Large-scale wildfires are essential sources of black carbon (BC) and brown carbon (BrC), affecting aerosol-induced radiative forcing. This study investigated the impact of two wildfire plumes (Plume 1 and 2) transported to Moscow on the optical properties of BC and BrC during August 2022. During the wildfires, the total light absorption at 370 nm (b(abs_370nm)) increased 2.3-3.4 times relative to background (17.30 +/- 13.98 Mm(-)(1)), and the BrC contribution to total absorption increased from 14 % to 42-48 %. BrC was further partitioned into primary (BrCPri) and secondary (BrCSec) components. Biomass burning accounted for similar to 83-90 % of BrCPri during the wildfires. The b(abs_370nm) of BrCPri increased 5.6 times in Plume 1 and 11.5 times in Plume 2, due to the higher prevalence of peat combustion in Plume 2. b(abs_370nm) of BrCSec increased 8.3-9.6 times, driven by aqueous-phase processing, as evidenced by strong correlations between aerosol liquid water content and b(abs_370nm) of BrCSec. Daytime b(abs_370nm) of BrCSec increased 7.6 times in Plume 1 but only 3.6 times in Plume 2, due to more extensive photobleaching, as indicated by negative correlations with oxidant concentrations and longer transport times. The radiative forcing of BrCPri relative to BC increased 1.8 times in Plume 1 and Plume 2. In contrast, this increase for BrCSec was 3.4 times in Plume 1 but only 2.3 times in Plume 2, due to differences in chemical processes, which may result in higher uncertainty in its radiative forcing. Future work should prioritize elucidating both the emissions and atmospheric processes to better quantify wildfire-derived BrC and its radiative forcing.

Both freeze-thaw cycles and vegetation cover changes significantly influence slope runoff and sediment yield in permafrost regions. Nevertheless, their synergistic mechanisms remain inadequately quantified and poorly understood. Through simulated rainfall experiments conducted on slopes in the source region of the Yangtze River, this study investigated the impacts of vegetation cover variation combined with soil freeze-thaw processes on runoff and sediment yield from typical alpine meadows and alpine steppes. The results indicate that: (1) The three factors of vegetation type and coverage, as well as rainfall intensity, jointly shape the relationship between precipitation runoff and sediment. Alpine meadows showed stronger erosion resistance than alpine steppes. (2) The freeze-thaw process of soil dominated the runoff and sediment generation: Runoff volume across varying vegetation coverage followed the order: autumn freezing period > spring thawing period > summer thawed period. However, sediment yield was highest during the spring thawing period, followed by the autumn freezing period and summer thawed period. (3) For higher vegetation coverage, freeze-thaw effects had a greater impact on runoff than on sediment yield; on the contrary, under low-coverage vegetation, the freeze-thaw process influenced sediment yield more than runoff; These findings provide theoretical guidance for achieving integrated soil erosion regulation goals in alpine grassland ecosystems within the Qinghai-Tibet Plateau under climate change.

This study assesses the stability of the Bei'an-Hei'he Highway (BHH), located near the southern limit of latitudinal permafrost in the Xiao Xing'anling Mountains, Northeast China, where permafrost degradation is intensifying under combined climatic and anthropogenic influences. Freeze-thaw-induced ground deformation and related periglacial hazards remain poorly quantified, limiting regional infrastructure resilience. We developed an integrated framework that fuses multi-source InSAR (ALOS, Sentinel-1, ALOS-2), unmanned aerial vehicle (UAV) photogrammetry, electrical resistivity tomography (ERT), and theoretical modeling to characterize cumulative deformation, evaluate present stability, and project future dynamics. Results reveal long-term deformation rates from -35 to +40 mm/yr within a 1-km buffer on each side of the BHH, with seasonal amplitudes up to 11 mm. Sentinel-1, with its 12-day revisit cycle, demonstrated superior capability for monitoring the Xing'an permafrost. Deformation patterns were primarily controlled by air temperature, while precipitation and the topographic wetness index enhanced spatial heterogeneity through thermo-hydrological coupling. Wavelet analysis identified a 334-day deformation cycle, lagging climate forcing by similar to 107 days due to the insulating effects of peat. Early-warning analysis classified 4.99 % of the highway length as high-risk (subsidence 10.91 mm/yr). The InSAR-based landslide prediction model achieved high accuracy (Area Under the Receiver Operating Characteristic (ROC) Curve, or AUC = 0.9486), validated through field surveys of subsidence, cracking, and slow-moving failures. The proposed 'past-present-future' framework demonstrates the potential of multi-sensor integration for permafrost monitoring and provides a transferable approach for assessing infrastructure stability in cold regions.

