Permafrost is one of the crucial components of the cryosphere, covering about 25% of the global continental area. The active layer thickness (ALT), as the main site for heat and water exchange between permafrost and the external atmosphere, its changes significantly impact the carbon cycle, hydrological processes, ecosystems, and the safety of engineering structures in cold regions. This study constructs a Stefan CatBoost-ET (SCE) model through machine learning and Blending integration, leveraging multi-source remote sensing data, the Stefan equation, and measured ALT data to focus on the ALT in the Qinghai-Tibet Plateau (QTP). Additionally, the SCE model was verified via ten-fold cross-validation (MAE: 20.713 cm, RMSE: 32.680 cm, R2: 0.873, and MAPE: 0.104), and its inversion of QTP's ALT data from 1958 to 2022 revealed 1998 as a key turning point with a slow growth rate of 0.25 cm/a before 1998 and a significantly increased rate of 1.26 cm/a afterward. Finally, based on multiple model input factor analysis methods (SHAP, Pearson correlation, and Random Forest Importance), the study analyzed the ranking of key factors influencing ALT changes. Meanwhile, the importance of Stefan equation results in SCE model is verified. The research results of this paper have positive implications for eco-hydrology in the QTP region, and also provide valuable references for simulating the ALT of permafrost.

To address the issues of abrasive wear, impact wear, and soil adhesion that can lead to wear failure and excessive operational resistance in agricultural soil touching parts during farming. This study focuses on UHMWPE composites, modified by filling Nano-SiC as a hard phase filler and XNBR as an elastic filler. These fillers were dispersed into the UHMWPE matrix through melt blending technology to create a high-performance composite material for the surface protective material of soil touching parts. The study discovered that by adding hard and elastic fillers to the UHMWPE matrix, the density, hardness, flexural modulus and thermal stability of the materials were all increased. Specifically, the density increased by 5.67% and the flexural modulus increased by 107%. In the block on ring wear test the volumetric wear rate decreased by 98%, while in the mortar wear test the mass wear rate decreased by 64.64%. Additionally, the contact angle on the surface of the specimen after mortar erosion and wear increased to 102.76 degrees, 18% higher than that of pure UHMWPE. These results demonstrate that the modified fillers can improve the abrasion and plastic deformation resistance and hydrophobic desorption of UHMWPE. UHMWPE composite material, serving as the surface protection for soil touching parts, resolves the issues of abrasion of soil abrasive particles and excessive soil adhesion resistance on these parts. This significantly prolongs the service life of soil touching parts of agricultural machinery and improves the operational efficiency and economy.

Melt blending is a reliable and well-demonstrated strategy for improving the mechanical, thermal, rheological, and surface properties of biopolymers. Poly(hydroxy-3-butyrate-co-3-hydroxyvalerate) (PHBV) and poly(butylene adipate-co-terephthalate) (PBAT) are the two popular choices for blending polymers due to their diverse properties and complementary soil biodegradable behaviour. Due to their immiscibility, however, blending with the help of processing additives is necessary to reap the most significant benefits from this process and to avoid immiscibility issues. This study utilized the additives (peroxides and epoxy-based chain extender) to compatibilize the biodegradable polymers PHBV and PBAT in a 60:40 blending ratio. The tensile strength and Young's modulus of the PHBV/PBAT(60/40) blend were improved by 32% and 64%, respectively, after adding a combination of peroxide (0.02 phr) and chain extender (0.3 phr) due to the formation of a complex network structure with increased chain length. The positive effect of an additive addition was also reflected by a 30 degrees C increment in heat deflection temperature of biodegradable blend due to its high modulus value as supported by mechanical properties. The combined action of a peroxide and chain extender demonstrated a significantly higher complex viscosity of the PHBV/PBAT(60/40) blend due to the formation of a crosslinked polymer network as analyzed by rheological analysis. Our research demonstrated the effect of additives and their combined impact on analytical properties of PHBV/PBAT(60/40) blend to guide future work in improving their candidature to serve as a drop-in solution in replacing non-biodegradable petro-based plastic products.

