabolic versatility in using organic materials from ancient soils undergoing microbial degradation determine organic matter decomposition and greenhouse gas emissions upon permafrost thawing. Attention to their functional genes is therefore essential to predict potential soil-climate feedbacks to the future warmer climate.

Key message Juveniles and canopy trees may not exhibit similar nitrogen acquisition responses to soil temperature change caused by variation in snow cover over winter. The use of(15)N tracer is a powerful tool for tracking the effects of variation in soil frost on plant nitrogen acquisition. While the responses of juvenile trees to environmental change are often used to infer the responses of canopy trees, the(15)N enrichment responses of juveniles and mature canopy trees may not be comparable. We conducted a winter soil temperature manipulation study (snow exclusion, ambient snow or soil insulation) in a lowlandFagus sylvaticaforest.N-15 tracer was applied the following spring and the(15)N enrichments of soil, juvenile and mature canopy trees were examined in late fall. Within canopy trees and juveniles, the relative treatment effects on(15)N enrichment were consistent among all sampled tissues (roots, stem cores, leaves, buds and the current year's shoot growth). For juveniles,N-15 enrichment was highest under snow exclusion (coldest soil) and lowest under soil insulation (warmest soil), and lower(15)N enrichment occurred under ambient conditions than under snow exclusion. For canopy trees,N-15 enrichment also was highest under snow exclusion and lowest under soil insulation, but there was no difference in(15)N enrichment between ambient conditions and the snow exclusion treatment. Therefore, our results indicate that sampling of juveniles may overestimate the nitrogen acquisition responses of mature trees to winter temperature variation.

This paper reviews and analyses the past 20 years of change and variability of European mountain permafrost in response to climate change based on time series of ground temperatures along a south-north transect of deep boreholes from Sierra Nevada in Spain (37 degrees N) to Svalbard (78 degrees N), established between 1998 and 2000 during the EU-funded PACE (Permafrost and Climate in Europe) project. In Sierra Nevada (at the Veleta Peak), no permafrost is encountered. All other boreholes are drilled in permafrost. Results show that permafrost warmed at all sites down to depths of 50 m or more. The warming at a 20 m depth varied between 1.5 degrees C on Svalbard and 0.4 degrees C in the Alps. Warming rates tend to be less pronounced in the warm permafrost boreholes, which is partly due to latent heat effects at more ice-rich sites with ground temperatures close to 0 degrees C. At most sites, the air temperature at 2 m height showed a smaller increase than the near-ground-surface temperature, leading to an increase of surface offsets (SOs). The active layer thickness (ALT) increased at all sites between c. 10% and 200% with respect to the start of the study period, with the largest changes observed in the European Alps. Multi-temporal electrical resistivity tomography (ERT) carried out at six sites showed a decrease in electrical resistivity, independently supporting our conclusion of ground ice degradation and higher unfrozen water content.

The response of microbial communities to the predicted rising temperatures in alpine regions might be an important part of the ability of these ecosystems to deal with climate change. Soil microbial communities might be significantly affected by elevated temperatures, which influence the functioning of soils within high-alpine ecosystems. To evaluate the potential of the permafrost microbiome to adapt to short-term moderate and extreme warming, we set up an incubation experiment with permafrost and active soil layers from northern and southern slopes of a high-alpine mountain ridge on Muot da Barba Peider in the Swiss Alps. Soils were acclimated to increasing temperatures (4-40 degrees C) for 26 days before being exposed to a heat shock treatment of 40 degrees C for 4 days. Alpha-diversity in all soils increased slightly under gradual warming, from 4 to 25 degrees C, but then dropped considerably at 40 degrees C. Similarly, heat shock induced strong changes in microbial community structures and functioning in the active layer of soils from both northern and southern slope aspects. In contrast, permafrost soils showed only minor changes in their microbial community structures and no changes in their functioning, except regarding specific respiration activity. Shifts in microbial community structures with increasing temperature were significantly more pronounced for bacteria than for fungi, regardless of the soil origin, suggesting higher resistance of high-alpine fungi to short-term warming. Firmicutes, mainly represented by Tumebacillus and Alicyclobacillaceae OTUs, increased strongly at 40 degrees C in active layer soils, reaching almost 50% of the total abundance. In contrast, Saccharibacteria decreased significantly with increasing temperature across all soil samples. Overall, our study highlights the divergent responses of fungal and bacterial communities to increased temperature. Fungi were highly resistant to increased temperatures compared to bacteria, and permafrost communities showed surprisingly low response to rising temperature. The unique responses were related to both site aspect and soil origin indicating that distinct differences within high-alpine soils may be driven by substrate limitation and legacy effects of soil temperatures at the field site.

A comprehensive overview is provided evaluating direct real-world CO2 emissions of both diesel and petrol cars newly registered in Europe between 1995 and 2015. Before 2011, European diesel cars emitted less CO2 per kilometre than petrol cars, but since then there is no appreciable difference in per-km CO2 emissions between diesel and petrol cars. Real-world CO2 emissions of diesel cars have not declined appreciably since 2001, while the CO2 emissions of petrol cars have been stagnant since 2012. When adding black carbon related CO2 equivalents, such as from diesel cars without particulate filters, diesel cars were discovered to have had much higher climate relevant emissions until the year 2001 when compared to petrol cars. From 2001 to 2015 CO2 equivalent emissions from new diesel cars and petrol cars were hardly distinguishable. Lifetime use phase CO2 equivalent emissions of all European passenger vehicles were modelled for 1995-2015 based on three scenarios: the historic case, another scenario freezing percentages of diesel cars at the low levels from the early 1990s (thus avoiding the observed boom in new diesel registrations), and an advanced mitigation scenario based on high proportions of petrol hybrid cars and cars burning gaseous fuels. The difference in CO2-equivalent emissions between the historical case and the scenario avoiding the diesel car boom is only 0.4%. The advanced mitigation scenario would have been able to achieve a 3.4% reduction in total CO2-equivalent emissions over the same time frame. The European diesel car boom appears to have been ineffective at reducing climate-warming emissions from the European transport sector.