Ecosystem carbon use efficiency (CUE) is a key indicator of an ecosystem's capacity to function as a carbon sink. While previous studies have predominantly focused on how climate and resource availability affect CUE through physiological processes during the growing season, the role of canopy structure in regulating carbon and energy exchange, especially its interactions with winter climate processes and nitrogen use efficiency (NUE) in shaping ecosystem CUE in semi-arid grasslands, remains insufficiently understood. Here, we conducted a 5-year snow manipulation experiment in a temperate grassland to investigate the effects of deepened snow on ecosystem CUE. We measured ecosystem carbon fluxes, soil nitrogen concentration, species biomass, plants' nitrogen concentration, canopy height and cover and species composition. We found that deepened snow increased soil nitrogen availability, while the concurrent rise in soil moisture facilitated nutrient acquisition and utilization. Together, these changes supported greater biomass accumulation per unit of nitrogen uptake, thereby enhancing NUE. In addition, deepened snow favoured the dominance of C3 grasses, which generally exhibit higher NUE and greater height than C3 forbs, providing a second pathway that further elevated community-level NUE. The enhanced NUE, through both physiological efficiency and compositional shifts, promoted biomass production and facilitated the development of larger canopy volumes. Larger canopy volumes under deepened snow increased gross primary production through improved light interception, while the associated increase in autotrophic maintenance respiration was moderated by higher NUE. Besides, denser canopies reduced understorey temperatures throughout the day, particularly at night, thereby suppressing heterotrophic respiration. Ultimately, deepened snow increased ecosystem CUE by enhancing carbon uptake while limiting respiratory carbon losses. Synthesis. These findings demonstrated the crucial role of biophysical processes associated with canopy structure and NUE in regulating ecosystem CUE, which has been largely overlooked in previous studies. We also highlight the importance of winter processes in shaping carbon sequestration dynamics and their potential to modulate future grassland responses to climate change.

Frozen soils, including seasonally frozen ground and permafrost, are rapidly changing under a warming climate, with cascading effects on water, energy, and carbon cycles. We synthesize recent advances in the physics, observation, and modeling of frozen-soil hydrology, emphasizing freeze-thaw dynamics, infiltration regimes and preferential flow, groundwater-permafrost interactions (including talik development and advective heat), and resulting shifts in streamflow seasonality. Progress in in situ sensing, geophysics, and remote sensing now resolves unfrozen water, freezing fronts, and active-layer dynamics across scales, while land-surface and tracer-aided hydrological models increasingly represent phase change, macropore bypass, and vapor transport. Thaw-induced activation of subsurface pathways alters recharge and baseflow, influences vegetation and biogeochemistry, and modulates greenhouse-gas emissions. Key uncertainties persist in scaling micro-scale processes, parameterizing ice-impeded hydraulics, and representing abrupt thaw and wetland dynamics. We outline a tiered modeling framework, priority observations, and integration of vegetation-hydrology-carbon processes to improve projections of cold-region water resources and climate feedbacks.

The reasonable value of good gradation characteristic parameters is key in designing and optimising soil-rock mixed high fill embankment materials. Firstly, the DJSZ-150 dynamic-static large-scale triaxial testing instrument was used for triaxial compression shear tests on compacted skeleton structure soil-rock mixture standard specimens. The changes in strength and deformation indicators under different gradation parameters and confining pressure were analysed. Then, based on the Janbu empirical formula, relationships between parameters K, n, and (sigma 1-sigma 3)ult and the coefficient of uniformity Cu and coefficient of curvature Cc were explored. Empirical fitting formulas for Duncan-Chang model constants a and b were proposed, establishing an improved Duncan-Chang model for soil-rock mixtures considering gradation characteristics and stress states. Finally, based on significant differences in particle spatial distribution caused by gradation changes, three generalised models of matrix-block stone motion from different particle aggregation forms were proposed. Results indicate the standard specimen's strength and deformation indicators exhibit significant gradation effects and stress-state correlations. The improved Duncan-Chang model effectively simulates the stress-strain relationship curve under different gradations and confining pressure, with its characteristics explainable based on the matrix block stone motion generalised model.

Bedrock-soil layer slopes (BSLSs) are widely distributed in nature. The existence of the interface between bedrock and soil layer (IBSL) affects the failure modes of the BSLSs, and the seismic action makes the failure modes more complex. In order to accurately evaluate the safety and its corresponding main failure modes of BSLSs under seismic action, a system reliability method combined with the upper bound limit analysis method and Monte Carlo simulation (MCS) is proposed. Four types of failure modes and their corresponding factors of safety (Fs) were calculated by MATLAB program coding and validated with case in existing literature. The results show that overburden layer soil's strength, the IBSL's strength and geometric characteristic, and seismic action have significant effects on BSLSs' system reliability, failure modes and failure ranges. In addition, as the cohesion of the inclination angle of the IBSL and the horizontal seismic action increase, the failure range of the BSLS gradually approaches the IBSL, which means that the damage range becomes larger. However, with the increase of overburden layer soil's friction angle, IBSL's depth and strength, and vertical seismic actions, the failure range gradually approaches the surface of the BSLS, which means that the failure range becomes smaller.

