While the sentinel nature of freshwater systems is now well recognized, widespread integration of freshwater processes and patterns into our understanding of broader climate-driven Arctic terrestrial ecosystem change has been slow. We review the current understanding across Arctic freshwater systems of key sentinel responses to climate, which are attributes of these systems with demonstrated and sensitive responses to climate forcing. These include ice regimes, temperature and thermal structure, river baseflow, lake area and water level, permafrost-derived dissolved ions and nutrients, carbon mobilization (dissolved organic carbon, greenhouse gases, and radiocarbon), dissolved oxygen concentrations, lake trophic state, various aquatic organisms and their traits, and invasive species. For each sentinel, our objectives are to clarify linkages to climate, describe key insights already gained, and provide suggestions for future research based on current knowledge gaps. We suggest that tracking key responses in Arctic freshwater systems will expand understanding of the breadth and depth of climate-driven Arctic ecosystem changes, provide early indicators of looming, broader changes across the landscape, and improve protection of freshwater biodiversity and resources.

The cryosphere in the Himalaya-Karakoram (H-K) is widespread, and its services significantly affect the SDGs implementation in the region, in particular related to the 'No poverty' (SDG 1), 'zero hunger' (SDG 2), 'good health and well-being' (SDG 3), 'work and economic' (SDG 8) and 'partnership for the goals' (SDG 17). We here established the networks to illustrate the complex relationship of cryosphere services with national SDG priorities in the countries of H-K, including Afghanistan, Pakistan, India, China, Nepal and Bhutan. The cryosphere services contributing to the national SDG priorities and the key targets were elucidated in line with the centralities of the network. It was found that 'freshwater', 'clean energy', 'runoff regulation', 'climate regulation', 'research and education' and 'infrastructure and engineering' are the services that play critical roles in H-K, and they were then applied to assess the impact of cryosphere services on the national SDG priorities. We subsequently identified a set of principal indicators in relation to the key targets of national SDG priorities, which has the explanation up to 85% of six entry points (SEPs) to advance SDGs of each country in H-K. In conjunction with the centrality of the key targets to be contributed by the overall cryosphere services in the network for each country, the dependency of SEPs on the cryosphere services can be established through principal indicators in association with the national SDG priorities in H-K countries.

Managing water is a top social and economic responsibility and is expected to become even more critical as climate change, in addition to other human activities, alters water availability and quality. Robust indicators reflecting the effects of climate change on the US and global water cycles are needed in order to appropriately manage water resources. Here, we describe a suite of seventeen water cycle and management indicators, which are based on synthesis of available datasets. These indicators include average and heavy precipitation, standardized precipitation index, annual, 7-day low and 3-day high streamflow volume, streamflow timing, snow cover, snow water equivalent, groundwater level, lake water temperature, stream water temperature, dissolved oxygen, salinity, Palmer Drought Severity Index, water withdrawals, and water use. We also identify three indicators that could be included in the suite of water cycle and management indicators with some additional, directed work: snowfall, evapotranspiration, and soil moisture. Our conceptual framework focuses on known water cycle changes in addition to potential effects on management and addresses water quantity and quality, as well as water use and related interactions with freshwater ecosystems, societal impacts, and management. Water cycle indicators are organized into three categories: (1) hydrologic processes, (2) water quality processes, and (3) water quality and quantity impacts. Indicators described here are recommended to serve as critical references for periodic climate assessments. As such, these indicators support analyses of the effects of global change on the natural environment, agriculture, energy, and water resources, among other sectors. Additionally, we identify research gaps and needs that can be addressed to advance the development of future indicators.

The accumulation of polycyclic aromatic hydrocarbons (PAHs) in the profiles of permafrost-affected peat mounds is related to certain groups of plant residues produced in the Atlantic climatic optimum of the Holocene. Both heavy (benzo[ghi]perylene, dibenz[a,h]anthracene, and benzo[b]fluoranthene) and light (pyrene and naphthalene) PAHs predominate in them. The polyarenes preserved in the permafrost horizons are not subjected to transformation in contrast to the polyarenes in the active layer. Dynamic freeze-thaw processes at the boundary between seasonally thawed and permanently frozen layers result in considerable transformation of plant remains, humic substances, and nonspecific organic compounds with the accumulation of 5-6-nuclear PAH structures. The composition of PAHs in peatlands and a significant increase in the weight fraction of PAHs at the boundary between seasonally thawed and permafrost layers may serve as indicators of permafrost response to climate changes in high latitudes.