The focus of present paper is upon aerosol variability in Bucharest metropolitan area and its relationships with aerosol direct effect/forcing (DRE/DRF). The aerosol (particulate matter less than 10 mu m, PM10) mass concentrations were collected at three sampling sites (within a grid-scale of a regional climate model) covering three types of pollution (urban, suburban, and rural) in Bucharest area during 1st of June 2014 to 31st of May 2015. The aerosol optical properties were computed using the Optical Properties of Aerosol and Clouds (OPAC) software package, based on Mie scattering theory. We observed relatively high levels of PM10 with moderate to low seasonal cycle. DRF values indicate a cooling aerosol effect and show annual variations due to the combined effects of variability of aerosol optical properties over Bucharest region and of local geophysical variables. A dedicated to comparison of aerosol DRF and its efficiency in Bucharest area and worldwide is included.

Heterogeneous Holocene climate evolutions in the Northern Hemisphere high latitudes are primarily determined by orbital-scale insolation variations and melting ice sheets. Previous inter-model comparisons have revealed that multi-simulation consistencies vary spatially. We, therefore, compared multiple model results with proxy-based reconstructions in Fennoscandia, Greenland, north Canada, Alaska and Siberia. Our model-data comparisons reveal that data and models generally agree in Fennoscandia, Greenland and Canada, with the early-Holocene warming and subsequent gradual decrease to 0 ka BP (hereinafter referred as ka). In Fennoscandia, simulations and pollen data suggest a 2 degrees C warming by 8 ka, but this is less expressed in chironomid data. In Canada, a strong early-Holocene warming is suggested by both the simulations and pollen results. In Greenland, the magnitude of early-Holocene warming ranges from 6 degrees C in simulations to 8 degrees C in delta O-18-based temperatures. Simulated and reconstructed temperatures are mismatched in Alaska. Pollen data suggest strong early Holocene warming, while the simulations indicate constant Holocene cooling, and chironomid data show a stable trend. Meanwhile, a high frequency of Alaskan peatland initiation before 9 ka can reflect a either high temperature, high soil moisture or large seasonality. In high-latitude Siberia, although simulations and proxy data depict high Holocene temperatures, these signals are noisy owing to a large spread in the simulations and between pollen and chironomid results. On the whole, the Holocene climate evolutions in most regions (Fennoscandia, Greenland and Canada) are well established and understood, but important questions regarding the Holocene temperature trend and mechanisms remain for Alaska and Siberia. (C) 2017 Elsevier Ltd. All rights reserved.

A reliable assessment of the optical properties of atmospheric black carbon is of crucial importance for an accurate estimation of radiative forcing. In this study we investigated the spatio-temporal variability of the mass absorption cross- (MAC) of atmospheric black carbon, defined as light absorption coefficient (sigma(ap)) divided by elemental carbon mass concentration (m(EC)). sigma(ap) and m(EC) have been monitored at supersites of the ACTRIS network for a minimum period of one year. The 9 rural background sites considered in this study cover southern Scandinavia, central Europe and the Mediterranean. sigma(ap) was determined using filter based absorption photometers and m(EC) using a thermal-optical technique. Homogeneity of the data-set was ensured by harmonization of all involved methods and instruments during extensive intercomparison exercises at the European Center for Aerosol Calibration (ECAC). Annual mean values of sigma(ap) at a wavelength of 637 nm vary between 0.66 and 1.3 Mm(-1) in southern Scandinavia, 3.7-11 Mm(-1) in Central Europe and the British Isles, and 2.3-2.8 Mm(-1) in the Mediterranean. Annual mean values of mEC vary between 0.084 and 0.23 mu g m(-3) in southern Scandinavia, 0.28 -1.1 in Central Europe and the British Isles, and 0.22-0.26 in the Mediterranean. Both sigma(ap) and mEC in southern Scandinavia and Central Europe have a distinct seasonality with maxima during the cold season and minima during summer, whereas at the Mediterranean sites an opposite trend was observed. Annual mean MAC values were quite similar across all sites and the seasonal variability was small at most sites. Consequently, a MAC value of 10.0 m(2) g(-1) (geometric standard deviation = 133) at a wavelength of 637 nm can be considered to be representative of the mixed boundary layer at European background sites, where BC is expected to be internally mixed to a large extent. The observed spatial variability is rather small compared to the variability of values in previous literature, indicating that the harmonization efforts resulted in substantially increased precision of the reported MAC. However, absolute uncertainties of the reported MAC values remain as high as +/- 30-70% due to the lack of appropriate reference methods and calibration materials. The mass ratio between elemental carbon and non-light-absorbing matter was used as a proxy for the thickness of coatings around the BC cores, in order to assess the influence of the mixing state on the MAC of BC. Indeed, the MAC was found to increase with increasing values of the coating thickness proxy. This provides evidence that coatings do increase the MAC of atmospheric BC to some extent, which is commonly referred to as lensing effect. (C) 2016 The Authors. Published by Elsevier Ltd.