The escalating environmental crisis posed by single-use plastics underscores the urgent need for sustainable alternatives. This study provides an approach to introduce biodegradable polymer blends by blending synthetic polyvinyl alcohol (PVA) with natural polymers-corn starch (CS) and hydroxypropyl methylcellulose (HPMC)-to address this challenge. Through a comprehensive analysis, including of the structure, mechanical strength, water solubility, biodegradability, and thermal properties, we investigated the enhanced performance of PVA-CS and PVA-HPMC blends over conventional polymers. Scanning electron microscopy (SEM) findings of pure PVA and its blends were studied, and we found a complete homogeneity between the PVA and both types of natural polymers in the case of a high concentration of PVA, whereas at lower concentration of PVA, some granules of CS and HMPC appear in the SEM. Blending corn starch (CS) with PVA significantly boosts its biodegradability in soil environments, since adding starch of 50 w/w duplicates the rate of PVA biodegradation. Incorporating hydroxypropyl methylcellulose (HPMC) with PVA not only improves water solubility but also enhances biodegradation rates, as the addition of HPMC increases the biodegradation of pure PVA from 10 to 100% and raises the water solubility from 80 to 100%, highlighting the significant acceleration of the biodegradation process and water solubility caused by HPMC addition, making these blends suitable for a wide range of applications, from packaging and agricultural films to biomedical engineering. The thermal properties of pure PVA and its blends with natural were studied using diffraction scanning calorimetry (DSC). It is found that the glass transition temperature (Tg) increases after adding natural polymers to PVA, referring to an improvement in the molecular weight and intermolecular interactions between blend molecules. Moreover, the amorphous structure of natural polymers makes the melting temperature (TM) lessen after adding natural polymer, so the blends require lower temperature to remelt and be recycled again. For the mechanical properties, both types of natural polymer decrease the tensile strength and elongation at break, which overall weakens the mechanical properties of PVA. Our findings offer a promising pathway for the development of environmentally friendly polymers that do not compromise on performance, marking a significant step forward in polymer science's contribution to sustainability. This work presents detailed experimental and theoretical insights into novel polymerization methods and the utilization of biological strategies for advanced material design.

There is a huge stock of industrial solid waste piles such as phosphogypsum (PG), desulfurization ash (DA), and waste soil (WS) in China, and their utilization rate is insufficient. These have potential risk for environmental safety due to pollutants contained in them. In this study, after proportioning design, raw material pretreatment, bubble regulation and multi -temperature maintenance process, successfully prepared a high blending solid waste based functional prefabricated autoclaved aerated concrete slabs (FPAS) with excellent functional performance, and the optimal ratio of each raw material is PG: WS: DA: cement: lime = 8:50:20:10:12, and the dry mass ratio is up to 75%, the compressive strength of the slabs is up to 5.2 MPa, the standard dry density is 606 kg/m 3 , the dry shrinkage value is 0.36 mm/m, and the post -freezing strength is 4.0 MPa, which is in line with the basic requirements in the standard Autoclaved aerated concrete slabs (GB/T15762) , and at the same time, its fire-resistant integrity is qualified for 240 min, and the coefficient of thermal conductivity is 0.15w(m. k), airborne sound -weighted sound insulation is 46 dB, also can show different functional characteristics. In order to investigate the environmental safety of heavy metals (HMs) in the slabs, the simulation experiment of HMs leaching from outdoor stacking of slabs was carried out. The results show that the HMs in the slabs do not pose obvious risks to the natural environment and human body, but three of the characteristic HMs, Cr, Cd and Hg, have significant leaching patterns, which can be expressed by a second -order kinetic model. Finally, the life cycle assessment and cost analysis of the high blending PG -DA -WS based FPAS and the conventional aerated slabs were carried out. The main environmental damage category of the high blending PG -DA -WS based FPAS is land ecological risk, and it has obvious environmental and economic benefits compared with the conventional aerated slabs.

Synthetic polymers have established the market due to their low cost and simplicity of production, despite the fact that society now requires a more environment friendly alternative to non-biodegradable polymers. To overcome this problem, natural polymers produced from renewable resources, including starch, cellulose, chitin, pectin, and chitosan, are presently being as an alternative to plastics due to their biodegradability, benign properties, widespread availability, and biocompatibility. According to the current environmental conditions, the creation of bio-based products is crucial. The potential of blending natural biopolymers is effective in addressing the problem of shortening the lifespan of degradation of these polymers, as well as demonstrating the efficiency of biodegradation of polymer blends between synthetic polymers and biopolymers. This article discusses the compatibilizer-based blending of natural and synthetic thermoplastic polymers. The graft copolymerization of natural polymers with monomers utilizing various initiation systems is also highlighted in this article.