An analytical methodology was developed for the first time in this work enabling the simultaneous enantiomeric separation of the fungicide fenpropidin and its acid metabolite by Capillary Electrophoresis. A dual cyclodextrin system consisting of 4 % (w/v) captisol with 10 mM methyl-beta-cyclodextrin was employed in a 100 mM sodium acetate buffer at pH 4.0. Optimal experimental conditions (temperature 25 degrees C, separation voltage -25 kV, and hydrodynamic injection of 50 mbar x 10 s) allowed the simultaneous separation of the four enantiomers in <10.7 min with resolutions of 3.1 (fenpropidin) and 3.2 (its acid metabolite). Analytical characteristics of the method were evaluated and found adequate for the quantification of both chiral compounds with a linearity range from 0.75 to 70 mg L-1, good accuracy (trueness included 100 % recovery, precision with RSD<6 %), and limits of detection and quantification of 0.25 and 0.75 mg L-1, respectively, for the four enantiomers. No significant differences were found between the concentrations determined and labelled of fenpropidin in a commercial agrochemical formulation. The stability over time (0-42 days) of fenpropidin enantiomers using the commercial agrochemical formulation was evaluated in two sugar beet soils, revealing to be stable at any time in one sample, while in the other a decrease of 45 % was observed after 42 days. Individual and combined toxicity of fenpropidin and its metabolite was determined for the first time for marine organism Vibrio fischeri, demonstrating higher damage caused by parent compound. Synergistics and antagonists' interactions were observed at low and high effects levels of contaminants.

With global warming and the intensification of human activities, frozen soils continue to melt, leading to the formation of thermokarst collapses and thermokarst lakes. The thawing of permafrost results in the microbial decomposition of large amounts of frozen organic carbon (C), releasing greenhouse gases such as carbon dioxide (CO2) and methane (CH4). However, little research has been done on the thermo-water-vapor-carbon coupling process in permafrost, and the interactions among hydrothermal transport, organic matter decomposition, and CO2 transport processes in permafrost remain unclear. We considered the decomposition and release of organic C and established a coupled thermo-water-vapor-carbon model for permafrost based on the study area located in the Beiluhe region of the Qingzang Plateau, China. The model established accurately reflected changes in permafrost temperature, moisture, and C fluxes. Dramatic changes in temperature and precipitation in the warm season led to significant soil water and heat transport, CO2 transport, and organic matter decomposition. During the cold season, however, the soil froze, which weakened organic matter decomposition and CO2 transport. The sensitivity of soil layers to changes in the external environment varied with depth. Fluctuations in energy, water, and CO2 fluxes were greater in shallow soil layers than in deeper ones. The latent heat of water-vapor and water-ice phase changes played a crucial role in regulating the temperature of frozen soil. The low content of soil organic matter in the study area resulted in a smaller influence of the decomposition heat of soil organic matter on soil temperature, compared to the high organic matter content in other soil types (such as peatlands).

Permafrost is undergoing widespread degradation affected by climate change and anthropogenic factors, leading to seasonal freezing and thawing exhibiting interannual, and fluctuating differences, thereby impacting the stability of local hydrological processes, ecosystems, and infrastructure. To capture this seasonal deformation, scholars have proposed various InSAR permafrost deformation models. However, due to spatial-temporal filtering smoothing high-frequency deformation and the presence of approximate assumptions in permafrost models, such differences are often difficult to accurately capture. Therefore, this paper applies an InSAR permafrost monitoring method based on moving average models and annual variations to detect freezing and thawing deformation in the Russian Novaya Zemlya region from 2017 to 2021 using Sentinel-1 data. Most of the study area's deformation rates remained between 10 and 10 mm/yr, while in key oil extraction areas, they reached -20 mm/yr. Seasonal deformation amplitudes were relatively stable in urban areas, but reached 90 mm in regions with extensive development of thermokarst lakes, showing a significant increasing trend. To validate the accuracy of the new method in capturing seasonal deformations, we used seasonal deformations obtained from different methods to retrieval the Active Layer Thickness (ALT), and compared them with field ALT measurement data. The results showed that the new method had a smaller RMSE and improved accuracy by 5% and 30% in two different ALT observation areas, respectively, compared to previous methods. Additionally, by combining the spatial characteristics of seasonal deformation amplitudes and ALT, we analyzed the impact of impermeable surfaces, confirming that human-induced surface hardening alters the feedback mechanism of perennial frozen soil to climate.